• Water for future
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• v.28 no.3
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• pp.143-157
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• 1995

A precipitation change in Korea due to atmospheric $CO_2$ doubling has been estimated with a mixed method(Robinson and Finkelstein, 1991) to represent regional precipitation distribution from the simulated precipitation data by three GCM(general circulation model) (CCC, UI, and GFDL GCM) experiments. As a result of this analysis, the precipitation change by atmospheric $CO_2$ doubling can be summarized as follows: The precipitation increases as much as 25mm/yr during spring season and more than 50mm/yr during summer and autumn. However, it decreases as much as 13mm/yr during winter. In terms of percentage with respect to current precipitation climatology, we may have more rain as much as 10%, 13% and 24%, respectively, for spring, summer and autumn than current precipitation. However, we may have less winter precipitation than current climatological average.

• Journal of Powder Materials
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• v.23 no.4
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• pp.287-296
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• 2016

$Ni_{1/3}Co_{1/3}Mn_{1/3}(OH)_2$ powders have been synthesized in a continuously stirred tank reactor via a co-precipitation reaction between aqueous metal sulfates and NaOH using $NH_4OH$ as a chelating agent. The co-precipitation temperature is varied in the range of $30-80^{\circ}C$. Calcination of the prepared precursors with $Li_2CO_3$ for 8 h at $1000^{\circ}C$ in air results in Li $Ni_{1/3}Co_{1/3}Mn_{1/3}O_2$ powders. Two kinds of obtained powders have been characterized by X-ray diffraction (XRD), scanning electron microscopy, particle size analyzer, and tap density measurements. The co-precipitation temperature does not differentiate the XRD patterns of precursors as well as their final powders. Precursor powders are spherical and dense, consisting of numerous acicular or flaky primary particles. The precursors obtained at 70 and $80^{\circ}C$ possess bigger primary particles having more irregular shapes than those at lower temperatures. This is related to the lower tap density measured for the former. The final powders show a similar tendency in terms of primary particle shape and tap density. Electrochemical characterization shows that the initial charge/discharge capacities and cycle life of final powders from the precursors obtained at 70 and $80^{\circ}C$ are inferior to those at $50^{\circ}C$. It is concluded that the optimum co-precipitation temperature is around $50^{\circ}C$.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.329-329
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• 2022

Accurate characterization of terrestrial precipitation variation from high spatial resolution satellite sensors is beneficial for urban hydrology and microscale agriculture modeling, as well as natural disasters (e.g., urban flooding) early warning. However, the widely-used top-down approach for precipitation retrieval from microwave satellites is limited in several hydrological and agricultural applications due to their coarse spatial resolution. In this research, we aim to apply a novel bottom-up method, the parameterized SM2RAIN, where precipitation can be estimated from soil moisture signals based on an inversion of water balance model, to generate high spatial resolution terrestrial precipitation estimates at 0.01º grid (roughly 1-km) from the C-band SAR Sentinel-1. This product was then tested against a common reanalysis-based precipitation data and a domestic rain gauge network from the Korean Meteorological Administration (KMA) over central South Korea, since a clear difference between climatic types (coasts and mainlands) and land covers (croplands and mixed forests) was reported in this area. The results showed that seasonal precipitation variability strongly affected the SM2RAIN performances, and the product derived from separated parameters (rainy and non-rainy seasons) outperformed that estimated considering the entire year. In addition, the product retrieved over the mainland mixed forest region showed slightly superior performance compared to that over the coastal cropland region, suggesting that the 6-day time resolution of S1 data is suitable for capturing the stable precipitation pattern in mainland mixed forests rather than the highly variable precipitation pattern in coastal croplands. Future studies suggest comparing this product to the traditional top-down products, as well as evaluating their integration for enhancing high spatial resolution precipitation over entire South Korea.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.334-334
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• 2022

Improvement of old-fashioned rain gauge systems for automatic, timely, continuous, and accurate precipitation observation is highly essential for weather/climate prediction and natural hazards early warning, since the occurrence frequency and intensity of heavy and extreme precipitation events (especially floods) are recently getting more increase and severe worldwide due to climate change. Although rain gauge accuracy of 0.1 mm is recommended by the World Meteorological Organization (WMO), the traditional rain gauges in both weighting and tipping bucket types are often unable to meet that demand due to several existing technical limitations together with higher production and maintenance costs. Therefore, we aim to introduce a newly developed and cost-effective hybrid rain gauge system at 0.1 mm accuracy that combines advantages of weighting and tipping bucket types for continuous, automatic, and accurate precipitation observation, where the errors from long-term load cells and external environmental sources (e.g., winds) can be removed via an automatic drainage system and artificial intelligence-based data quality control procedure. Our rain gauge system consists of an instrument unit for measuring precipitation, a communication unit for transmitting and receiving measured precipitation signals, and a database unit for storing, processing, and analyzing precipitation data. This newly developed rain gauge was designed according to the weather instrument criteria, where precipitation amounts filled into the tipping bucket are measured considering the receiver's diameter, the maximum measurement of precipitation, drainage time, and the conductivity marking. Moreover, it is also designed to transmit the measured precipitation data stored in the PCB through RS232, RS485, and TCP/IP, together with connecting to the data logger to enable data collection and analysis based on user needs. Preliminary results from a comparison with an existing 1.0-mm tipping bucket rain gauge indicated that our developed rain gauge has an excellent performance in continuous precipitation observation with higher measurement accuracy, more correct precipitation days observed (120 days), and a lower error of roughly 27 mm occurred during the measurement period.

• Korean Journal of Metals and Materials
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• v.47 no.11
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• pp.694-698
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• 2009

The $Co_{3}Ti$ phase hardens appreciably by the fine precipitation of disordered fcc Co-rich phase upon aging after quenching from solution annealing temperature. Transmission electron microscope (TEM) observations revealed that the precipitates are platelet in shape, lying nearly parallel to the {100} planes of the $Ll_{2}$-ordered matrix, and perfectly coherent with the matrix lattice at the beginning of aging. The high temperature strength increases appreciably with the fine precipitation of disordered Co-rich phase over the whole temperature range investigated. TEM observations of the under-aged and deformed alloys revealed that superdislocations are pinned by precipitates indicating an attractive interaction between dislocations and precipitates. In the over-aged state, thin twins are introduced in the fcc Co-rich precipitates during deformation.

• Resources Recycling
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• v.31 no.5
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• pp.34-41
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• 2022

Smelting reduction of spent lithium-ion batteries results in metallic alloys, slag, and dust containing Li(I). Precipitation of Li₂CO₃ was performed using the synthetic leachate of the dust. Herein, the effects of the precipitant and addition of non-aqueous solvents on the precipitation of Li(I) were investigated. Na₂CO₃ was a more effective precipitating agent than (NH₄)₂CO₃ owing to the hydrolysis reaction of dissolved ammonium and carbonate. The addition of acetone or ethanol improved the Li(I) precipitation percentage for both the precipitants. When using (NH₄)₂CO₃, the Li(I) precipitation percentage increased at a solution pH of 12. Under the same conditions, the Li(I) precipitation percentage using Na₂CO₃ was much higher than that using (NH₄)₂CO₃.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.45 no.6
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• pp.44-54
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• 2013

Replacing OMG (old magazine) to ONP (old newspaper) by raising optical property through $CaCO_3$ in-situ precipitation method in white duplex board presents cost reduction and possible drying energy saving. The strength property impairment by the presence of $CaCO_3$ could be supplemented by the fiber furnish treatment or strength polymer addition. In $CaCO_3$ in-situ precipitation of ONP, it was found from morphological study using FlowCAM, an image analyzer, that most of calcium carbonate were formed on the fines, and made the size of the fines larger. For the case of forming calcium carbonate only on the fractionated fines, the size of the fines were the biggest, and there were more clean surface areas available for bonding for the fractionated long fibers when fractionated fibers and fines were regrouped to make paper.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.2
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• pp.249-256
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• 2011

In this study, the Ni-based catalysts for the production of synthetic natural gas were prepared by various preparation methods such as the co-precipitation, precipitation, impregnation and physical mixing methods. The ranges of the reaction conditions were the temperatures of 250~$350^{\circ}C$, $H_2$/CO mole ratio of 3.0, the pressures of 1 atm and the space velocity of 20000 $ml/g_{-cat{\cdot}}{\cdot}h$. It was found that the catalyst prepared by precipitation method had higher CO conversion than the catalyst prepared by co-precipitation method. While the catalyst prepared by precipitation method had the formation of NiO structure, the catalyst prepared by co-precipitation method had the formation of $NiAl_2O_4$ structure. It was confirmed that Ni-based catalyst prepared by the physical mixing method had the lowest CO conversion because it was deactivated by the production of $Ni_3C$ during the methanation. As a result, it was shown clearly that Ni-based catalysts prepared by impregnation method expressed the highest catalytic activity in CO methanation.

• Proceedings of the Microbiological Society of Korea Conference
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• 2001.11a
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• pp.26-36
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• 2001

A novel approach of microbiologically-enhanced crack remediation (MECR) has been initiated and evaluated in this report. Under the laboratory conditions, Bacillus pasteurii was used to induce $CaCO_3$ precipitation as the microbial urease hydrolyzes urea to produce ammonia and carbon dioxide. The ammonia released in surroundings subsequently increases pH, leading to accumulation of insoluble $CaCO_3$. Scanning electron micrography (SEM) and x-ray diffraction (XRD) analyses evidenced the direct involvement of microorganisms in $CaCO_3$ precipitation. In biochemical studies, the primary roles of microorganisms and microbial urease were defined. Furthermore, the role of urease in $CaCO_3$ precipitation was characterized utilizing recombinant Escherichia coli that encoded B. pasteurii urease genes in a plasmid. Microorganisms immobilized in polyurethane (PU) polymer were applied to remediate concrete cracks. Although microbiologically- induced calcite precipitation enhanced neither the tensile strength nor the modulus of elasticity of the PU polymer, cement mortar whose crack was remediated with the cemaden polymer showed a significant increase in compressive strength. Through detailed investigation, MECR showed an excellent potential in cementing cracks in granite, concrete, and beyond.

• Nuclear Engineering and Technology
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• v.55 no.2
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• pp.516-522
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• 2023

The co-precipitation process plays a key role in the decontamination of radionuclides from low and intermediate levels of liquid waste. For that reason, the removal of Cs ions from waste solution by the co-precipitation method was carried out. A simulated liquid waste (¹³³Cs) was prepared from a 0.1 M CsCl solution, while wastewater generated by washing steel ash served as a representative of radioactive cesium solution (¹³⁷Cs). By co-precipitation, potassium ferrocyanide was applied for the adsorption of Cs ions, while nickel nitrate and iron sulfate were selected for supporting the precipitation. The amount of residual Cs ions in the CsCl solution after precipitation and filtration was determined by ICP-OES, while the radioactivity of ¹³⁷Cs was measured using a gamma-ray spectrometer. After cesium removal, the amount of cesium appearing in both XRD and SEM-EDS was analyzed. The removal efficiency of ¹³³Cs was 60.21% and 51.86% for nickel nitrate and iron sulfate, respectively. For the ash-washing solution, the removal efficiency of ¹³⁷Cs was revealed to be more than 99.91% by both chemical agents. This implied that the co-precipitation process is an excellent strategy for the effective removal of radioactive cesium in waste solution treatment.