• Journal of Magnetics
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• v.19 no.1
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• pp.5-9
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• 2014

The amine functionalized $CoFe_2O_4$ nanoparticles were prepared by thermal decomposition method at reflux temperatures $160^{\circ}C$ and $172^{\circ}C$. The obtained $CoFe_2O_4$ nanoparticles at $160^{\circ}C$ reflux temperature show aggregation free poly-dispersed nanoparticles in 4-15 nm range. In an elevated reflux temperature of $172^{\circ}C$, $CoFe_2O_4$ show aggregated poly-dispersed nanoparticles in the size range of 20-46 nm. The saturation magnetization value at 300 K exhibited 51 emu/g at reflux temperature of $160^{\circ}C$. However, the sample synthesized at an elevated temperature of $172^{\circ}C$ has shown a coercive field value of 560 Oe with saturation magnetization of 68 emu/g.

• Journal of Powder Materials
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• v.13 no.5 s.58
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• pp.336-339
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• 2006

Magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as pain size (or particle size), internal strain and crystal structure. Thus, studies on the synthesis of nanostructured materials with controlled microstructure are necessary fur a significant improvement in magnetic properties. In the present work, nanostructured Fe-Co alloy powders with a grain size of 50 nm were successfully fabricated from the powder mixtures of (99.9% purity) $FeCl_2$ and $CoCl_2$ by chemical solution mixing and hydrogen reduction.

• Proceedings of the Korean Magnestics Society Conference
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• 2011.06a
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• pp.19-19
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• 2011

We studied the effect of Dy content on the magnetic properties of cobalt ferrite single crystal. The $CoFe_{1.9}Dy_{0.1}O_4$ single crystals were grown by the flux method by using $Na_2B_4O_{7.}10H_2O$ (Borax) as a solvent (flux). The black and shiny single crystals were obtained as a product. The X-ray diffraction test at room temperature confirmed the spinel cubic symmetry with lattice constant a = $8.42{\AA}$ of the single crystals. The presences of constitute elements (Co, Fe and Dy) was endorsedby EDAX analysis. The saturation magnetization (Ms) of $CoFe_{1.9}Dy_{0.1}O_4$ single crystals was measured and is found to be 72emu/g or equivalently $3.2{\mu}B$/f.u. at 300 K. The observed Ms and coercivity (Hc) is found to be lower than that of pure $CoFe_2O_4$.

• Journal of the Korean Ceramic Society
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• v.43 no.3 s.286
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• pp.143-147
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• 2006

Co-Fe-Al-O nanogranular thin films were fabricated by RF-magnetron sputtering under an $Ar+O_2$ atmosphere. High resolution transmission electron microscopy revealed that the Co-Fe-Al-O films are composed of bcc (Co, Fe) nanograins finer than 5 nm and an Al-O amorphous phase. A very large electrical resistivity of $374{\mu}{\Omega}cm$ was obtained, together with a large uniaxial anisotropy field of 50 Oe, a hard axis coercivity of 1.25 Oe, and a saturation magnetization of 12.9 kG. The actual part of the relative permeability was measured to be 260 at low frequencies and this value was maintained up to 1.3 GHz. The ferromagnetic resonance frequency was 2.24 GHz. The resulting Co-Fe-Al-O nanogranular thin films with a high electrical resistivity and high resonance frequency are considered to be suitable for GHz magnetic device applications.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.124-124
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• 2017

Fe-Ni-Co 합금 박막(<$100{\mu}m$)을 황화물계 용액에서 전주공정으로 제조하였다. XRF로 측정한 박판의 평균 조성은 Fe-34 wt.% Ni-3 wt.% Co 이다. AFM으로 측정한 표면 조도는 35.2 nm 이다. 표면의 나노 경도는 평균 5.4 GPa 이었다. Oliver 모델을 적용한 구리 박막의 탄성하강강성도는 약 75 이었다. Alekhin 모델을 적용한 구리 박막의 마찰계수, 피로한계는 각각 0.134, 0.027 이었다. 유한요소법으로 평가한 Berkovich 형 나노압침선단의 하중분포를 이차원 선형 및 비선형 해석하면 1 [mN]의 정적하중을 가한 Fe-Ni-Co 박막은 약 576 [mN]로 예측되었다. 압침선단의 하중집중정도는 표면탐침현미경으로 관찰한 압흔의 변형정도와 유사한 경향을 보였다.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.245-245
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• 2011

$BiFeO_3$ (BFO)박막에 전위금속 Pb와 Co를 각각 치환환 박막을 chemical solution deposition 방법으로 Pt/Ti/SiO2/Si(100) 기판위에 증착하였다. Bi 자리에 Pb와 Co를 20 at.% 치환하였으며, 치환된 $Bi_{0.8}Pb_{0.2}FeO_3$ (BPFO), $Bi_{0.8}Co_{0.2}FeO_3$ (BCFO) 박막의 구조적, 자기적 특성 변화를 BFO 박막과 비교하여 조사하였다. XRD 패턴을 분석한 결과 BPFO, BCFO 박막들은 모두 rhombohedrally distorted perovskite 구조였으며 불순물인 pyrochlore 상이 약하게 관측되었다. 치환이 이루어진 BPFO, BCFO 박막들의 자기 이력곡선은 안정된 포화곡선을 나타냈으며 BFO의 포화값(5 emu/$cm^3$)에 비해 크게 증가된 55 emu/$cm^3$, 35 emu/$cm^3$의 값을 나타냈다. 또한 보자력장(coercive field, Hc)값도 BFO의 500 Oe보다 크게 증가된 1,200 Oe, 800 Oe의 값을 보였다.

• Journal of Magnetics
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• v.9 no.4
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• pp.121-124
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• 2004

NiO thickness dependences of perpendicular magnetic anisotropy (PMA) in the $NiO/[CoFe/Pt]_5$ multilayers for exchange biasing and $[CoFe/Pt]_4/Pt/[CoFe/Pt]_4$ for interlayer exchange coupling were investigated. Perpendicular magnetization curve was obtained by out-of-plane extraordinary Hall measurement. Magnetic force microscopy (MFM) has been used for the investigation of magnetic domains on thin films. We confirmed that the interlayer exchange coupling (IEC) as a function of NiO thickness at room temperature existed with a period of two monolayers.

• Applied Science and Convergence Technology
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• v.23 no.5
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• pp.273-278
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• 2014

Using ab initio calculations, the effects of uniaxial, biaxial, and hydrostatic strains on the magnetocrystalline anisotropy of $L1_0$-orderd FePt and CoPt alloys were systematically investigated. Interestingly, the rates and the signs of magnetocrystalline anisotropy changes of FePt and CoPt were determined by the directions and dimensions of strains. The calculation results are consistent with the previous experimental observations and are expected to provide directions to tailor magnetic properties of various types of $L1_0$-ordered FePt and CoPt systems.

• Bulletin of the Korean Chemical Society
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• v.9 no.2
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• pp.87-94
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• 1988

The substitution reaction of Fe$(CO)_5$ by ethylene has been studied for plausible intermediates by means of extended Huckel calculations. Among various reaction mechanisms the favorable reaction pathway is via a dissociative mechanism in which ethylene approaches to Fe$(CO)_4$ unit. For Fe$(CO)_4$ fragment, the square planar conformation is found to be the most stable form by the extended Huckel calculations. Our calculations show that ethylene attacks square planar intermediate formed by removing one carbonyl from Fe$(CO)_5$ and then the unstable species thus formed is distored to the most stable trigonal bipyramid with the ethylene lying in the equatorial plane.

• Journal of the Korean Society of Safety
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• v.3 no.1
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• pp.7-13
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• 1988

The oxides in perovskite type, $LaMO_3$ (M=Ni, Cr, Fe, Co), compared with gas sensors which have been used, were synthesised and then examined sensor response comparatively in order to make a thick film gas sensor having a good gas selectivity, durability and simple manufacturing. The oxides in perovskite type, $LaFe_{1-x}O_3$ (x=0.2, 0.4, 0.6, 0.8), which a part of Fe was replaced with Co, were examined with regard to their electric resistance with variable temperature and sensor response for carbon monoxide gas.