• Title/Summary/Keyword: Co-Evaporation

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Effects of Pulping Conditions in the Reconstituted Tobacco Sheet Making Process on the Properties of the Pulp Slurry (판상엽 펄퍼 운전 조건에 따른 펄핑특성 변화)

  • Sung, Yong-Joo;Han, Young-Lim;Kim, Kun-Soo;Rhee, Moon-Soo;Ha, In-Ho;Lee, Ki-Yeul;Lee, Young-Eh;Kim, You-Choul
    • Journal of the Korean Society of Tobacco Science
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    • v.28 no.2
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    • pp.117-123
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    • 2006
  • The pulping process in a papermaking process for a reconstituted tobacco sheet (RECON) was evaluated. For the practical information, the experiments were conducted in a real mill. Two pulping conditions were chosen and changed depending on the feasibility, such as the pulping temperature and the properties of pulping water. The higher pulping temperature resulted in the easier dissolution of solubles from the raw materials. However, the efficiency of screw press process was decreased by the higher pulping temperature, which resulted in the reduction of the HWS and the concentration in the #1 screw press filtrate. The addition of SEL(Strong extracted liquor) to pulper affected the efficiency of dissolution and the final concentration of #1 screw press filtrate. Although the higher SEL resulted in the less dissolution of the solubles from the raw materials, the concentration of the #1 screw press filtrate was greatly increased by the higher addition of SEL, which could provide much better efficiency to the following evaporation process of the filtrate and could increase the whole productivity.

APPLICATION OF 3D TERRAIN MODEL FOR INDUSTRY DISASTER ASSESSMENT

  • Kim, Hyung-Seok;Cho, Hyoung-Ki;Chang, Eun-Mi;Kim, In-Hyun;Kim, In-Won
    • Proceedings of the KSRS Conference
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    • 2008.10a
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    • pp.3-5
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    • 2008
  • An increase in oil and gas plants caused by development of process industry have brought into the increase in use of flammable and toxic materials in the complex process under high temperature and pressure. There is always possibility of fire and explosion of dangerous chemicals, which exist as raw materials, intermediates, and finished goods whether used or stored in the industrial plants. Since there is the need of efforts on disaster damage reduction or mitigation process, we have been conducting a research to relate explosion model on the background of real 3D terrain model. By predicting the extent of damage caused by recent disasters, we will be able to improve efficiency of recovery and, sure, to take preventive measure and emergency counterplan in response to unprepared disaster. For disaster damage prediction, it is general to conduct quantitative risk assessment, using engineering model for environmental description of the target area. There are different engineering models, according to type of disaster, to be used for industry disaster such as UVCE (Unconfined Vapour Cloud Explosion), BLEVE (Boiling Liquid Evaporation Vapour Explosion), Fireball and so on, among them, we estimate explosion damage through UVCE model which is used in the event of explosion of high frequency and severe damage. When flammable gas in a tank is released to the air, firing it brings about explosion, then we can assess the effect of explosion. As 3D terrain information data is utilized to predict and estimate the extent of damage for each human and material. 3D terrain data with synthetic environment (SEDRIS) gives us more accurate damage prediction for industrial disaster and this research will show appropriate prediction results.

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Fabrication of Thick SmBCO/IBAD-MgO coated conductor (후막 SmBCO/IBAD-MgO 초전도 박막선재의 제조)

  • Lee, J.H.;Kang, D.K.;Ha, H.S.;Ko, R.K.;Oh, S.S.;Kim, H.K.;Yang, J.S.;Jung, S.W.;Moon, S.H.;Youm, D.;Kim, C.J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.05a
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    • pp.9-9
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    • 2009
  • Coated conductor is required to have good critical current property for high efficiency of electric power applications. Until now, long coated conductor does not show high Jc over 3 MA/$cm^2$ in thick superconducting layer because of texture degradation by thick superconducting layer. In this study, in order to overcome this issue, thicker superconducting layer was deposited with optimized conditions to reduce the degradation of critical current density. SmBCO superconducting coated conductor was deposited with 1~3 um of thickness at $750\sim850^{\circ}C$ under 15~20 mTorr of oxygen partial pressure using batch type EDDC( evaporation using drum in dual chamber). The buffered substrate for superconducting layer deposition was used IBAD-MgO template with the architecture of $LaMnO_3/MgO/Y_2O_3/Al_2O_3$/Hastelloy. After fabrication of coated conductor, critical current was measured by 4-prove method under self-magnetic field and 77K. In addition, surface morphology and texture were analyzed by SEM and XRD, respectively. 3 um thick SmBCO coated conductor shows highest $I_C$ values of 638A/cm-w in 1 m long in the world.

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The Change of Magnetic Easy Axis in Ion Beam Mixed Co/Pt Multilayer

  • Kim, S.H.;Chang, G.S.;Son, J.H.;Kim, T.Y.;Chae, K.H.;Kang, S.J.;Lee, J.;Jeong, K.;Lee, Y.P.;Whang, C.N.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.162-162
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    • 2000
  • We have studied magnetic properties of Co/Pt multilayered films which have attracted great interest as high-density magneto-optical (MO) recording media due to their good MO properties. For this study, [Pt(45 )/Co(35 )]$\times$8 films were deposited with a Pt buffer layer of 60 on Si(100) substrate by alternating electron-beam evaporation in a high vacuum and were ion beam mixed by using 80keV Ar+ at 25$0^{\circ}C$. Especially, an external magnetic field was added to help changing magnetic property during ion beam mixing (IBM). The intermixing of Co and Pt layers after IBM was confirmed with Rutherford Backscattering Spectroscopy (RBS) and Transmission Electron Microscopy (TEM). The MO property of the film was measured with magneto-optical Kerr spectrometer and the change of magnetic easy axis in the film plane was observed from Ker loop data. This anomalous result might be correlated with the change of atomic structure due to the intermixing effect.

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Properties of CIGS thin film developed with evaporation system (진공증발원 시스템을 이용한 CIGS 박막의 특성평가에 관한 연구)

  • Kim, Eundo;Jeong, Ye-Sul;Jung, Da Woon;Eom, Gi Seog;Hwang, Do Weon;Cho, Seong Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.85.1-85.1
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    • 2010
  • $Cu(In,Ga)Se_2$ (CIGS) thin film solar cell is currently 19.5% higher efficiency and developing a large area technology. The structure of CIGS solar cell that make five unit layers as back contact, light absorption, buffer, front transparent conducting electrode and antireflection to make them sequentially forming. Materials and various compositions of thin film unit which also manufacture a variety method used by the physical and chemical method for CIGS solar cell. The construction and performance test of evaporator for CIGS thin film solar cell has been done. The vapor pressures were changed by using vapor flux meter. The vapor pressure were copper (Cu) $2.1{\times}10^{-7}{\sim}3.0{\times}10^{-7}$ Torr, indium (In) $8.0{\times}10^{-7}{\sim}9.0{\times}10^{-7}$ Torr, gallium (Ga) $1.4{\times}10^{-7}{\sim}2.8{\times}10^{-7}$ Torr, and selenium (Se) $2.1{\times}10^{-6}{\sim}3.2{\times}10^{-6}$ Torr, respectively. The characteristics of the CIGS thin film was investigated by using X-ray diffraction (XRD), scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) and photoluminescence (PL) spectroscopy using a He-Ne laser. In PL spectrum, temperature dependencies of PL spectra were measured at 1137 nm wavelength.

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Influence of Na incorporation on the Morphology of CIGS absorber layers (Na 첨가량에 따른 CIGS 광흡수층의 결정성 변화에 관한 연구)

  • Kim, Daesung;Kim, Chaewoong;Kim, Daekyong;Lee, Duckhoon;Kim, Taesung
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.52-52
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    • 2010
  • CIS(CuInSe2)계 화합물 태양전지는 높은 광흡수계수와 열적 안정성으로 고효율 태양전지 제조가 가능하여 태양전지용 광흡수층으로 매우 이상적이다. 미국 NREL에서는 이러한 CIGS 태양전지를 Co-evaporation 방법으로 제조 20%이상의 에너지 변환 효율을 달성하였다고 보고하였다. CIGS 태양전지의 경우 기존의 유리 기판 대신 유연한 철강 기판을 사용해 태양전지를 flexible하게 제조 할 수 있다는 장점이 있다. 이러한 flexible 태양전지의 경우 기존의 rigid 태양전지의 적용분야 뿐만 아니라 BIPV, 선박, 장난감, 군용, 자동차등 더욱더 많은 분야에 활용이 가능하다. 하지만 flexible 태양전지에 사용되는 철강기판의 경우 기존의 유리 기판인 SLG에 함유되어 있는 Na이 첨가되어 있지 않아 별도의 Na 첨가가 필요하다. Na은 CIGS 광흡수층의 결정을 증가 시키며 태양전지의 전기적 특성을 향상시킨다. 이러한 Na이 없는 경우 효율이 감소한다. 따라서 flexible 태양전지 개발을 위해서는 Na 첨가에 대한 연구가 필수적이다. 본 연구에서는 Na의 증착 순서를 변화시켜서 CIGS 증착 전, 동시증착, CIGS 증착 후로 나누어 CIGS 광흡수층 결정성의 변화를 알아보고자 한다. Na의 두께를 5nm에서 500nm 까지 단계 별로 나누어 실험을 실시하였다. 이때 CIGS 광흡수층은 미국의 NREL과 같은 3 stage 방식을 이용하였다. 1st stage의 시간은 15분으로 고정하였으며 기판온도는 약 $300^{\circ}C$로 고정 하였다. 2nd stage는 실시간 온도 감지 장치를 이용하여 Cu와 In+Ga의 조성비가 1:1이 되는 시간을 기준으로 Cu의 조성을 30%더 높게 조절하였으며 기판 온도는 약 $640^{\circ}C$로 고정 후 실험을 실시하였다. 3rd stage의 경우 Cu poor 조성으로 조절하기 위해 모든 조건을 10분으로 고정 후 실험을 실시하였다. 기판은 Na의 영향만을 비교하기위하여 Na이 첨가되어있지 않은 corning glass를 사용하였다. 후면 전극으로 약 $1{\mu}m$ 두께의 Mo을 DC Sputtering 방법을 이용하여 증착 하였다. 각각의 Na 두께에 따른 CIGS 광흡수층의 특성을 분석하기 위해 FE-SEM, XRD 분석을 실시하였다.

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A Study on the Characteristics of MgO Thin Films Prepared by Electron Beam (전자빔 증착법에 의해 형성된 MgO 박막의 증착 및 특성)

  • Lee, Choon-Ho;Kim, Sun-Il;Shin, Ho-Shik
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1171-1176
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    • 2002
  • The growth characteristics on the MgO thin films prepared by the e-beam evaporation method have been investigated. We observed the film of preferred orientation and surface morphology with various parameters such as substrate temperature, deposition rate on Si(100) and slide glass respectively. Consequently, it was shown that MgO(111) preferred orientation films can be obtained as the deposition rate was increased on Si(100) substrate. MgO(220) peak was found as the substrate temperature was increased. Whereas, in case of slide glass the orientation is changed from (200) to (111) by substrate temperature. Also we investigated the relationship between the film characteristics and the orientation of MgO thin films.

Research for Deposition of $CeO_2$ Buffer Layer on Coated Conductor by Electron Beam Evaporation (전자빔 증발법에 의한 박막형 고온초전도체의 $CeO_2$ 버퍼층 증착 연구)

  • Lee, J.B.;Park, S.K.;Kim, H.J.;Moon, S.H.;Lee, H.G.;Hong, G.W.
    • Progress in Superconductivity
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    • v.11 no.2
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    • pp.123-127
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    • 2010
  • The properties of buffer layer for thermal and chemical stability in coated conductor is a very important issue. $CeO_2$ has desirable thermal and chemical stability as well as good lattice match. In this study, $CeO_2$ was deposited by electron beam deposition. The MgO(001) single crystal and LMO buffered IBAD substrate(LMO/IBAD-MgO/$Y_2O_3/Al_2O_3$/Hastelloy) were used as substrates, which have $\Delta\phi$ values of ${\sim}8.9^{\circ}$. The epitaxial $CeO_2$ films was deposited with high deposition rate of $12{\sim}16\;{\AA}/sec$. During deposition, the change of oxygen partial pressure(${\rho}O_2$) does not cause change in c-axis texture. In case of $CeO_2$ on MgO single crystal, the substrate temperature was optimized at $750^{\circ}C$ with superior $\Delta\phi$ and $\Delta\omega$ value. Otherwise, In case of LMO buffered IBAD substrate, It was optimized at $650^{\circ}C$ with increasing its deposition thickness of $CeO_2$, which was finally obtained with best $\Delta\phi$ value of $5.5^{\circ}$, $\Delta\omega$ value of $2^{\circ}$ and Ra value of 2.2 nm.

Mist Cooling of High-Temperature Cylinder Surface (고온 실린더의 미스트 냉각)

  • Kim, Mu-Hwan;Lee, Su-Gwan;Park, Ji-Man;Lee, Pil-Jong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.3
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    • pp.448-457
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    • 2002
  • Heat treatment such as quenching of a high-temperature cylinder is being used on steel to produce high strength levels. Especially, the mist cooling with the high and uniform surface heat flux rate s expected to contribute for better products. The experimental mist cooling curve is produced for better understanding, and two distinct heat transfer regions are recognized from the cooling curve produced. It is shown that the liquid film evaporation dominated region follows the film boiling-dominated region as decreasing the temperature of test cylinder by mist flow. Based on the intuitive view from some previous investigations, a simplified model with some assumptions is introduced to explain the mist cooling curve, and it is shown that the estimation agrees well with our experimental data. In the meanwhile, it is known that the wetting temperature, at which surface heat flux rate is a maximum, increases with mass flow rate ratio of water to air ($\varkappa$ < 10). However, based on our experimental data, it is explained that there exists a critical mass flow rate ratio, at which the wetting temperature is maximum, in the range of 3 < $\varkappa$ < 130. Also, it is described that despite of the same value of $\varkappa$, the wetting temperature may increase with mist velocity.

Hydrogeochemical and geostatistical study of shallow alluvial groundwater in the Youngdeok area

  • Kim, Nam-Jin;Yun, Seong-Taek;Kwon, Man-Jae;Kim, Hyoung-Soo;Kim, Chang-Hoon;Koh, Yong-Kwon
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.232-236
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    • 2000
  • Multi-regression statistical analyses were applied for the water quality data of shallow alluvial ground water (n = 47) collected from the Youngdeok area, in order to quantitatively generalize the natural (non-anthropogenic) causes of regional water quality variation. Seven samples having the high contamination index ( $C_{a}$ > 3) reflect the striong effects by anthropogenic activity. Most of the alluvial groundwaters have acquired their quality primarily due to the dissolution of carbonate minerals. The results of multi-regression analysis show that chlorine is mainly derived from seawater effect. Sulfur isotopic compositions of dissolved sulfur and the S $O_4$/Cl ratio also enable us to discriminate the samples (n = 18) which are affected by atmospheric input of marine aerosol (sea-spray) and also by mixing between freshwater and seawater. Hydrogen and oxygen isotope data of the samples collected lie close to the local meteoric water line obtained from nearby Pohang city but has lower slope (5.45) on the $\delta$D-$^{18}$ O plot, indicating that alluvial groundwater was recharged from infiltrated meteoric water which has undergone some degree of kinetic evaporation. The estimated initial isotopic composition of the recharged water ($\delta$D = -74.8$^{0}$ /$_{00}$, $\delta$$^{18}$ O = -10.8$^{[-1000]}$ /$_{[-1000]}$ ) suggests that the alluvial ground water recharge largely occurs during summer storm events.s.s.

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