• Journal of the Korean Magnetic Resonance Society
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• v.28 no.2
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• pp.6-9
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• 2024

HscA is a Hsp70-type chaperone protein that plays an essential role to mediate the iron-sulfur (Fe-S) cluster biogenesis mechanism in Escherichia coli. Like other Hsp70 chaperones, HscA is composed of two domains: the nucleotide binding domain (NBD), which can hydrolyze ATP and use its chemical energy to facilitate the Fe-S cluster transfer process, and the substrate binding domain (SBD), which directly interacts with the substrate, IscU, the scaffold protein of an Fe-S cluster. In the present work, we prepared the isolated SBD construct of HscA (HscA(SBD)) and conducted the solution-state nuclear magnetic resonance (NMR) experiments to have its backbone chemical shift assignment information. Due to low spectral quality of HscA(SBD), we obtained all the NMR data from the sample containing the peptide LPPVKIHC, the HscA-interaction motif of IscU, from which the chemical shift assignment could be done successfully. We expect that this information provides an important basis to execute detailed structural characterization of HscA and appreciate its interaction with IscU.

• Proceedings of the Korean Magnestics Society Conference
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• 2002.12a
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• pp.17-17
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• 2002

The magnetic effects connected to finite-size of the particles become dominant at transition of particles in region several nanometers and less [1]. At reduction of atom numbers in magnetic cluster (tens or hundreds atoms), along the classical features, essential appear the quantum phenomena resulting in spin transformation of magnetic structure, both with reduction of the size and at applying of an external magnetic field. (omitted)

• The Journal of Korea Robotics Society
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• v.1 no.2
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• pp.107-116
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• 2006

We propose a planning algorithm to automatically generate a robust behavior plan (RBP) with which mobile robots can achieve their task goal from any initial states under dynamically changing environments. For this, task description space (TDS) is formulated, where a redundant task configuration space and simulation model of physical space are employed. Successful task episodes are collected, where $A^*$ algorithm is employed. Interesting TDS state vectors are extracted, where occurrence frequency is used. Clusters of TDS state vectors are found by using state transition tuples and features of state transition tuples. From these operations, characteristics of successfully performed tasks by a simulator are abstracted and generalized. Then, a robust behavior plan is constructed as an ordered tree structure, where nodes of the tree are represented by attentive TDS state vector of each cluster. The validity of our method is tested by real robot's experimentation for a box-pushing-into-a-goal task.

• Korean Journal of Culture and Social Issue
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• v.27 no.4
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• pp.475-503
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• 2021

The purpose of this study is to clarify the constructs of emotion suppression and help understanding on the multidimensional nature of emotion suppression by classifying constructs for suppression according to the KMW model. Also, this study examined the gender differences of emotion suppression. For this purpose, 657 adult male and female subjects were evaluated for attitude toward emotions, and difficulty in emotional regulation, as well as depression, state anger and daily stress scale. As a result of the exploratory factor analysis on the scales related to the emotion suppression factors, the emotion suppression factors corresponding to each stage of the KMW model were found to be 'distraction against emotional information, 'difficulty in understanding and interpretation of emotions', 'emotion control beliefs', 'vulnerability on emotional expression beliefs'. Next, the study participants were classified by performing a cluster analysis based on each emotion suppression factor. As a result, four clusters were extracted and named 'emotional control belief cluster', 'emotional expression cluster', 'emotional attention failure cluster', and 'general emotional suppression cluster'. As a result of examining the average difference of male depression, depression, state anger, and daily stress for each group, significant differences were found in all dependent variables. As a result of examining whether there is a difference in the frequency of emotional suppression clusters according to gender, the frequency of emotional suppression clusters was high in men, and the ratio of emotional expression clusters was high in women. Finally, it was analyzed whether there was a gender difference in the effect of the emotional suppression cluster on psychosocial adaptation, and the implications were discussed based on the results of this study.

• The Bulletin of The Korean Astronomical Society
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• v.43 no.1
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• pp.33.2-34
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• 2018

Galaxies associated with massive groups/clusters are normally gas deficient in contrast to field galaxies. HI observations on such galaxies have revealed signs of violent gas stripping, the direct evidence of the environmental effect. At the same time, the notable number of passive galaxies at the cluster outskirts indicates the presence of pre-processing that makes galaxies gas-poor before entering clusters. We investigate the possible channels for the production of the gas deficient galaxies using the state-of-the-art cosmological hydrodynamic zoom-in simulations of 16 clusters (Choi&Yi). We find cluster effect and pre-processing together play an important role in producing the gas-poor galaxies and in both cases gas loss qualitatively agrees with the ram pressure stripping description. Among the currently gas-poor cluster galaxies, 34% are pre-processed before the cluster infall. They are mainly satellites that have undergone ram pressure stripping in group halos. 43% deplete quickly after arriving at cluster during their first approach to the center. Some of them are group halo satellites low in the gas at the infall compared to galaxies directly coming from the field. 24% retain gas even after their first pericentric pass mainly because they are falling into low mass clusters and/or they have a circular orbit that minimizes the ram pressure effect. This study highlights the importance of the past history of galaxies, especially in group halos, before joining the current cluster when understanding the excess of passive galaxies in clusters.

• Bulletin of the Korean Chemical Society
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• v.30 no.2
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• pp.445-448
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• 2009

This study examined the effect of the uptake of one and two electrons on the atomic structure of three isomers of $C_{20}$ clusters, namely the ring, bowl (corannulene like), and cage (the smallest fullerene). Geometry optimizations were performed using the hybrid density functional (B3LYP) methods for neutral, singly and doubly charged $C_{20},\;{C_{20}}^-,and\;{C_{20}}^{2-}$. These results show that the symmetry of the lowest energies for ring and bowl isomers were not changed, whereas the increasing order of energy for the cage (the smallest fullerene) isomers was changed from $D_{2h}\;<\;C_{2h}\;{\leq}\;C_2\;of\;C_{20}\;through\;Ci\;<\;C_{2h}\;<\;C_2\;<\;D_{2h}\;of\;{C_{20}}^-\;to\;Ci\;<\;C_2\;<\;D_{2h}\;<\;C_{2h}\;of\;{C_{20}}^{2-}$. The reduced symmetry isomers of the cage have comparative energy and the ground state symmetry of the neutral and single and double charged $C_{20}$ decreased with increasing number of electrons taken up in the point of energetics. Interestingly, the difference in energy between the ground state and the next higher energy state of ${C_{20}}^{2-}$ was 3.5kcal/mol, which is the largest energy gap of the neutral, single anion and double anion of the cage isomers examined.

• Bulletin of the Korean Chemical Society
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• v.18 no.11
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• pp.1186-1191
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• 1997

Solvolyses of methanesulfonyl chloride (CH3SO2Cl) in water and methanol have been studied theoretically using ab initio self-consistent reaction field (SCRF) molecular orbital method. All stationary structures including transition state on the potential energy surface in solution have been found and compared with the gas phase structures. The overall reaction occurs via a concerted SN2 mechanism with a non-cyclic trigonal bipyramidal transition state, and the activation barrier is lowered significantly in solution. The transition state for the hydrolysis reaction is looser than that for the methanolysis reaction, and this is in accord with the experimental findings that an SN2 type mechanism, which is shifted toward an SN1 process or an SAN process in the hydrolysis and alcoholysis reaction, respectively, takes place. The catalytic role of additional solvent molecules appears to be a purely general-base catalysis based on the linear transition structures. Experimental barrier can be estimated by taking into account the desolvation energy of nucleophile in the reaction of methanesulfonyl chloride with bulk solvent cluster as a nucleophile.

• Proceedings of the Korea Inteligent Information System Society Conference
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• 2001.01a
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• pp.25-29
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• 2001

There are so many researches about the search method for the most compatible dispatching rule to a manufacturing system state. Most of researches select the dispatching rule using simulation results. This paper touches upon two research topics: the clustering method for manufacturing system states using simulation, and the search method for the most compatible dispatching rule to a manufacturing system state. The manufacturing system state variables are given to ART II neural network as input. The ART II neural network is trained to cluster the system state. After being trained, the ART II neural network classifies any system state as one state of some clustered states. The simulation results using clustered system state information and those of various dispatching rules are compared and the most compatible dispatching rule to the system state is defined. Finally there are made two knowledge bases. The simulation experiments are given to compare the proposed methods with other scheduling methods. The result shows the superiority of the proposed knowledge base.

• ETRI Journal
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• v.37 no.1
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• pp.147-156
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• 2015

A typical solid-state drive contains several independent channels that can be operated in parallel. To exploit this channel-level parallelism, a variety of works proposed to split consecutive write sequences into small segments and schedule them to different channels. This scheme exploits the parallelism but breaks the spatial locality of write traffic; thus, it is able to significantly degrade the efficiency of garbage collection. This paper proposes a channel-aware write reordering (CAWR) mechanism to schedule write requests to different channels more intelligently. The novel mechanism encapsulates correlated pages into a cluster beforehand. All pages belonging to a cluster are scheduled to the same channels to exploit spatial locality, while different clusters are scheduled to different channels to exploit the parallelism. As CAWR covers both garbage collection and I/O performance, it outperforms existing schemes significantly. Trace-driven simulation results demonstrate that the CAWR mechanism reduces the average response time by 26% on average and decreases the valid page copies by 10% on average, while achieving a similar hit ratio to that of existing mechanisms.

• The Korean Journal of Ceramics
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• v.4 no.2
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• pp.78-82
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• 1998

The oxygen nonstoichiometry (x) of UO$_{2+x}$ and $(Ce_yU_{1-y})O_{2+x}$ (y=0.05, 0.25) has been measured as a function of oxygen activity (a02) at 100$0^{\circ}C$ by a solid state coulometri titration technique. The results for UO$_{2+x}$ are in a good agreement with literature data and the ao2-dependence of the nonstoichimetry has been well explained with (2:2:2) cluster model. The equilibrium oxygen activity of $(Ce_yU_{1-y})O_{2+x}$ increases with Ce-content (y) for given nonstoichiometry (x), which is ascribed to the fact that Ce is present as Ce$^{3+}\; and\; Ce^{4+}$, and, therefore, the addition of Ce reduces the oxidation capacity of UO$_{2+x}$. From the oxygen activity dependence of x in $(Ce_yU_{1-y})O_{2+x}$ the defect structure of $(Ce_yU_{1-y})O_{2+x}$ is discussed.