• Title/Summary/Keyword: Cluster Models

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Theoretical Studies on Selectivity of Dibenzo-18-Crown-6-Ether for Alkaline Earth Divalent Cations

  • Heo, Ji-Young
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2669-2674
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    • 2012
  • Crown ether is one of well-known host molecules and able to selectively sequester metal cation. We employed M06-2X density functional theory with IEFPCM and SMD continuum solvation models to study selectivity of dibenzo-18-crown-6-ether (DB18C6) for alkaline earth dications, $Ba^{2+}$, $Sr^{2+}$, $Ca^{2+}$, and $Mg^{2+}$ in the gas phase and in aqueous solution. $Mg^{2+}$ showed predominantly strong binding affinity in the gas phase because of strong polarization of CO bonds by cation. In aqueous solution, binding free energy differences became smaller among these dications. However, $Mg^{2+}$ had the best binding, being incompatible with experimental observations in aqueous solution. The enthalpies of the dication exchange reaction between DB18C6 and water cluster molecules were computed as another estimation of selectivity in aqueous solution. These results also demonstrated that $Mg^{2+}$ bound to DB18C6 better than $Ba^{2+}$. We speculated that the species determining selectivity in water could be 2:1 complexes of two DB18C6s and one dication.

Keyword-based network analysis for contemporary fashion show affected by intermedia

  • Lee, Seulah;Shin, HyunJu;Lee, Younhee;Lee, Hyun-Jung
    • The Research Journal of the Costume Culture
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    • v.28 no.4
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    • pp.562-571
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    • 2020
  • Intermedia refers to the convergence of media. The advance of intermedia has not only facilitated the delivery of brand messages in contemporary fashion shows but also facilitated interactive communication. This study investigated the mediating roles played by various media in fashion and fashion shows, focusing on the phenomenon of intermedia in contemporary fashion shows. To investigate the impact of intermedia on contemporary fashion shows, we conducted a social network analysis-a promising approach for research into fashion trends. Analyzing 159 fashion-related articles published in the 2000s, we extracted intermedia-related words (n=253). The relation-ships between keywords made an analysis of between centrality, and cluster variables applied Clauset-Newman-Moore by using KrKwic and NodeXL programs. The results of the between centrality analysis indicated that the most important factors in contemporary fashion shows are "models" and "stages." We found that the impacts of intermedia on contemporary fashion shows can be divided into four categories: "model performance," "symbolic stage management," "new media utilization," and "convergence in arts." Our analysis thus identified considerable synergy between the characteristics of intermedia and contemporary fashion shows. These results have found intermedia-related commonalities in intermedia and fashion show, and this might increase customer interest in fashion, a positive outcome for the fashion industry.

Governance Structures to Facilitate Collaboration of Higher Education Institutions (HEIs) and Science &Technology Parks

  • Kang, Byung-Joo
    • World Technopolis Review
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    • v.5 no.2
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    • pp.108-118
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    • 2016
  • There are very few studies on governance structure for the collaboration between HEIs and science and technology parks until today. Major activities between science parks and HEIs are R&D activities, collaborative researches, technology transfer, space provision for BIs and Technology BIs in the science parks, provision of technical, legal and financial services for start-ups and venture firms. Governance structure for the collaboration of high education institutes with science and technology parks is the handling of complexity and management of dynamic flows of collaboration between two groups. Three models on the governance structure for the collaboration are suggested in this study. The first model is a governance structure that links R&D system such as universities, public research institutes and private research institutes with industrial production cluster such as a group of companies and industrial parks. The second model is a governance structure that has four layers of hierarchy. This hierarchical governance model is composed of four levels of organizations such as central government, three actors, one center for collaboration and many individual research performers. The third model is a governance structure that networks all the stakeholders horizontally. Under this structure, governance is conducted by the network members with no separate and unique governance entity.

Regional Strategic Industry (RSI) Promotion Projects and Their Impact on Regional Economic Growth: Focused on Chungbuk Province Cases (지역전략산업육성사업과 지역경제성장 파급효과: 충북 사례를 중심으로)

  • Choi, Nam-Hee;Jo, Byung-Seol;Ahn, Yoo-Jeong;Lee, Man-Hyung
    • Korean System Dynamics Review
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    • v.14 no.1
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    • pp.5-29
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    • 2013
  • This study tries to measure the direct and indirect effects of the Regional Strategic Industry (RSI) promotion projects in Chungbuk Province in Korea. In specific, it critically examines whether there exists policy consistency and connectivity between the hardware-oriented Stage I (2002~2007) and the software-centered Stage II (2008~2012) RSI promotion projects. Applying System Dynamics (SD) techniques, this study examines complex system characteristics of RSI promotion projects, all of which have been derived from the causal and stock-flow models and their simulated results. Major findings are as follows: Firstly, 'the continuous investment' is regarded as the most crucial policy leverage for the strategic industry promotion and regional economic growth. Secondly, without exceptions, the RSI promotion projects should switch their evaluation criteria to performance-oriented ones. Thirdly, in selecting their subprojects, the RSI promotion projects should pay due attention to evaluating technology value and marketability. Fourthly, it should put policy priority in strengthening cluster networking and interconnectivity among projects, inevitably supporting a selective number of virtuous network systems. Fifthly, auxiliary projects such as marketing, technology aid, and knowledge-based services should not be overlooked.

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Segmentation by Benefit Sought in Marketing Channel : A Sequential Approach (추구혜택에 의한 유통시장의 시장세분화 : 순차적 접근)

  • Yi, Seong-Keun;Kim, Jae-Wook;Lee, Seo-Koo
    • Journal of Distribution Research
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    • v.10 no.3
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    • pp.87-101
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    • 2005
  • Market segmentation has been an important issue in marketing for a long time. Many models and statistical methods have been developed by many scholars. The purpose of this research provides one insight for market segmentation based on clustering technique in channel benefit sought. We proposed a sequential approach in market segmentation. A sequential approach means that we do market segmentation by multi-stage method based on the benefits sought in marketing channel. To achieve this approach, we divided the main benefits sought into subcategories. That is to say, after dividing each benefit sought into more detailed concepts, we did market segmentation sequentially.

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A Divisive Clustering for Mixed Feature-Type Symbolic Data (혼합형태 심볼릭 데이터의 군집분석방법)

  • Kim, Jaejik
    • The Korean Journal of Applied Statistics
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    • v.28 no.6
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    • pp.1147-1161
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    • 2015
  • Nowadays we are considering and analyzing not only classical data expressed by points in the p-dimensional Euclidean space but also new types of data such as signals, functions, images, and shapes, etc. Symbolic data also can be considered as one of those new types of data. Symbolic data can have various formats such as intervals, histograms, lists, tables, distributions, models, and the like. Up to date, symbolic data studies have mainly focused on individual formats of symbolic data. In this study, it is extended into datasets with both histogram and multimodal-valued data and a divisive clustering method for the mixed feature-type symbolic data is introduced and it is applied to the analysis of industrial accident data.

Threshold Modelling of Spatial Extremes - Summer Rainfall of Korea (공간 극단값의 분계점 모형 사례 연구 - 한국 여름철 강수량)

  • Hwang, Seungyong;Choi, Hyemi
    • The Korean Journal of Applied Statistics
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    • v.27 no.4
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    • pp.655-665
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    • 2014
  • An adequate understanding and response to natural hazards such as heat wave, heavy rainfall and severe drought is required. We apply extreme value theory to analyze these abnormal weather phenomena. It is common for extremes in climatic data to be nonstationary in space and time. In this paper, we analyze summer rainfall data in South Korea using exceedance values over thresholds estimated by quantile regression with location information and time as covariates. We group weather stations in South Korea into 5 clusters and t extreme value models to threshold exceedances for each cluster under the assumption of independence in space and time as well as estimates of uncertainty for spatial dependence as proposed in Northrop and Jonathan (2011).

An Analysis of Women's Somatotype and Virtual Fitting Model Size for the Development of Virtual Fitting Models for Consumer (소비자용 가상모델 개발을 위한 성인여성 체형구분 및 가상모델치수 분석)

  • Kang, Yeo Sun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.40 no.5
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    • pp.894-909
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    • 2016
  • This study analyzed a somatotype that was more suitable to a virtual fitting model and to improve the reality of a virtual model size. We analyzed 1,868 women 18-59 years old from the 6th Size Korea data. First, factor analysis was done for abstracting new criteria for dividing the somatotype; subsequently, we selected the waist height proportion to stature (body proportion) and drop (torso shape). Next, the cluster analysis was done with these criteria and 7 body proportion types and 11 torso shapes were distinguished. A virtual model size for the most common somatotype was also developed by a regression analysis of constituting sizes of each factor that was compared with body sizes well as with Clo's virtual model size. The model of this research showed a high similarity in sizes with body as well as improved better realisty than the Clo model which presented size problems such as longer limbs, bigger bust, smaller waist and a smaller arm circumference than the real body.

A Low-Power Clustering Algorithm Based on Fixed Radio Wave Radius in WSN (WSN에서 전파범위 기반의 저 전력 클러스터링 알고리즘)

  • Rhee, Chung Sei
    • Convergence Security Journal
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    • v.15 no.3_1
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    • pp.75-82
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    • 2015
  • Recently, lot of researches on multi-level protocol have been done to balance the sensor node energy consumption of WSN and to improve the node efficiency to extend the life of the entire network. Especially in multi-hop protocol, a variety of models have been studied to improve energy efficiency and apply it in real system. In multi-hop protocol, we assume that energy consumption can be adjusted based on the distance between the sensor nodes. However, according to the physical property of the actual WSN, it's hard to establish this. In this paper, we propose low-power sub-cluster protocol to improve the energy efficiency based on the spread of distance. Compared with the previous protocols, the proposed protocol is energy efficient and can be effectively used in the wireless sensing network.