• 암석학회지
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• 제13권3호
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• pp.133-141
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• 2004

포천지역의 쥬라기 화강암내 결의 특성을 규명하였다 3가지 미세균열의 분포상은 박편의 확대사진(x6.7)에서 잘 나타난다. 우세균열 면은 1번 결의 면에 평행하며, 준 우세균열 면은 2번 결의 면에 평행하다. 이러한 1번 결 및 2번 결을 형성하는 미세균열은 3번 결의 면상에서 상호 거의 수직을 이룬다. 따라서, 연구지역의 화강암질암의 결은 미세균열의 선택적 배향성에 지배된다고 할 수가 있다. 결은 리프트, 그레인, 하드웨어 면의 순으로 발생빈도, 길이 및 밀도가 발달하고 있다.

• 한국세라믹학회지
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• 제31권2호
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• pp.147-154
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• 1994

The imperfections of LiTaO3 crystals grown from the Pt-Rh and the Ir crucible were investigated with X-ray diffraction, optical and electron microscope. The growth direction was <100>h and the plane parallel to the plane connecting two main growth ridges was (012)h which would be the main cleavage plane. The dislocation density in the specimen cut parallel to (012)h plane increased with polishing time and the inverted ferroelectric microdomains were induced based on this dislocations. Such imperfections as 180$^{\circ}$ domains, microcracks, dislocations and stacking faults. could be found in the LiTaO3 crytals. The crystal contaminated with lots of Rh form Pt-Rh crucible during the crystal growing under air atmosphere contained more imperfections. The main cleavage plane and subgrain boundary parallel to its growing axis might be the main source of reducing the mechnical strength during the wafering process.

• 암석학회지
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• 제20권4호
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• pp.219-230
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• 2011

합천지역의 쥬라기 화강암에 대하여 결의 특성에 대한 분석을 실시하였다. 미세균열의 분포상은 박편의 확대사진(${\times}6.7$)에서 잘 확인되었다. 일차 우세 미세균열은 1번 면에 평행하고 이차 우세 미세균열은 2번 면에 평행하다. 이들 1번 결과 2번 결을 형성하는 미세균열은 3번 면상에서 상호 거의 수직을 이룬다. 결과적으로 연구대상 석산에서 채취한 쥬라기 화강암에서 발달하는 결은 미세균열의 배향성과 관련이 있다. 빈도수, 길이 및 밀도와 같은 미세균열의 매개변수들은 1번결 > 2번 결 > 3번 결의 순서로 우세하게 나타난다. 이러한 결과는 결의 상대적인 강도를 지시한다. 한편 6개 방향에 따른 압열 인장강도가 측정되었다. 암석의 강도와 상기한 미세균열 매개변수들 사이에는 밀접한 상관성을 보이고 있다.

• 한국세라믹학회지
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• 제26권5호
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• pp.661-669
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• 1989

The defect structure in LiNbO3 single crystals grown by Czochralski method from the congruently melting composition were investigated. Chemical etching patterns were studied in x-plane, z-plane, and major cleavage plane, respectively, dislocation density was higher at the periphery of crystals than at the center because the thermal stress due to radial temperature gradient had a main effect on it, as compared with dislocations formed from the solid-liquid interface. Many dislocation lineages were arranged along several directions.

• 터널과지하공간
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• 제26권4호
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• pp.327-337
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• 2016

본 연구에서는 화강암 내부의 미세균열 분포에 따른 이방성이 수압파쇄실험 결과에 미치는 영향을 평가하였다. 압력증가율을 일정하게 설정하여 수압파쇄실험을 수행한 결과, 원주방향(주입정 방향과 직교)으로 리프트면이 분포한 시료의 파쇄압력이 가장 낮게 측정되었고, 이는 미세균열의 밀도가 높기 때문이다. 수압파쇄실험과정에서 시료 내부의 변화가 발생하는 주입압력의 크기와 유체 주입속도의 변화 또한 결방향에 따라 분포한 미세균열의 밀도와 관계가 있는 것으로 판단된다. 유체주입속도를 일정하게 설정하여 수압파쇄실험을 수행하였을 경우, 상대적으로 미세균열의 밀도가 높은 리프트면이 원주방향으로 분포된 시료에서 주입압력증가율이 낮게 나타났고, 유체가 침투될 수 있는 균열망이 상대적으로 적게 형성된 그레인면 및 하드웨이면이 원주방향으로 분포된 시료에서는 압력증가율이 높게 나타났다. X-ray CT 촬영을 통해 시료 내부에 생성된 균열의 방향을 확인한 결과, 대부분의 시료에서 리프트면 혹은 그레인면과 평행한 방향으로 균열이 생성된 것을 확인하였고, 이는 암석 내에 상대적으로 미세균열의 밀도가 높아서 분리성이 크기 때문이다.

• 한국결정성장학회지
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• 제20권5호
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• pp.202-206
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• 2010

Single crystals of $ZnWO_4$ were grown successfully in the [100], [010] and [001] directions using the Czochralski method. The growth parameters and the formation of slip plane in $ZnWO_4$ crystals were studied. $ZnWO_4$ crystals had a cleavage plane of (010). The dislocation density on the (010) plane at the center of the crystal was lower than that of the edge region. It was inferred that the high density at the edge of the crystals was caused by the thermal gradient during crystal growth. The etch pit arrangement revealed the (100) slip plane to be most active during crystal growth.

• 한국세라믹학회지
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• 제27권4호
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• pp.447-456
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• 1990

ZnWO4 single crystals were grown by Czochralski method. And the orientation of grown crystals were determined by Laue back reflection, and the crystals were siliced at (100), (010), (001) face before polishing. The morphologys and distribution of etch pits on each face were observed by optical microscopy. In the present study, we understood that dislocation distributjioon rely on shape of solid-liquid interface, and secondary phase acts on the dislocation source. We also observed dislocation trace(etch pits) of (100) slip plane on (010) cleavage plane.

• 한국주조공학회지
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• 제25권1호
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• pp.16-22
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• 2005

This study aims to investigate the effects of the microstructures and nodule type on the fatigue characteristics of cast iron. Fatigue tests were carried out in tension-tension mode using a servo-hydraulic testing machine with load control mode operating at a frequency of 15 Hz. The tests were conducted at stress ratio R=Kmin/Kmax, of 0.1. Initial crack ${\Dalta}K$ values were highly performed with increase in tensile strength of DCI fatigue specimens. ${\Dalta}K_{th}$ region, fatigue crack propagation was primarily advanced through cell boundary and in periphery of near nodule. Fatigue crack propagation rate of D2 consisted with 2Phase(Ferrite+Pearlite) was slow due to crack closure enhanced by crack deflection and occurred crack branching. The generation of crack branch was occurred due to interaction of crack-nodule. At Threshold and Paris zone, the fractographs of the fatigue fracture surface for DCI show typical striations of a ductile fracture and isolated cleavage planes near graphite. The effect of microstructure on fatigue crack propagation of GC strongly depends on the type of flake. The generation of crack branch occurred due to interaction of crack-nodule. The fractographs of the fatigue fracture surface for GC show cleavage plane along the flake graphite.

• 한국주조공학회지
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• 제23권2호
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• pp.77-85
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• 2003

Some alloying elements such as Cr, B, Ti and Si were added individually or as a mixture to Fe-30 at.%Al alloys. The alloys were melted using an arc furnace and then heat-treated for homogenization at 1000$^{\circ}C$ for 7 days and followed by rolling at 1000$^{\circ}C$. The alloying elements on rolling characteristics were investigated by the microstructures and fracture mode before and after rolling. The microstructures before rolling showed that all of the alloys had equiaxed grains. On the other hand, the microstructures of rolling plane as well as its perpendicular plane became elongated after rolling. The alloys such as Fe-30Al, Fe-30Al-3Ti, Fe-30Al-0.5B, Fe-30Al-5Cr and Fe-30Al-3Ti-0.5B revealed better rolling behaviour from the point that intergranular and cleavage fractures were not fundamentally occurred. But the addition of 5Ti or 3Si to Fe-Al alloys had detrimental effects. The Ti-added alloy system such as Fe-30Al-5Ti, Fe-30Al-5Ti-5Cr, Fe-30Al-3Ti-5Cr and Fe-30Al-5Ti-0.5B were cracked through grain and showed cleavage fracture. The Si-added alloy system such as Fe-30Al-5Si, Fe-27Al-3Si and Fe-27Al-5Cr-3Si were cracked along the grain boundary and showed intergranular fracture. $DO_3{\leftrightarrow}B_2$ transition temperature of Fe-30at.%Al alloy was 520$^{\circ}C$, whereas the addition of 3Ti and 3Ti+0.5B comparably increased the temperature to 797 and 773$^{\circ}C$, respectively.

• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.1920-1926
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• 2008

We investigated the C-H bond activation mechanism of aldimine by the [RhCl$(PPH_3)_3$] model catalyst using DFT B3LYP//SBKJC/6-31G*/6-31G on GAMESS. Due to their potential utility in organic synthesis, C-H bond activation is one of the most active research fields in organic and organometallic chemistry. C-H bond activation by a transition metal catalyst can be classified into two types of mechanisms: direct C-H bond cleavage by the metal catalyst or a multi-step mechanism via a tetrahedral transition state. There are three structural isomers of [RhCl$(PH_3)_2$] coordinated aldimine that differ in the position of chloride with respect to the molecular plane. By comparing activation energies of the overall reaction pathways that the three isomeric structures follow in each mechanism, we found that the C-H bond activation of aldimine by the [RhCl$(PH_3)_3$] catalyst occurs through the tetrahedral intermediate.