• 제목/요약/키워드: Clean technology

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ON CLEAN AND NIL CLEAN ELEMENTS IN SKEW T.U.P. MONOID RINGS

  • Hashemi, Ebrahim;Yazdanfar, Marzieh
    • 대한수학회보
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    • 제56권1호
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    • pp.57-71
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    • 2019
  • Let R be an associative ring with identity, M a t.u.p. monoid with only one unit and ${\omega}:M{\rightarrow}End(R)$ a monoid homomorphism. Let R be a reversible, M-compatible ring and ${\alpha}=a_1g_1+{\cdots}+a_ng_n$ a non-zero element in skew monoid ring $R{\ast}M$. It is proved that if there exists a non-zero element ${\beta}=b_1h_1+{\cdots}+b_mh_m$ in $R{\ast}M$ with ${\alpha}{\beta}=c$ is a constant, then there exist $1{\leq}i_0{\leq}n$, $1{\leq}j_0{\leq}m$ such that $g_{i_0}=e=h_{j_0}$ and $a_{i_0}b_{j_0}=c$ and there exist elements a, $0{\neq}r$ in R with ${\alpha}r=ca$. As a consequence, it is proved that ${\alpha}{\in}R*M$ is unit if and only if there exists $1{\leq}i_0{\leq}n$ such that $g_{i_0}=e$, $a_{i_0}$ is unit and aj is nilpotent for each $j{\neq}i_0$, where R is a reversible or right duo ring. Furthermore, we determine the relation between clean and nil clean elements of R and those elements in skew monoid ring $R{\ast}M$, where R is a reversible or right duo ring.

Facile and Clean Synthetic Route to Non-Layered Two-Dimensional ZIF-67 Nanosheets

  • Choi, Chang-Ho
    • 청정기술
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    • 제26권4호
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    • pp.257-262
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    • 2020
  • Two-dimensional (2D) metal organic framework (MOF) nanosheets (NSs) have recently gained considerable interest owing to their structural advantages, such as large surface area and exposed active sites. Two different types of 2D MOF NSs have been reported, including inherently layered MOFs and non-layered ones. Although several studies on inherently layered 2D MOFs have been reported, non-layered 2D MOFs have been rarely studied. This may be because the non-layered MOFs have a strong preference to form three-dimensionality intrinsically. Furthermore, the non-layered MOFs are typically synthesized in the presence of the surfactant or modulator, and thus developing facile and clean synthetic routes is highly pursued. In this study, a facile and clean synthetic methodology to grow non-layered 2D cobalt-based zeolitic imidazolate framework (ZIF-67) NSs is suggested, without using any surfactant and modulator at room temperature. This is achieved by directly converting ultrathin α-Co(OH)2 layered hydroxide salt (LHS) NSs into non-layered 2D ZIF-67 NSs. The comprehensive characterizations were conducted to elucidate the conversion mechanism, structural information, thermal stability, and chemical composition of the non-layered 2D ZIF-67. This facile and clean approach could produce a variety of non-layered 2D MOF NS families to extend potential applications of MOF materials.

팜 잔사유를 이용한 고품위화 석탄의 안정화 특성분석 (Stabilization Characteristics of Upgraded Coal Using Palm Oil Residues)

  • 박인수;전동혁;조완택;유지호;이시훈;이영우
    • 청정기술
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    • 제19권4호
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    • pp.469-475
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    • 2013
  • 본 연구에서는 팜 잔사유를 이용하여 고품위화된 저등급 석탄의 건조 안정화 특성을 알아보았다. 인도네시아 저등급 석탄인 에코탄을 사용하였고, 팜지방산증류물(palm fatty acid distillate, PFAD)을 혼합시킨 후 $107^{\circ}C$ 질소분위기에서 건조하였으며 그 후에 안정화 특성을 평가하였다. 교차점온도(crossing-point temperature, CPT) 측정을 통해 자연발화 경향을 확인하였으며, 저온산화 실험을 통해 $CO_2$, CO 가스 배출량은 건조석탄보다 고품위 석탄이 감소하는 것을 확인하였다. 수분 재흡착 실험을 통해 고품위 석탄이 대기방치와 항온항습 분위기에서 수분 재흡착이 줄어드는 것을 확인하였다. 고품위화된 석탄은 PFAD의 표면코팅을 통해 안정화 되며, 함량이 증가할수록 안정화도가 높아졌다.

토양매설 스테인리스강 상수도 배관의 부식원인 규명 (Elucidation of Corrosion and Failure of Stainless Steel Tubing buried in Soil for Potable Water)

  • 김영식;박수진;황보덕;신민철
    • Corrosion Science and Technology
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    • 제11권1호
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    • pp.20-28
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    • 2012
  • Since buried pipes contact the soil directly, corrosion by the soil could be occurred. Recently, some stainless steel pipes after 8 years burial at G area were corroded and leaked. In order to elucidate highly corroded phenomena(its rate was about 0.175 mm/y) of these pipes, the investigation for corrosion environment, soil, stray current's effect, and chemical analysis on the pipes were performed. Most of investigated sites were close to traditional water-closet and showed high moisture and thus those areas could be highly corrosive. In the investigation by two kinds of soil evaluation methods, it was revealed that the soils at G areas were highly corrosive, and moreover the contents of sulfate reducing bacteria in the soils were high. Also, open circuit potentials of many pipes showed different values and its potentials were high positive. Therefore, it was considered that corrosion of buried pipes at G area could be affected by high corrosive soil's environment and stray current corrosion.

Effects of NaCl Concentration and Solution Temperature on the Galvanic Corrosion between CFRP and AA7075T6

  • Hur, S.Y.;Kim, K.T.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • 제19권2호
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    • pp.75-81
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    • 2020
  • To reduce structural weight, light metals, including aluminum and magnesium alloys, have been widely used in various industries such as aircraft, transportation and automobiles. Recently, composite materials such as Carbon Fiber Reinforced Plastics (CFRP) and Graphite Epoxy Composite Material (GECM) have also been applied. However, aluminum and its alloys suffer corrosion from various factors, which include aggressive ions, pH, solution temperature and galvanic contact by potential difference. Moreover, carbon fiber in CFRP and GECM is a very efficient cathode, and very noble in the galvanic series. Galvanic contact between carbon fiber composites and metals in electrolytes such as rain or seawater, is highly undesirable. Notwithstanding the potentially dangerous effects of chloride and temperature, there is little research on galvanic corrosion according to chloride concentration and temperature. This work focused on the effects of chloride concentration and solution temperature on AA7075T6. The increased galvanic corrosion between CRFP and AA7075T6 was evaluated by electrochemical experiments, and these effects were elucidated.

Control of Galvanic Corrosion Between A516Gr.55 Steel and AA7075T6 Depending on NaCl Concentration and Solution Temperature

  • Hur, S.Y.;Jeon, J.M.;Kim, K.T.;Kim, Y.S.
    • Corrosion Science and Technology
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    • 제19권6호
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    • pp.281-287
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    • 2020
  • Chloride ion is one of the most important corrosive agents in atmospheric corrosion, especially in marine environments. It has high adsorption rate and increases the conductivity of electrolytes. Since chloride ions affect the protective properties and the surface composition of the corrosion product, they increase the corrosion rate. A low level of chloride ions leads to uniform corrosion, whereas a high level of chloride ions may induce localized corrosion. However, higher solution temperatures tend to increase the corrosion rate by enhancing the migration of oxygen in the solution. This work focused on the effect of NaCl concentration and temperature on galvanic corrosion between A516Gr.55 carbon steel and AA7075T6 aluminum alloys. When AA7075T6 aluminum alloy was galvanically coupled to A516Gr.55 carbon steel, AA7075T6 was severely corroded regardless of NaCl concentration and solution temperature, unlike the corrosion properties of single specimen. The combined effect of surface treatment involving carbon steel and aluminum alloy on corrosion behavior was also discussed.

이소프렌 정제를 위한 제올라이트 5A 흡착제 재생 (Regeneration of Zeolite 5A in the Adsorption Process for Isoprene Purification)

  • 전경진;유계상;이창하;안병성
    • 청정기술
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    • 제16권4호
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    • pp.272-276
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    • 2010
  • 이소프렌(isoprene)에 포함되어 있는 acetylene류의 불순물 중 2-butyne을 선택적으로 제거하기 위해 제올라이트를 흡착제로 사용한 흡착 및 탈착 특성을 연구하였다. 본 연구에서는 제올라이트 5A를 사용하여 흡착실험을 실시한 후, 흡착제를 재생하기 위한 탈착실험을 수행하여 2-butyne의 재흡착 성능을 확인하였다. 감압 및 고온의 질소 가스를 이용한 탈착실험에서 온도 영향과 탈착 시간에 따른 변화를 검토하고 재흡착실험을 실시하였으며 에너지 소비를 최소화하며 흡착성능을 유지할 수 있는 탈착조건을 확립하였다. 473 K, 16시간 탈착 및 액상흡착 반복실험을 10회 진행하여 흡착제의 재생가능성을 확인하였다.

Life-Cycle Assessment of Technological Processes

  • Graedel, T.E.
    • 청정기술
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    • 제2권2호
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    • pp.44-50
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    • 1996
  • "Pollution prevention" is an important and appropriate part of efforts to minimize the environmental impacts of industrial processes, but it is only a part. Even more important is to assess the environmental characteristics of processes across all stages of their lives. This paper presents a formalism for evaluating the environmental implications of processes at each life stage(a procedure termed "life-cycle assessment").

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