• Economic and Environmental Geology
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• v.40 no.6
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• pp.771-784
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• 2007

This study shows the weathering characteristics of mica-schist affected by faulting and metamorphism through laboratory tests. Frozen-thaw test, which simulate the physical-chemical weathering processes in the laboratory, shows the important influence of foliation developed in mica-schist, resulting in $20{\sim}40%$ reduction of UCS according to weathering grade of rock. Slaking durability test was carried out for different weathering grade rock specimens and indicated that the specimens from fault area had a low durability index compared to other relatively fresh samples. XRD analysis allowed to estimate the dynamic evolution of mineral composition through wet-dry cycle in which the chlorite was the most important mineral leached out during slaking test. The creep test indicated that the main deformation produced along the foliation plane. The compacted clay minerals between discontinuity planes influence on the discontinuity shearing properties and result in a big difference between peak shear strength and residual strength. The results of laboratory tests on mica-schist show the possibility of a important deformation along the foliation plane or discontinuity.

• Korean Journal of Heritage: History & Science
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• v.51 no.1
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• pp.4-31
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• 2018

The Neolithic pottery excavated from the Jungsandong site has been classified into four types of pottery (I: feldspar type, II: mica type, III: talc type and IV: asbestos type) according to their mineral composition. These four types of potteries generally appear to have undergone incomplete firing, while the level of oxidation in the type I pottery objects, which have a relatively higher clay content, was found to be particularly low. The type III objects, which have a high talc content, are judged to have been somewhat slow in removing carbon because they contain saponite belonging to the smectite group. Of the four types of pottery, type IV showed the highest redness and the most uniform characteristics, thus indicating a good level of oxidation. In particular, fixed carbide (C; 33.7 wt.%) with a thickness of about 1mm, and originating from organic substances, was detected inside the walls of the type I pottery, while the deep radial cracks in the outer surfaces of the pottery are thought to have been caused by repeated thermal shocks. Given that all of the pottery except for the type I artifacts are considered to be have been made for storage purposes, those containing talc and tremolite are easy to done liquid storing vessels based on an analysis of their material characteristics. As for the type II relics, which are composed of various minerals and exhibit poor physical properties, they seem to have been used for simple storage purposes. As domestic talc and asbestos mines were concentrated in the areas of Gyeonggi, Gangwon, Chungbuk, and Chungnam, it seems likely that talc and tremolite were produced as contiguous minerals. Considering the distance between the remains in Jungsandong and these mines and their geographical distribution, there is a possibility - albeit somewhat slight - that these mines were developed for the mining of various minerals. Although ultramafic rock masses - such as serpentine capable of generating talc and tremolite - have not been found in the Jungsandong area, limestone and biotite granite containing mica schist have been identified in the northwestern part of Yeongjong Island, indicating that small rock masses might have formed there in the past. Therefore, it is judged necessary to accumulate data on pottery containing talc and tremolite, other than the remains in Jungsandong, and to investigate the rocks and soils in the surrounding area with greater precision. The firing temperatures of the pottery found at the Jungsandong site were interpreted by analyzing the stability ranges of the mineral composition of each type. As a result, they have been estimated to range from 550 to $800^{\circ}C$ for the type I artifacts, and from 550 to $700^{\circ}C$ for the type I, II and IV artifacts. However, these temperatures are not the only factors to have affected their physical properties and firing temperature, and the types, particle sizes, and firing time of the clay should all be taken into consideration.

• Korean Journal of Soil Science and Fertilizer
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• v.34 no.4
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• pp.237-244
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• 2001

Investigation on the surface charge properties of some Korean arable soils was performed by ion adsorption technique with two kinds of indifferent ion ($Na^+$ and $K^+$) at the range of pH 3 to 9 in bulk solution. The contribution of soil components(organic matter, oxides and clay mineral) on the surface charge density was determined at two soil depth with different solid particle composition When the pH of solution increased, the negative charge of soil surface was increased among the all soils, but positive charge were not appeared above pH 6. apparently. The magnitude of surface charge density measured by NaCl adsorption method showed ra nges of $0.01{\sim}2.84cmol_c{\cdot}kg^{-1}$ and $7.41{\sim}12.20cmol_c{\cdot}kg^{-1}$ at pH 3 and pH 9, respectively. Ion adsorption method using KCl as index ion overestimated than the method using NaCl as index ion. The content of organic matter is the strongest factor on the value of dCEC/dpH.

• Journal of the Mineralogical Society of Korea
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• v.19 no.4 s.50
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• pp.291-300
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• 2006

This study has been carried out to reveal the mineralogical compositions, the concentrations of heavy metals, and related factors in the sediments of the Kumho River which is the main tributary of the Nakdong River. Even though this river flows in a short distance, it runs through different geology and industrial areas and can be a good candidate to study different geological and anthropogenic factors affecting the concentrations of heavy metals in the sediment. The major rock-forming minerals were quartz and albite. Minor amount of orthoclase, microcline, and amphybole were also identified. Clay minerals including illite, chlorite, kaolinite were associated with those minerals. In the downstream, no noticeable changes in species and amount of minerals were observed, indicating there is almost no influence on the mineralogical compositions from rock types. The concentrations of heavy metals in the sediments are in the order of Zn > Pb > Cu > Ni > Cr > Co > Cd. Following the downstream, the concentrations of heavy metals generally increase, except Pb. The regional increase of the heavy metal content is well correlated with the location of the tributary. Without changes in mineral compositions, the main factors controlling the heavy metal contents are the locations of pollutant sources. Except Pb and Ni, most of the concentrations of heavy metals were thought to be enriched by the past pollutant sources.

• Geotechnical Engineering
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• v.12 no.4
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• pp.115-130
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• 1996

The definition of laterite or lateritic soils is discussed on a climatic condition of tropical and semitropical regions, and the weathering index is indicated by the chemical composition. The chemical composition of$(Fe_2O_3+Al_2O_3)$ of the weathered granite residual soils in tropical and the temperate regions which shelus laterization usually ranges from 0.2 to 0.5. This study shows that the chemical ratio of the Chonju Ajung site is about 0.2U, and that of the regions along the shore of the western sea of Hongsong and Taechon is about 0.33. The chemical ratio of the non-laterite is less than 0.2, and the Kyougju Pulguksa site confirmed about 0.17, The X-Ray diffraction test shows that the clay mineral of the laterite soils is made of kaolinite, this X -Ray result indicates the same characteristics compared with the wrathered granite residual soils of other sites.

• Economic and Environmental Geology
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• v.47 no.5
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• pp.479-488
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• 2014

Naturally occurring asbestos (NOA) from disturbance of rocks and soils has been overlooked as a source of exposure that could potentially have a detrimental impact on human health. But, few researches on mineralogical characteristics of NOA occurred in soils have been reported in Korea. Therefore, the objective of this study was to investigate the mineralogical characteristics of NOA occurred in soils at Daero-ri area, Seosan, Chungnam Province, Korea. Sedimentation method was used for particle size separation of the asbestos-containing soils. XRD and PLM analyses were used to characterize mineralogical characteristics and mineral assemblages in soils. SEM-EDS and TEM-EDS analyses were used to characterize mineral morphology and chemical composition. Particle size analyses of the asbestos-containing soils showed they were composed of 26-93% sand, 4-23% silt and 3-70% clay. Soil texture of the soils was mainly sand, sandy loam, sandy clay, and clay. PLM analyses of the soil showed that most of the soil contained asbestiform tremolite and actinolite. The average content of asbestos in the soil was 1.5 wt. %. Therefore, the soil can be classified into asbestos-contaminated soils based on U. S. Environmental Protection Agency classification (content of asbestos in contaminated soil > 1%). Morphologically different types of tremolite such as long fibrous, needle-like, fiber bundle, bladed and prismatic forms co-existed. Prismatic tremolite was dominant in sand fraction and asbestiform tremolite was dominant in silt fraction. This study indicates that the prismatic form of tremolite transform gradually into a fibrous form of tremolite due to soil weathering because tremolite asbestos was mainly existed in silt fraction rather than sand fraction.

• Journal of the Mineralogical Society of Korea
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• v.18 no.2
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• pp.109-115
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• 2005

Beidellite, a member of the smectite group, was synthesized hydrothermally from dickite. Physical and chemical properties of the synthetic Na-beidellite were characterized by the analytical methods of XRD, IR, TG, DTA, EDS, XRF and ICP. The result of Greene-Kelly test indicates that the synthesized smectite is Na-beidellite. IR spectrum of synthesized beidellite exhibited Al-O-H bending vibration at $818\;cm^{-1}\;and\;770\;cm^{-1}$ which was observed particularly in pure beidellite. TGA analysis revealed that the synthesized Na-beidellite comprises $16\;wt\%$ of water. DTA curve showed an endothermic peak at $117^{\circ}C$ due to dehydration reaction and peaks at $482^{\circ}C$ and $685^{\circ}C$ due to dehydroxylation reaction. The clay mineral was transformed to mullite and cristobalite at the temperature of $1028^{\circ}C$. The CEC value, Methylene Blue test and swelling capacity was determined to be $116\~118\;cmol/kg,\;84\~91\%,\;29\~32\;mL/2g$, respectively. The chemical composition of the synthesized phase was identified as $Na_{0.5}Al_{2.5}Si_{3.5}O_{10}(OH)_2$ from EDS and XRF analyses.

• The Journal of Engineering Geology
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• v.21 no.4
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• pp.313-322
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• 2011

On September 2007, numerous slopes at Jeonranam-Do collapsed as a result of rainfall related to Typhoon Nari. Failure occurred at a road cut-slope on the ${\bigcirc}{\bigcirc}$ detour road, damaging transport infrastructure. This study aims to determine the cause of failure based on field investigations, the geotechnical properties of soil, clay mineral composition, and quantitative analysis. The studied cut slope consists of weathered soil that originated from volcanic rocks, and minor faults and a mafic dyke. Surface water tends to seep into the soil because the roadway is not sealed and because of poorly installed drainage. Sieve and XRD analyses indicate that soils in the failure zone are ML and CH, which are prone to swelling due to the presence of clay minerals such as smectite and vermiculite. The slope failed due to the improper construction of drainage facilities, the presence of geological weak zones, and high soil contents of swelling clay.

• Journal of Conservation Science
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• v.30 no.4
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• pp.395-407
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• 2014

In this study, firing temperature of bricks from the Songsanri tomb complex is interpreted based on the mineralogical and physical changes of soil samples fired at different temperature. When soil samples were burned at 500 to $1,200^{\circ}C$, phase transition of clay minerals affected the mineralogical composition and microstructure, which leaded to alteration of physical features as color, water absorption and porosity. Mineralogical composition can be assumed to vary with the temperature by mineral phase stability, however, color, water absorption, porosity and microstructure had slow change under $1,000^{\circ}C$, and had rapid change from 1,000 to $1,200^{\circ}C$. Upon the mineral and physical alteration of soil, firing temperature of bricks from the Songsanri tomb complex were estimated. Some bricks were over fired at temperature more than $1,200^{\circ}C$, some high-burned bricks were fired from 1,100 to $1,200^{\circ}C$, some bricks were fired by 900 to $1,000^{\circ}C$ and some bricks ere assumed not to be fired. Henceforward mineralogical and physical study can be applied to interpretate more precise firing temperature.

• Economic and Environmental Geology
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• v.45 no.5
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• pp.487-502
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• 2012

This paper is focused on mineral compositions, microstructures and distributional characters of remained grains in the fault rocks collected from a fault developed in Yongdang-ri, Yangbuk-myeon, Gyeongju City, Korea, using X-ray diffraction (XRD), optical microscope, laser grain size analysis and fractal dimension analysis methods. The exposed fault core zone is about 1.5 meter thick. On the average, the breccia zone is 1.2 meter and the gouge zone is 20cm thick, respectively. XRD results show that the breccia zone consists predominantly of rock-forming minerals including quartz and feldspar, but the gouge zone consists of abundant clay minerals such as chlorite, illite and kaolinite. Mineral vein, pyrite and altered minerals commonly observed in the fault rock support evidence of fault activity associated with hydrothermal alteration. Fractal dimensions based on box counting, image analysis and laser particle analysis suggest that mineral grains in the fault rock underwent fracturing process as well as abrasion that gave rise to diminution of grains during the fault activity. Fractal dimensions(D-values) calculated by three methods gradually increase from the breccia zone to the gouge zone which has commonly high D-values. There are no noticeable changes in D-values in the gouge zone with trend being constant. It means that the bulk-crushing process of mineral grains in the breccia zone was predominant, whereas abrasion of mineral grains in the gouge zone took place by continuous fault activity. It means that the bulk-crushing process of mineral grains in the breccia zone was predominant, whereas abrasion of mineral grains in the gouge zone took place by continuous fault activity. Mineral compositions in the fault zone and peculiar trends in grain distribution indicate that multiple fault activity had a considerable influence on the evolution of fault zones, together with hydrothermal alteration. Meanwhile, fractal dimension values(D) in the fault rock should be used with caution because there is possibility that different values are unexpectedly obtained depending on the measurement methods available even in the same sample.