• Title/Summary/Keyword: Cladding embrittlement

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Overview of Research Trends and Problems on Cr-Mo Low Alloy Steels for Pressure Vessel (압력용기용 Cr-Mo 계 저합금 강의 개발동향 및 재료적 문제점)

  • Chi, Byung-Ha;Kim, Jeong-Tae
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.67-76
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    • 2000
  • Cr-Mo low alloy steels have been used for a long time for pressure vessel due to its excellent corrosion resistance, high temperature strength and toughness. The paper reviewed the latest trends on material development and some problems on Cr-Mo low alloy steel for pressure vessel, such as elevated temperature strength, hardenability, synergetic effect between temper and hydrogen embrittlement, hydrogen attack and hydrogen induced disbonding of overlay weld-cladding.

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Overview of Research Trends and Problems on Cr-Mo Low Alloy Steels for Pressure Vessel (압력용기용 Cr-Mo 계 저합금 강의 개발동향 및 재료적 문제점)

  • Chi, Byung-Ha;Kim, Jeong-Tae
    • Proceedings of the KSME Conference
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    • 2000.11a
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    • pp.67-76
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    • 2000
  • Cr-Mo low alloy steels have been used for a long time for pressure vessel due to its excellent corrosion resistance, high temperature strength and toughness. The paper reviewed the latest trends on material development and some problems on Cr-Mo low alloy steel for pressure vessel, such as elevated temperature strength, hardenability, synergetic effect between temper and hydrogen embrittlement, hydrogen attack and hydrogen induced disbonding of overlay weld-cladding.

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Improving Accident Tolerance of Nuclear Fuel with Coated Mo-alloy Cladding

  • Cheng, Bo;Kim, Young-Jin;Chou, Peter
    • Nuclear Engineering and Technology
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    • v.48 no.1
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    • pp.16-25
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    • 2016
  • In severe loss of coolant accidents (LOCA), similar to those experienced at Fukushima Daiichi and Three Mile Island Unit 1, the zirconiumalloy fuel claddingmaterials are rapidlyheateddue to nuclear decay heating and rapid exothermic oxidation of zirconium with steam. This heating causes the cladding to rapidly react with steam, lose strength, burst or collapse, and generate large quantities of hydrogen gas. Although maintaining core cooling remains the highest priority in accident management, an accident tolerant fuel (ATF) design may extend coping and recovery time for operators to restore emergency power, and cooling, and achieve safe shutdown. An ATF is required to possess high resistance to steam oxidation to reduce hydrogen generation and sufficient mechanical strength to maintain fuel rod integrity and core coolability. The initiative undertaken by Electric Power Research Institute (EPRI) is to demonstrate the feasibility of developing an ATF cladding with capability to maintain its integrity in $1,200-1,500^{\circ}C$ steam for at least 24 hours. This ATF cladding utilizes thin-walled Mo-alloys coated with oxidation-resistant surface layers. The basic design consists of a thin-walled Mo alloy structural tube with a metallurgically bonded, oxidation-resistant outer layer. Two options are being investigated: a commercially available iron, chromium, and aluminum alloy with excellent high temperature oxidation resistance, and a Zr alloy with demonstratedcorrosionresistance.Asthese composite claddings will incorporate either no Zr, or thin Zr outer layers, hydrogen generation under severe LOCA conditions will be greatly reduced. Key technical challenges and uncertainties specific to Moalloy fuel cladding include: economic core design, industrial scale fabricability, radiation embrittlement, and corrosion and oxidation resistance during normal operation, transients, and severe accidents. Progress in each aspect has been made and key results are discussed in this document. In addition to assisting plants in meeting Light Water Reactor (LWR) challenges, accident-tolerant Mo-based cladding technologies are expected to be applicable for use in high-temperature helium and molten salt reactor designs, as well as nonnuclear high temperature applications.

Understanding the role of hydrogen on creep behaviour of Zircaloy-4 cladding tubes using nanoindentation

  • Suman, Siddharth
    • Nuclear Engineering and Technology
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    • v.52 no.9
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    • pp.2041-2046
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    • 2020
  • The present article investigates the influence of hydrogen concentration on the creep performance of cold-worked stress-relieved unirradiated Zircaloy-4 cladding tube using nanoindentation technique. The as-received Zircaloy-4 tube is hydrided to the concentrations of 600 ppm and 900 ppm using gaseous hydrogen charging method. Constant load indentation creep tests are performed for a dwell period of 600 s in the temperature range of 300℃-500 ℃ at 1000 μN, 2000 μN, and 3000 μN. The impact of hydrogen is evaluated in terms of steady state power law creep exponent and activation energy. The power law creep exponent decreases with increase in hydrogen concentration, however, it remains fairly constant with increase in temperature up to 500 ℃. Moreover, activation energy too decreases significantly with increase in hydrogen concentration. The mean stress exponent and activation energy are found to be 3.58 and 28.67 kJ/mol, respectively, for as-received sample.

FUEL BEHAVIOR UNDER LOSS-OF-COOLANT ACCIDENT SITUATIONS

  • CHUNG HEE M.
    • Nuclear Engineering and Technology
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    • v.37 no.4
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    • pp.327-362
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    • 2005
  • The design, construction, and operation of a light water reactor (LWR) are subject to compliance with safety criteria specified for accident situations, such as loss-of-coolant accident (LOCA) and reactivity-initiated accident (RIA). Because reactor fuel is the primary source of radioactivity and heat generation, such a criterion is established on the basis of the characteristics and performance of fuel under the specific accident condition. As such, fuel behavior under accident situations impact many aspects of fuel design and power generation, and in an indirect manner, even spent fuel storage and management. This paper provides a comprehensive review of: the history of the current LOCA criteria, results of LOCA-related investigations on conventional and new classes of fuel, and status of on-going studies on high-burnup fuel under LOCA situations. The objective of the paper is to provide a better understanding of important issues and an insight helpful to establish new LOCA criteria for modem LWR fuels.

Effect of Flaw Characterization on the Structural Integrity Evaluation Under Pressurized Thermal Shock (가압열충격 사고시 결함 이상화 방법이 구조물 건전성 평가에 미치는 영향)

  • Kim, Jin-Su;Choe, Jae-Bung;Kim, Yeong-Jin;Park, Yun-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.2
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    • pp.275-282
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    • 2001
  • The reactor pressure vessel is usually cladded with stainless steel to prevent corrosion and radiation embrittlement. Number of subclad cracks may be found during an in-service-inspection due to the presence of cladding. It is specified, in ASME Sec. XI, that a subclad crack is characterized as a surface crack when the thickness of the clad is less than 40% of the crack depth. This condition is provided to keep the crack integrity evaluation conservative. In order to refine the fracture assessment procedures for such subclad cracks under a pressurized thermal shock condition, three dimensional finite element analyses are applied for various subclad cracks existing under cladding. A total of 36 crack geometries are analyzed, and the results are compared with those for surface cracks. The resulting stress intensity factors for subclad cracks are 6 to 44% less than those for surface cracks. It is proven that the flaw characterization condition as specified in ASME Sec. XI can be overly conservative for some subclad cracks.

Spent fuel simulation during dry storage via enhancement of FRAPCON-4.0: Comparison between PWR and SMR and discharge burnup effect

  • Dahyeon Woo;Youho Lee
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4499-4513
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    • 2022
  • Spent fuel behavior of dry storage was simulated in a continuous state from steady-state operation by modifying FRAPCON-4.0 to incorporate spent fuel-specific fuel behavior models. Spent fuel behavior of a typical PWR was compared with that of NuScale Power Module (NPMTM). Current PWR discharge burnup (60 MWd/kgU) gives a sufficient margin to the hoop stress limit of 90 MPa. Most hydrogen precipitation occurs in the first 50 years of dry storage, thereby no extra phenomenological safety factor is identified for extended dry storage up to 100 years. Regulation for spent fuel management can be significantly alleviated for LWR-based SMRs. Hydride embrittlement safety criterion is irrelevant to NuScale spent fuels; they have sufficiently lower plenum pressure and hydrogen contents compared to those of PWRs. Cladding creep out during dry storage reduces the subchannel area with burnup. The most deformed cladding outer diameter after 100 years of dry storage is found to be 9.64 mm for discharge burnup of 70 MWd/kgU. It may deteriorate heat transfer of dry storage by increasing flow resistance and decreasing the view factor of radiative heat transfer. Self-regulated by decreasing rod internal pressure with opening gap, cladding creep out closely reaches the saturated point after ~50 years of dry storage.

Investigation of a best oxidation model and thermal margin analysis at high temperature under design extension conditions using SPACE

  • Lee, Dongkyu;No, Hee Cheon;Kim, Bokyung
    • Nuclear Engineering and Technology
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    • v.52 no.4
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    • pp.742-754
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    • 2020
  • Zircaloy cladding oxidation is an important phenomenon for both design basis accident and severe accidents, because it results in cladding embrittlement and rapid fuel temperature escalation. For this reason during the last decade, many experts have been conducting experiments to identify the oxidation phenomena that occur under design basis accidents and to develop mathematical analysis models. However, since the study of design extension conditions (DEC) is relatively insufficient, it is essential to develop and validate a physical and mathematical model simulating the oxidation of the cladding material at high temperatures. In this study, the QUENCH-05 and -06 experiments were utilized to develop the best-fitted oxidation model and to validate the SPACE code modified with it under the design extension condition. It is found out that the cladding temperature and oxidation thickness predicted by the Cathcart-Pawel oxidation model at low temperature (T < 1853 K) and Urbanic-Heidrick at high temperature (T > 1853 K) were in excellent agreement with the data of the QUENCH experiments. For 'LOCA without SI' (Safety Injection) accidents, which should be considered in design extension conditions, it has been performed the evaluation of the operator action time to prevent core melting for the APR1400 plant using the modified SPACE. For the 'LBLOCA without SI' and 'SBLOCA without SI' accidents, it has been performed that sensitivity analysis for the operator action time in terms of the number of SIT (Safety Injection Tank), the recovery number of the SIP (Safety Injection Pump), and the break sizes for the SBLOCA. Also, with the extended acceptance criteria, it has been evaluated the available operator action time margin and the power margin. It is confirmed that the power can be enabled to uprate about 12% through best-estimate calculations.

Assessment of $13{\sim}19%Cr$ Ferritic Oxide Dispersion Strengthened Steels for Fuel Cladding Applications

  • Lee, J.S.;Kim, I.S.;Kimura, A.;Choo, K.N.;Kim, B.G.;Choo, Y.S.;Kang, Y.H.
    • Proceedings of the Korean Nuclear Society Conference
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    • 2004.10a
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    • pp.911-912
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    • 2004
  • 1. Cathodic hydrogen charging considerably reduced the tensile ductility of ODS steels and a 9Cr-2W RMS. The hydrogen embrittlement of ODS steels was strongly affected by specimen sampling orientation, showing significant embrittlement in the T-direction. This comes from the microstructural anisotropy caused by elongated grains of ODS steels in L-direction. 2. The ODS steels contained a higher concentration of hydrogen than 9Cr-2W RMS at the same cathodic charging condition, and the critical hydrogen concentration required to transition from ductile to brittle fracture was in the range of $10{\sim}12$ wppm, which approximately 10 times larger than that of a 9Cr-2W martensitic steel. 3. The ODS steels showed a typical ductile to brittle transition behavior and it strongly depended on the specimen sampling direction, namely L- and T-direction. In T-direction, the SP-DBTT was about 170 L, irrespective of the ODS materials, and L-direction showed a lower SP-DBTT than that of T-direction.

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A Study on the Integrity Evaluation Method of Subclad Crack Under Pressurized Thermal Shock (가압열충격 사고시 클래드 하부균열 안전성 평가 방법에 관한 연구)

  • Kim, Yeong-Jin;Kim, Jin-Su;Gu, Bon-Geol;Choe, Jae-Bung;Park, Yun-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.7
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    • pp.1139-1146
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    • 2001
  • The reactor pressure vessel(RPV) is usually cladded with stainless steel to prevent corrosion and radiation embrittlement, and a number of subclad cracks have been found during an in-service-inspection. These subclad cracks should be assured for a safe operation under normal conditions and faulted conditions such as pressurized thermal shock(PTS). Currently available integrity assessment procedure for an RPV, ASME Code Sec. XI, are built on the basis of linear fracture mechanics (LEFM). In PTS condition, however, thermal stress and mechanical stress give rise to high tensile stress at the cladding and elastic-plastic behavior is expected in this area. Therfore, ASME Code Sec. XI is overly conservative in assessing the structural integrity under PTS condition. In this paper, the fracture parameter (stress intensity factor, K, and RT(sub)NDT) from elastic analysis using ASME Sec. XI and finite element method were validated against 3-D elastic-plastic finite element analyses. The difference between elastic and elastic-plastic analysis became significant with increasing crack depth. Therfore, it is recommended to perform elastic-plastic analysis for the accurate assessment of subclad cracks under TPS which causes plastic deformation at the cladding.