• 전자공학회논문지S
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• 제35S권10호
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• pp.42-51
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• 1998

본 논문은 CL (ConnectionLess) 가입자와 CL 서버간, CL 서버간, 그리고 종단간 CL가입자간 궤한 루프와 CL서버의 헤더 변환 테이블을 이용하여CL 중첩망의 폭주 제어 방안을 제안한다. ITU-T(International Telecommunication Union-Telecommunication)에 의하여 정의된 CBDS(Connectionless Broadhand Data Service)을 위한 CL 중첩망은 프레임을 라우팅해 주는 CL 서버와 CL 가입자와 CL서버 또는 CL 서버를 연결해주는 링크들로 구성된다. 이와 같은 CL 중첩망에서, 두 종류의 폭주, 즉. CL 링크 폭주와 CL 서버폭주가 일어날 수 있다. 본 논문에서 두 종류의 폭주를 해결할 수 있는 방안을 제시한다. 링크-바이-링크 방법[18]은 CL가입자와 CL서버간 또는 CL 서버간 ATM 계층의 ABR(Available Bit Rate) 궤환 루프와 CL 서버의 헤더 변환 테이블을 이용한다. 그러나 이 방법은 출력 가상 채널의 폭주 발생시 링크를 통해 전송되는 모든 트래픽에 영향을 주게 되어 폭주에 관여하지 않은 트래픽에게도 영향을 주어 이 트래픽이 출력되는 출력 가상 채널의 링크 이용도가 떨어지게 된다. 이와 같은 단점을 보완하기 위하여 본 논문에서 제한한 하이브리드 방법은 링크-바이-링크 방법의 ABR 궤환 루프, CL 계층의 종단의 CL 가입자간 궤환 루프, 그리고 헤더 변환 테이블을 이용한 폭주 상태표를 이용한다. 이 방안은 링크-바이-링크 루프와 헤더 변환 테이블을 이용하여 폭주에 즉시 대처하고, 다음에 종단간 루프를 이용하여 실제 폭주에 관여한 CL 가입자의 전송속도를 조절하는 것이다.

• Nuclear Engineering and Technology
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• 제49권8호
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• pp.1778-1782
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• 2017

The interaction of $NpO^+_2$ with $Cl^-$ was studied using visible-near-infrared spectroscopy in $NaCl-Ca-Cl_2-NaClO_4$, $NaCl-NaClO_4$, and $CaCl_2-NaClO_4$ solutions with ionic strength (I) of 6M. The spectra of $NpO^+_2$ around 980 nm varied with $Cl^-$ concentration in the $NaCl-CaCl_2-NaClO_4$ and $NaCl-NaClO_4$ solutions at [$Cl^-$] ${\geq}3.5M$, but not in the $CaCl_2-NaClO_4$ solution. Assuming the 1:1 interaction between $NpO^+_2$ and $Cl^-$, the apparent equilibrium constants at I = 6M were evaluated. The presence of $Ca^{2+}$ was found to destabilize overall interaction between $NpO^+_2$ and $Cl^-$. The observations were consistent with the density functional theory calculation.

• Bulletin of the Korean Chemical Society
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• 제5권1호
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• pp.3-16
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• 1984

The effect of solvent on the dipole moments for (chloromethyl) stannanes has been investigated by applying EHT calculation for the isomers of trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ and $Cl_n$Sn(Ⅳ) $(CH_2Cl)_{4-n}$, octahedral Sn(Ⅳ)$Cl_42X$ and $Cl_nSn$(Ⅳ)$(CH_2Cl)_{4-n}$ 2X type complexes in dioxane and ethylacetate solutions (X: dioxane or ethylacetate). For Sn(Ⅳ)$Cl_4$ in dioxane solution, the calculated dipole moment for the trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ type complex [isomer (b)] is closer to the experimental dipole moment than octahedral Sn(Ⅳ)$Cl_4X$2X type complexes. This calculated dipole moment suggests that Sn(Ⅳ)$Cl_4X$ may have the trigonal bipyramidal structure in dioxane solution. However, the calculated dipole moment for octahedral $Cl_3$Sn(Ⅳ) ($CH_2$Cl)2X type complex [Isomer (d)], ClSn(Ⅳ)(CH2Cl)32X type complex [Isomer(k)] and Cl2Sn(Ⅳ)(CH2Cl)22X type complex [Isomer(h)] are closer to the experimental dipole moments than other isomers for octahedral complexes and trigonal bipyramidal complexes. Such theoretical results indicate that $Cl_3Sn$(Ⅳ )($CH_2Cl$), ClSn(Ⅳ)$(CH_2Cl)_3$ and $Cl2Sn$(Ⅳ)$(CH_2Cl)_2$ complexes may have octahedral structures, Isomer(d), (k) and (h) in ethylacetate solution, respectively.

• Korean Chemical Engineering Research
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• 제44권3호
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• pp.259-264
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• 2006

염화반응에 의한 $TaCl_5$의 제조에서 반응생성물 중 $NbCl_5$, $TiCl_4$, $FeCl_2$ 등이 주요 불순물로 존재하게 된다. $TaCl_5$와 $NbCl_5$는 증류나 수소 환원법에 의해 쉽게 분리가 되므로, 반응생성물에서 $TaCl_5/NbCl_5$ 혼합물을 99.9％ 이상 순도로 분리하기 위해 2기의 연속식 증류공정을 사용하여 light한 성분과 heavy한 성분을 제거하는 공정을 구성하였다. 본고에서는 순차배열(direct sequence)과 비 순차배열(indirect sequence)으로서의 두 분리공정에 대한 비교연구를 상용성 화학공정모사기인 Aspen Plus 13.1을 이용해서 전산모사를 수행하였다. 비교결과 순차배열이 비 순차배열에 비하여 초기 장치투자비용이나 운전비용에서 좀 더 우수한 것으로 나타났다.

• 방사성폐기물학회지
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• 제7권4호
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• pp.207-212
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• 2009

본 연구에서는 산화조건하 LiCl-KCl 공융염내에서 란탄계 염화물의 하나인 $PrCl_3$의 열적거동을 살펴보았다. 먼저 산소를 주입하면서 $PrCl_3$의 열중량분석(TGA; thermogravimetric analysis)을 실시하였고, 이 때 얻어진 결과들을 바탕으로, 산소분산법을 이용하여 온도에 따른 LiCl-KCl 공융염내 $PrCl_3$의 산화실험을 수행하였다. $PrCl_3$의 열중량분석 결과에 따르면, 약 $380^{\circ}C$까지 $PrCl_3$에서 염소의 해 리가 급격하게 발생되었고 약 $600^{\circ}C$에서 $PrCl_3$가 PrOCl로 전환되는 반응이 종료되는 것으로 확인되었다. 산소분산법에 의한 LiCl-KCl 공융염내 $PrCl_3$의 열적거동은 산화조건에서 열중량분석시 나타난 $PrCl_3$의 열적거동과 유사하였고, 발생된 PrOCl은 공융염내에서 불용성 화합물로써 바닥으로 침전하였다. 산소분산법에 의한 공융염내 $PrCl_3$의 PrOCl로의 전환은 $650^{\circ}C$ 이상의 온도에서 활발하게 진행되었고, 이 때 발생되는 배기가스내 $Cl_2$의 농도분석을 통해 공융염내 $PrCl_3$의 전환상태를 예측할 수 있을 것으로 판단된다.

• 전자공학회논문지S
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• 제35S권3호
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• pp.29-38
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• 1998

This ppaer suggests a congestion control scheme for CL(ConnectionLess) overlay network using the feedback loops getween CL werver, between CL servers, and the header translation table of CL server. The CL overlay network for CBDS(Connectionless Broadband Data Service) defined by ITU0T(International Telecommunication Union-Telecommunication) consists of CL servers which route frames and links which connect between CL user and CL server or between CL servers. In this CL overlay network, two kinds of congestions, link congestion and CL server congestion, may occur. We suggest a scheme that can solve the congestion using ABR(Available Bit Rate) feedback control loop, the traffic control mechanism. This scheme is the link-by-link method suing the ABR feedback control loops between CL user and CL server or between CL servers, and the header translation table of CL server. As CL servers are always endpoints of ABR connections, the congestion staturs of the CL server can be informed to the traffic sources using RM(Resource Management) cell of the ABR feedback loops. Also CL server knows the trafffic sources making congestion by inspecting the source address field of CLNAP-PDUs(ConnectionLess Network Access Protocol - Protocol Data Units). Therefore this scheme can be implemeted easily using only both ABR feedback control loop of ATM layer and the congestion state table using the header translation table of CL server because it does not require separate feedback links for congestion control of CL servers.

• 동아시아식생활학회지
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• 제4권3호
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• pp.123-133
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• 1994

The ground pork patties were made to add two level of sodium chloride(2.5%, 3.0%) and replace part(50%) of the sodium chloride(NaCl) with either potassium chloride(KCl), magnesium chloride(MgCl2) or calcium chloride(CaCl2). These samples were analyzed for their chemical composition, VBN value, TBA value, microbial counts, and cooking loss. The ground pork with NaCl 2.5% was more desirable in saltness than the ground pork with NaCl 3.0%. Replacing 50% of the sodium chloride with potassium chloride was more desirable to flavor, color, juiciness, and overall acceptability than replacing 50% of the sodium chloride with either magnesium chloride or calcium chloride. The ground pork with NaCl 2.5% or NaCl 1.25% ＋KCI 1.60% had higher pH value than the ground pork with NaCl 1.25% ＋MgCl2 0.67% or NaCl 1.25% ＋CaCl2 0.79%. The ground pork with the ground pork with NaCl 2.5% had lower VBN value than the ground pork with either NaCl 1.25%＋KCI 1.60%, NaCl 1.25% ＋ MgCl2 0.67%, or NaCl 1.25% ＋CaCl2 0.79%. The ground pork with NaCl 1.25% ＋ CaCl2 0.67% had higher increase in total colony count than the ground pork with NaCl 2.5% or NaCl 1.25% ＋ CaCl2 0.79%. Cooking loss of ground pork with NaCl 2.5% was lowest and cooking loss of ground pork with NaCl 1.25% ＋ KCl 1.60% was highest. Potassium chloride would not be a substitute for sodium chloride in cooking loss and total colony count but potassium chloride more closely approximated the sensory properties of sodium chloride than either magnesium chloride or calcium chloride.

• 한국동물번식학회:학술대회논문집
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• 한국동물번식학회 2001년도 춘계학술발표대회
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• pp.79-79
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• 2001

This study was conducted to measure the total protein, DNA, and RNA contents of corpus luteum(CL) in various stages of estrous cycle and pregnancy. CLs were collected from a local slaughterhouse and stages of the estrous cycle of CL were classified as CL1~2, days 1 to 10; CL3(with/without central cavity), days 11 to 17; CL4, days 18 to 20 by method of Ireland et. al(1980) and stages of the pregnancy of CL were classified as P1~3, months 11~3: P4~6, months 4~6; P7~9, months 7~9 of pregnancy. CL3 with/without central cavity(CC) was identified as described by Kastelic et. al.(1990)-CL with CC, more than 2mm in diameter; CL without CC, less than 2mm in diameter. In total protein content, CL3 with CC was significantly lower than P7~9(p<.05). The total DNA content was lower in CL3 with CC than CL3 without CC and CL4(p<.05). In protein : DNA ratio, CL3 with CC was significantly lower than CL4(p<.05), CL3 without CC was significantly lower than P7~9(p<.05), CL4 was significantly lower than CL3 with CC, P1~3 and P7~9(p<.05). No differences were observed in RNA content, protein:RNA ratio, RNA/DNA of CLs in stages of estrous cycle and pregnancy.

• 방사성폐기물학회지
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• 제21권1호
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• pp.55-64
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• 2023

There is a gap in our understanding of the behavior of fused and molten fuel salts containing unavoidable contamination, such as those due to fabrication, handling, or storage. Therefore, this work used calorimetry to investigate the change in liquidus temperature of PuCl₃, having an unknown purity and that had been in storage for several decades. Further research was performed by additions of NaCl, making several compositions within the binary system, and summarizing the resulting changes, if any, to the phase diagram. The melting temperature of the PuCl₃ was determined to be 746.5℃, approximately 20℃ lower than literature reported values, most likely due to an excess of Pu metal in the PuCl₃ either due to the presence of metallic plutonium remaining from incomplete chlorination or due to the solubility of Pu in PuCl₃. From the melting temperature, it was determined that the PuCl₃ contained between 5.9 to 6.2mol% Pu metal. Analysis of the NaCl-PuCl₃ samples showed that using the Pu rich PuCl₃ resulted in significant changes to the NaCl-PuCl₃ phase diagram. Most notably an unreported phase transition occurring at approximately 406℃ and a new eutectic composition of 52.7mol% NaCl-38.7mol% PuCl₃-2.5mol% Pu which melted at 449.3℃. Additionally, an increase in the liquidus temperatures was seen for NaCl rich compositions while lower liquidus temperatures were seen for PuCl₃ rich compositions. It can therefore be concluded that changes will occur in the NaCl-PuCl₃ binary system when using PuCl₃ with excess Pu metal. However, melting temperature analysis can provide valuable insight into the composition of the PuCl₃ and therefore the NaCl-PuCl₃ system.

• 대한화학회지
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• 제37권7호
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• pp.655-661
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• 1993

$[{Mo(NO)_2Cl_2}_n]$ 및 $[{W(NO)_2Cl_2}_n]$의 다핵착물과 킬레이트 리간드인 1,10-phenanthroline을 반응시켜 중성화합물인 $[Mo(NO)_2Cl_2(phen)]$ 과 $[W(NO)_2Cl_2(phen)]$을 각각 합성하였다. 아세톤 용매에서 이 cis-디니트로실 화합물과 과염소산 은(I)을 1:1로 반응시켜 $[Mo(NO)_2(phen)(S)Cl][ClO_4]$ 및 $[W(NO)_2(phen)(S)Cl] [ClO_4]$ (S = acetone)의 양이온 화합물을 얻었다. 이 1가 양이온 화합물과 피라진을 2:1의 양론으로 각각 반응시켜 $[Cl(phen)(NO)_2M(pyz)M'(NO)_2(phen)Cl][C1O_4]_2$(M = Mo, M' = W) 및 $[Cl(phen)(NO)_2M(pyz)M'(NO)2(phen)Cl][C1O4]2$(M = Mo, M' = W)형의 호모 및 헤테로 이핵착물을 합성하였다. 합성한 착물의 특성은 원소분석과, $^1H-,\;^{13}C-$핵자기 공명 및 자외선, 전자흡수스펙트럼을 이용해서 조사하였으며 이들 분광학적 결과로부터 디니트로실 이핵착물의 기하학적 구조가 피라진 다리 리간드를 중심으로 한 $C_{2v}$ 대칭구조임을 확인할 수 있었다.