• Title/Summary/Keyword: Chromism

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The Study on the Luminescent Element of Electro Chromisn in Polyelectrolyte (고분자전해질 Electro Chromism의 발광소자에 관한 연구)

  • 국상훈;고두석
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.2 no.1
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    • pp.65-74
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    • 1988
  • For experiment, we made the electro chemical display element with the NESA glass of display electrode which had low resistance. Density of injection charge, optical density and response characteristics were observed through coloring and achromatizing phemomena in the display element As optical electric chemical reaction was occured in $WO_3$ and cell, it was possible to repeat colouring and achromatizing, and the colouring characteristics was good. And the higher colouring and achromatizing voltage, the lower resistance of electrode and the thinner $WO_3$film was, the better response characteristics. With analyzing phenomena of electro chromism, we could find the possibility of practical use of the coloring and achromatizing element for clock, instrument and guide plate.

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Properties Evaluation of Thermochromic Gel Compounds for Detecting Overheating (과열감지용 열변색 겔성형체의 특성 평가)

  • Kim, Jeong-Hun;Cho, Myoung-Ho;Kang, Young-Goo
    • Fire Science and Engineering
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    • v.22 no.5
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    • pp.61-66
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    • 2008
  • In this research, gel compounds containing thermochromic ingredients were manufactured and evaluated to prevent the transition hazards of fire and explosion, which they are one of the methods for detecting abnormal conditions caused by overheating of special materials early. And also, compounds of viscoelastic and brushing types were manufactured as the kind and content of raw materials, and manufacturing process to enlarge the application for overheat-detecting targets. Test methods were conducted as chromism test, viscosity profile, starting time of thermochromism, and FT-IR analysis. Thermochromic gel materials exhibit chromism properties that can detect abnormal conditions effectively, and then they are possible to various applications.

Synthesis of the photochromic and electrochromic dyes and their sensible properties (I) - Dyeing application with photochromic moiety to the fiber substrate- (광변색성 및 전기변색성 색소의 합성 및 특성(I) -광변색성 특성의 섬유소재에의 응용-)

  • Son Young-A;Park Young-Min;Kim Byung-Soon;Kim Sung-Hoon
    • Textile Coloration and Finishing
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    • v.18 no.2 s.87
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    • pp.24-30
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    • 2006
  • The photosensitive spiroxazine compound and the electrosensitive viologen compound were prepared to examine their practical application feasibilities and behaviors. These dyes represent corresponding chromism effects related to their own characteristics of the dye molecules. Thus, the prepared dyes were characterized and their absorption spectra were also investigated. Besides, an interest on direct spiroxazine exhaustion to the polyamide substrates and its photochromic effects within the fiber molecules were determined. The photochromic reaction on the substrates was clearly observed and its reversible decoloration behaviors responded.

Electrochemical Properties of Diiron Complexes wish Conjugated Chains (공액 사슬을 갖는 철 화합물의 전기화학적 특성)

  • ;Micheal b. Sponsler
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.6
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    • pp.511-517
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    • 2002
  • The complex 1 $([Cp*Fe(CO)_2]_2-(\mu-CH=CH-CH=CH))$ which have butadiene as a bridge were synthesized from $Cp*(CO)_2FeK$ and cis-3,4-dichlorocyclobutene. The derivatives of complex 1 where one or two carbonyl groups are replaced by phosphine ligands have been prepared by photochemical substitution. The new derivatives $([Cp*Fe(L)_2]_2-(\mu-CH=CH-CH=CH))$ where L = $(Ph_2PCH_2CH_2PPh_2)$ and $([Cp*Fe(CO)(L)]_2-(\mu-CH=CH-CH=CH))$ where L : $PPh_3$ have been characterized from $^^1H-$, $^^13C-$,$^^31P-NMR$ and elemental analysis. Obtained complexes have been studied in electrochemical experiment and UV/VIS-near-IR. The mixed-valence radical cation forms of complex 2, 3 species were found to be delocalized as the Class III. Based on the separation of the waves ($\triangle E$ : 0.470 ~ 0.605 V), the efficiency of electronic communication between two metal centers of cation species leading to stabilization relative to neutral species. The phosphine-substitute complexes (2, 3) displays two reversible oxidation waves and oxidation state of metal centers-dependent color change, electrochromism, was observed from yellow to orange and deep blue in methylene chloride.