• Proceedings of the Korean Geotechical Society Conference
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• 1999.10a
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• pp.227-232
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• 1999

In this paper, a laboratory investigation was carried out to estimate the strength improvement of quicklime mixture for the effective use of surplus soils, and the shear strength with curing time was estimated at the content of lime. The effect of strength improvement has been established through the change of lime content with chlorides and sulfates from the samples taken at Samsan region, Ulsan. The test results indicated that the presence of calcium sulphate encouraged the efficiency of lime stabilization, and increased shear strength. Furthermore, it is necessary for inquiring into the relationship between the characteristics of strength and the chemical components.

• Macromolecular Research
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• v.15 no.1
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• pp.17-21
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• 2007

A series of new, vinyl sulfone-containing monomers was prepared by p-aminophenyl vinyl sulfone (1) with various acid chlorides such as adipoly chloride, terephthaloyl chloride and isophthaloyl chloride. Finally, tertiary amine-containing poly(amide-sulfone)s were prepared by the Michael-type addition polymerization using N,N-dimethylethylenediamine (DMEDA), p-phenylenediamine and piperazin. To evaluate the relevant properties for permselective membranes and enzyme substrate, various physical properties such as molecular weight, solubility, quaternization behavior and thermal properties were examined.

• Carbon letters
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• v.4 no.2
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• pp.86-92
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• 2003

A series of micro- and mesoporous activated carbons were prepared from two kinds of phenolic resin using a metal treated chemical activation methodology. $N_2$-adsorption data were used to characterize the surface properties of the produced activated carbons. Results of the surface properties and pore distribution analysis showed that phenolic resin can be successfully converted to micro- and mesoporous activated carbons with specific surface areas higher than 973 $m^2/g$. Activated carbons with porous structure were produced by controlling the amount of metal chlorides ($CuCl_2$). Pore evolvement depends on the amount of additional metal chloride and precursors used. From the SEM and EDX data, copper contents were shown to be most effected by the incremental addition of metal chloride.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10c
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• pp.211-216
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• 1998

Recently the shortage of good aggregate has encouraged the use of sea sand in construction field, and the corrosion damage of the reinforced steel in concrete structures has been increased due to chlorides from sea sand and deicing salt. Therefore, a number of researchs are proceeding to prevent the corrosion of the reinforced steel in concrete, especially in marine environments. This study focused on the effect of corrosion inhibitors to evaluate protection characteristics for mortar specimens containing clorides. Corrosion behaviors have been investigated by half-cell potential measurement, linear polarization method, AC impedance method, and cyclic polarization test after immersing in sea water for 7 years. A possitive effect of a corrosion inhibitor has been obtained.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.771-776
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• 2001

Test results on the deterioration process of concrete under single and combined attacks of chloride penetration have been obtained. After test period of 52 weeks, it is found that the internally penetrated chloride ion contents are less in the single attacks of chloride than the combined attacks of chloride and sulfate. Both the diffusion coefficients and surface chloride concentration derived form the chloride profiles showed a time dependence. Also the performance of fly ash-blended cements was observed to be better than plain cements in retarding chloride attack. However it should be needed that improved chloride diffusion model for the combined deterioration process.

• Proceedings of the Korea Concrete Institute Conference
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• 1994.10a
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• pp.87-92
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• 1994

The main objective of this study is to determine the critical chloride ion concentrations in the pore solutions causing depassivation of steel reinforcement in concrete made with cements of different $C_3A$ contents. Cement pastes with water-ratio of 0.5 were prepared using four cements with $C_3A$ contents of 0.46, 5.97, 9.14, and 9.65 percent. The pastes were allowed to hydrate in sealed containers for 28days and then objected to pore solution expression. The expressed pore fluids were analyzed for chloride and hydroxyl ion concentrations. It was found that the free cholride concentration in the pore solution decreases significantly with an increase in the $C_3A$ content of the cement. With increasing level of chloride addition, although the alsolute amount of bound chloride increase, the ratio of bound to total chlorides decreases.

• Magazine of the Korea Concrete Institute
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• v.4 no.4
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• pp.161-170
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• 1992

근래 들어 철근 콘크리트에 있어서의 철근부식이 관심의 대상이 되고 있는데 그이유는 이 현상이 실제 구조물에서 광범위하게 발생함이 확인되었고 이로 인한 보수비용이 급증하였기 때문이다. 철근의 부식이 처음 거론된 것은 해양구조물과 내화학성 구조물에서였고 최근 들어서는 교량상판, 주차공간등 염기에 노출되어 철근 부식이 우려되는 각 종의 구조물에 광범위하게 그 대책이 연구되기에 이르렀다. 이와같은 철근부식이 제어방법으로는 첫째로 콘크리트의 수밀화를 들 수 있고 다음으로 콘크리트의 표면을 처리하거나 피복두께를 늘이는 방법이 있다. 마지막으로 철근자체에 방청성능을 직접 부여하여 방법에 속하는 에폭시 도포 철근의 기본적인 방청성능을 고찰하기 위해 수행되었다. 연구결과 에폭시 도포철근의 방청성능은 매우 우수함을 발견하였고 앞으로 활용이 기대되고 있다.

• Computers and Concrete
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• v.13 no.1
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• pp.117-133
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• 2014

This study presents a rapid method for determining the steady state migration coefficient of concrete by measuring the electric current. This study determines the steady state chloride migration coefficient using the accelerated chloride migration test (ACMT). There are two stages to obtain the chloride migration coefficient. The first stage, the steady-state condition was obtained from the initial electric current at the beginning of ACMT. The second stage, the average electrical current in the steady state condition was used to determine the steady state chloride migration coefficient. The chloride migration coefficient can be determined from the average steady state current to avoid sampling and analyzing chlorides during the ACMT.

• Journal of the Korean Society of Combustion
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• v.1 no.1
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• pp.31-39
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• 1996

An equilibrium analysis was carried out to determine principal species in the incineration of hazardous waste, which was assumed as a compound of hydrocarbon fuel, chlorine, sulfur, and heavy metals, and their behaviors with variation of temperature, chlorine and sulfur concentrations. Calculated results showed that the most important parameter influencing the principal species was temperature. Chlorine concentration affected on mole fractions of the species, especially at high temperature. Existence of sulfur had a significant effect on the species at low temperature, regardless of surfur concentration. Generally, principal species at high temperature were chlorides and oxides, while the principal species at low temperature were sulfides. As temperature increased, mole fractions of the principal species increased at low temperature, however, mole fractions of some metal species decreased at high temperature.

• Journal of Microbiology and Biotechnology
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• v.23 no.11
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• pp.1610-1616
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• 2013

Endosulfan is a chlorinated pesticide; its persistence in the environment and toxic effects on biota are demanding its removal. This study aims at improving the tolerance of the previously isolated fungus Aspergillus niger (A. niger) ARIFCC 1053 to endosulfan. Released chloride, dehalogenase activity, and released proteins were estimated along with analysis of endosulfan degradation and pathway identification. The culture could tolerate 1,000 mg/ml of technical grade endosulfan. Complete disappearance of endosulfan was seen after 168 h of incubation. The degradation study could easily be correlated with increase in released chlorides, dehalogenase activity and protein released. Comparative infrared spectral analysis suggested that the molecule of endosulfan was degraded efficiently by A. niger ARIFCC 1053. Obtained mass ion values by GC-MS suggested a hypothetical pathway during endosulfan degradation by A. niger ARIFCC 1053. All these results provide a basis for the development of bioremediation strategies to remediate the pollutant under study in the environment.