• Journal of the Korea Concrete Institute
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• v.17 no.4 s.88
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• pp.663-670
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• 2005

The present study concerns the influence of binder type on the chloride-induced corrosion being accompanied by the chloride threshold level (CTL), chloride transport and as their results the corrosion-free lift. Two levels of cement content, $30\%$ PFA and $65\%$ GGBS concrete were employed. It was found that the most dominant factor to the CTL is the entrapped air void content at the steel-concrete interface, irrespective of the chloride binding capacity, binder type and acid neutralisation capacity of cement matrix. The CTL for lower interfacial air void contents was significantly increased up to $1.52\%$ by weight of cement, whereas a same mix produced $0.35\%$ for a higher level of voids. Because of a remarkable reduction in the diffusion fur GGBS concrete, its time to corrosion ranges from 255 to 1,250 days, while the corrosion-free life for control varies from 20 to 199 days sand for $30\%$ PFA concrete from 200 to 331 days.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.497-500
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• 2008

In order to prevent deterioration of reinforced concrete structures exposed to marine environment, performance based durability design than the design by conventional deemed-to-satisfy rule should be concerned. For example, even though chloride threshold level, which is a major parameter for durability design, is defined as a 1.2 $kg/m^3$ in the Korean concrete specification, it shows that the chloride threshold level leads to over design in its real application so that realistic value should be determined for the performance design. In this paper, not only the probabilistic properties of chloride threshold level obtained from published data are taken into account, but also the experimental results of the probabilistic properties using surface chloride content, diffusion coefficient, cover depth are considered in the assessment utilizing the concept of performance based durability design. In computation, the Monte Carlo Simulation (MCS) is used to perform an assessment due to chloride attack for a target submerged tunnel box. This study found that the specification on current chloride threshold level should be modified for more rational and accurate assessment and design.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.801-804
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• 2004

It should be noted that the critical chloride threshold level is not considered to be a unique value for all conditions. This value is dependent on concrete mixture proportions, cement type and constituents, presence of admixtures, environmental factors, steel reinforcement surface conditions, and other factors. In this study, the accelerated corrosion test for reinforcing steel was conducted by electrochemical and sea water-circulated method, respectively and during the test, corrosion monitoring by half cell potential method was carried out to estimate the critical chloride threshold value when corrosion for reinforcing steel in concrete was perceived. For this purpose, lollypop and beam test specimens were made for $31.4\%,\;41.5\%\;and\;49.7\%$ of w/c. respectively and then the accelerated corrosion test for reinforcing steel was executed. It was observed from the test that the time to initiation of corrosion was found to be different with water-cement ratio and the critical chloride threshold value was found to range from 0.91 to $1.27kg/m^3$.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.205-208
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• 2005

The present study surveys the concrete properties-concerned factors influencing the chloride threshold level for steel corrosion in concrete, altogether with supporting experimental works, in particular, chloride binding capacity, buffering capacity, condition of steel-concrete interface and cement replacement. It concluded that the order of the dominance on CTL is such that chloride binding < buffering capacity of cement matrix < physical condition of steel-concrete interface. This is attributed to the fact that calcium hydroxide does not form a continuous layer on the steel surface and that bound chlorides are released at the stage of corrosion initiation.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.245-248
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• 2005

It should be noted that the critical chloride threshold level is not considered to be a unique value for all conditions. This value is dependent on concrete mixture proportions, cement type and constituents, presence of admixtures, environmental factors, steel reinforcement surface. conditions, and other factors. In this study, the accelerated corrosion test for reinforcing steel was conducted by electrochemical and cyclic wet and dry seawater method, respectively and during the test, corrosion monitoring by half cell potential method was carried out to estimate the chloride corrosion threshold value when corrosion for reinforcing steel in concrete was perceived. For this purpose, lollypop and right hexahedron test specimens were made for 31.4$\%$, 41.5$\%$ and 49.7$\%$ of w/c, respectively and then the accelerated corrosion test for reinforcing steel was executed. It was observed from the test that the time to initiation of corrosion was found to be different with water-cement ratio and accelerated corrosion test method, respectively and the chloride corrosion threshold value was found to range from 0.91 to 1.43 kg/$m^{3}$.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.1A
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• pp.75-84
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• 2009

The present study assesses the chloride threshold level for corrosion of steel in concrete by examining the properties of four different binders used for blended concrete in terms of chloride binding, buffering of cement matrix to a pH fall and the corrosion behaviour. As binders, ordinary Portland cement (OPC), 30% pulverised fuel ash (PFA), 60% ground granulated blast furnace slag (GGBS) and 10% silica fume (SF) were used in a concrete mix. Testing for chloride binding was carried out using the water extraction method, the buffering of cement matrix was assessed by measuring the resistance to an artificial acidification of nitric acid, and the corrosion rate of steel in mortar with chlorides in cast was measured at 28 days using an anodic polarisation technique. Results show that the chloride binding capacity was much affected by $C_{3}A$ content and physical adsorption, and its order was 60% GGBS>30% PFA>OPC>10% SF. The buffering of cement matrix to a pH fall was varied with binder type and given values of the pH. From the result of corrosion test, it was found that the chloride threshold ranged 1.03, 0.65, 0.45 and 0.98% by weight of cement for OPC, 30% PFA, 60% GGBS and 10% SF respectively, assuming that corrosion starts at the corrosion rate of $0.1-0.2{\mu}A/cm^{2}$. The mole ratio of [$Cl^{-}$]:[$H^{+}$], as a new presentation of the chloride threshold, indicated the value of 0.008-0.009, irrespective of binder, which would be indicative of the inhibitive characteristic of binder.

• Corrosion Science and Technology
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• v.8 no.5
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• pp.171-176
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• 2009

The chloride threshold level (CTL) in mixed concrete containing, ordinary Portland cement (OPC), pulverized fuel ash (PFA) ground granulated blast furnace slag (GGBS), and silica fume (SF) is important for study on corrosion of reinforced concrete structures. The CTL is defined as a critical content of chloride at the steel depth of the steel which causes the breakdown of the passive film. The criterion of the CTL represented by total chloride content has been used due to convenience and practicality. In order to demonstrate a relationship between the CTL by total chloride content and the CTL by free chloride content, corrosion test and chloride binding capacity test were carried out. In corrosion test, Mortar specimens were cast using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.0, 0.2, 0.4, 0.8, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binder. All specimens were cured 28 days, and then the corrosion rate was measured by the Tafel's extrapolation method. In chloride binding capacity, paste specimens were casting using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.1, 0.2, 0.3, 0.5, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binders. At 28days, solution mixed with the powder of ground specimens was used to measure binding capacity. All specimens of both experiments were wrapped in polythene film to avoid leaching out of chloride and hydroxyl ions. As a result, the CTL by total chloride content ranged from 0.36-1.44% by weight of binders and the CTL by free chloride content ranged from 0.14-0.96%. Accordingly, the difference was ranging, from 0.22 to 0.48% by weight of binder. The order of difference for binder is OPC > 10% SF > 30% PFA > 60% GGBS.

• Journal of the Korea Concrete Institute
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• v.20 no.4
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• pp.415-421
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• 2008

Reinforced concrete starts to corrode when the chloride ion concentration which is the sum of included in concrete and penetrated from environments exceeds a certain level of critical chloride concentration. Therefore each country regulates the upper bounds of chloride amount in concrete and the regulations are different for each country due to its circumstances. In this study, the critical threshold chloride content according to unit cement amount is empirically calculated to propose a reasonable regulation method on the chloride amount. As a result, the critical threshold chloride content increases considerably according to cement content and it agrees with the established theories. The present regulations on total chloride amount 0.3 or 0.6 kg chloride ions per $1\;m^3$ of concrete does not reflect the influences of mix design, environmental conditions and etc. So it can be said that it is more reasonable to regulate the critical threshold chloride content by the ratio of chloride amount per unit cement content than by the total chloride content in $1\;m^3$ of concrete.

• Corrosion Science and Technology
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• v.8 no.2
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• pp.74-80
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• 2009

The high alkaline property in the concrete pore solution protects the embedded steel in concrete from corrosion due to aggressive ions attack. However, a continuous supply of those ions, in particular, chlorides altogether with a pH fall in electrochemical reaction on the steel surface eventually depassivate the steel to corrode. To mitigate chloride-induced corrosion in concrete structures, finely grained mineral admixtures, for example, pulverized fuel ash (PFA), ground granulated blast furnace slag (GGBS) and silica fume (SF) have been often advised to replace ordinary Portland cement (OPC) partially as binder. A consistent assessment of those partial replacements has been rarely performed with respect to the resistance of each binder to corrosion, although the studies for each binder were extensively looked into in a way of measuring the corrosion rate, influence of microstructure or chemistry of chlorides ions with cement hydrations. The paper studies the behavior of steel corrosion, chloride transport, pore structure and buffering capacity of those cementitious binders. The corrosion rate of steel in mortars of OPC, 30% PFA, 60% GGBS and 10% SF respectively, with chloride in cast ranging from 0.0 to 3.0% by weight of binder was measured at 7, 28 and 150 days to determine the chloride threshold level and the rate of corrosion propagation, using the anodic polarization technique. Mercury intrusion porosimetry was also applied to cement pastes of each binder at 7 and 28 days to ensure the development of pore structure. Finally, the release rate of bound chlorides (i.e. buffering capacity) was measured at 150 days. The chloride threshold level was determined assuming that the corrosion rate is beyond 1-2 mA/$m^3$ at corrosion and the order of the level was OPC > 10% SF > 60% GGBS > 30% PFA. Mercury intrusion porosimetry showed that 10% SF paste produced the most dense pore structure, followed by 60% GGBS, 30% PFA and OPC pastes, respectively. It was found that OPC itself is beneficial in resisting to corrosion initiation, but use of pozzolanic materials as binders shows more resistance to chloride transport into concrete, thus delay the onset of corrosion.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.201-204
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• 2006

It should be noted that the critical chloride threshold level is not considered to be a unique value for all conditions. This value is dependent on concrete mix proportions, cement type and constituents, presence of admixtures, environmental factors, reinforcement surface conditions, and other factors. In this study, the accelerated corrosion test for reinforcing steel was conducted by electrochemical and cyclic wet and dry seawater method, respectively and during the test, corrosion monitoring by half-cell potential method was carried out to detect the time to initiation of corrosion for individual test specimen. For this purpose, lollypop and right hexahedron test specimens were made for 31%, 42%, and 50% of W/C, respectively, and then the accelerated corrosion test for reinforcing steel was executed. It was observed from the test that the time to initiation of corrosion was found to be different with the water-cement ratio and accelerated corrosion test method, respectively and the critical chloride threshold values were found to range from 0.91 to $1.47kg/m^3$.