• Title/Summary/Keyword: Chloride permeability

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Mechanical and durability properties of self-compacting concrete with blended binders

  • Xie, T.Y.;Elchalakani, M.;Mohamed Ali, M.S.;Dong, M.H.;Karrech, A.;Li, G.
    • Computers and Concrete
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    • v.22 no.4
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    • pp.407-417
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    • 2018
  • Over the past three decades, self-compacting concrete (SCC), which is characterized by its superior rheological properties, has been gradually used in construction industry. It is now recognized that the application of SCC using supplementary cementitious materials (SCM) is highly attractive and promising technology reducing the environmental impact of the construction industry and reducing the higher materials costs. This paper presents an experimental study that investigated the mechanical and durability properties of SCCs manufactured with blended binders including fly ash, slag, and micro-silica. A total of 8 batches of SCCs were manufactured. As series of tests were conducted to establish the rheological properties, compressive strength, and durability properties including the water absorption, water permeability, rapid chloride permeability and initial surface absorption of the SCCs. The influences of the SCC strength grade, blended types and content on the properties of the SCCs are investigated. Unified reactive indices are proposed based on the mix proportion and the chemical composition of the corresponding binders are used to assess the compressive strength and strength development of the SCCs. The results also indicate the differences in the underlying mechanisms to drive the durability properties of the SCC at the different strength grades.

Durability Characteristics of High Performance Shotcrete for Permanent Support of Large Size Underground Space (대형 지하공간의 영구지보재로서 고성능 숏크리트의 내구 특성)

  • Won, Jong-Pil;Kim, Hwang-Hee;Jang, Chang-Il;Lee, Sang-Woo
    • Journal of the Korea Concrete Institute
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    • v.19 no.6
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    • pp.701-706
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    • 2007
  • This study evaluated the durability of high-performance shotcrete mixed in the proper proportions using alkali-free and cement mineral accelerators as a permanent support that maintains its strength for the long term. Durability tests were performed the chloride permeability, repeated freezing and thawing, accelerated carbonation, and the effects of salt environments. Test results showed that all the shotcrete mixes included silica fume had low permeability. In addition, after 300 freeze/thaw cycles, the shotcrete mix had excellent freeze/thaw resistance more than the 85% relative dynamic modulus of elasticity. The accelerated carbonation test results were no effect of accelerator type but, the depth of carbonation was greater in the shotcrete mix containing silica fume. No damage was seen in a salt environments. Therefore, the high performance shotcrete mix proportions used in this study showed excellent durability.

Blood-Brain Barrier Experiments with Clinical Magnetic Resonance Imaging and an Immunohistochemical Study

  • Park, Jun-Woo;Kim, Hak-Jin;Song, Geun-Sung;Han, Hyung-Soo
    • Journal of Korean Neurosurgical Society
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    • v.47 no.3
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    • pp.203-209
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    • 2010
  • Objective : The purpose of study was to evaluate the feasibility of brain magnetic resonance (MR) images of the rat obtained using a 1.5T MR machine in several blood-brain barrier (BBB) experiments. Methods : Male Sprague-Dawley rats were used. MR images were obtained using a clinical 1.5T MR machine. A microcatheter was introduced via the femoral artery to the carotid artery. Normal saline (group 1, n = 4), clotted autologous blood (group 2, n = 4), triolein emulsion (group 3, n = 4), and oleic acid emulsion (group 4, n = 4) were infused into the carotid artery through a microcatheter. Conventional and diffusion-weighted images, the apparent coefficient map, perfusion-weighted images, and contrast-enhanced MR images were obtained. Brain tissue was obtained and triphenyltetrazolium chloride (TTC) staining was performed in group 2. Fluorescein isothiocyanate (FITC)-labeled dextran images and endothelial barrier antigen (EBA) studies were performed in group 4. Results : The MR images in group 1 were of good quality. The MR images in group 2 revealed typical findings of acute cerebral infarction. Perfusion defects were noted on the perfusion-weighted images. The MR images in group 3 showed vasogenic edema and contrast enhancement, representing vascular damage. The rats in group 4 had vasogenic edema on the MR images and leakage of dextran on the FITC-labeled dextran image, representing increased vascular permeability. The immune reaction was decreased on the EBA study. Conclusion : Clinical 1.5T MR images using a rat depicted many informative results in the present study. These results can be used in further researches of the BBB using combined clinical MR machines and immunohistochemical examinations.

Neuroprotective effect of the water extract of Angelicae Gigantis Radix Palva in ischemic stroke rats (허혈성 뇌졸중 흰쥐에서 당귀미 열수추출물의 혈관신생인자 발현 조절을 통한 신경세포 보호작용에 대한 연구)

  • Park, Ki-Ho;Oh, Tae-Woo;Park, Yong-Ki
    • The Korea Journal of Herbology
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    • v.27 no.2
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    • pp.61-67
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    • 2012
  • Objective : Angelica Gigas Nakai is a popular oriental medicine used for the treatment of vascular diseases. The aim of this study is to investigate neuroprotective effect of the water extract of Anelicae Gigantis Radix Palva (AG) in transient middle cerebral artery occlusion (tMCAO)-induced ischemic rats via the regulation of angiogenesis-related molecules. Methods : Sprague-Dawley rats were intraperitoneally administrated with AG water extract at doses of 10, 25, 50 mg/kg body weight after tMCAO (90 min occlusion). reperfusion for 24 hr infarction volumes were measured by 2,3,5-tetrazolium chloride (TTC) staining. Brain tissues were observed neuronal cell injuries by nissl staining, and also brain-blood barrier (BBB) permeability change by evans blue. Expression of vascular endothelial growth factor (VEGF), angiopoietin-1 (Ang-1) and Tie-2 receptor protein in brain tissues was determined by western blot. Results : AG water extract significantly reduced infarction volume in ischemic brains of rats, degradation of neuronal cell, BBB permeability and expression of VEGF protein dose-dependently. Ang-1 protein was increased dose-dependantly, not significantly. Conclusion : This study suggests that AG water extract shows neuroprotective effect by preventing BBB breakdown, with regulating angiogenesis factor VEGF and Ang-1.

Engineering Properties of Sewage Polymer Concrete Culvert (폴리머 콘크리트를 적용한 하수암거의 공학적 특성)

  • Kwon, Seung Jun;Min, Byung Yoon;Park, Sang Soon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.9-17
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    • 2012
  • Concrete sewage culvert shows degradation with time since it is always exposed to various harmful ions, and deterioration of concrete culvert propagates to structural safety problems. After reclamation, maintenance for concrete sewage culvert is very difficult so that high durable and structural performance are essential for the sewage concrete culvert. Recently polymer concrete has been used to improve mechanical properties and durability performance. In this paper, engineering properties are evaluated for sewage culvert made with polymer concrete, and leakage and adhesive strength between joints are evaluated with small-scale models. The polymer sewage culvert shows high compressive strength over 100MPa with low water permeability and chloride penetration. Furthermore, high resistances to chemical and biological attack are evaluated. Through tests for leakage and adhesive, unification of joints is verified with evaluation of no leakage and high adhesive strength. Precast polymer sewage culvert in this paper can be actively used for severe conditions like sewage lines.

Solidification Process of a Binary Mixture with Anisotropy of the Mushy Region (머시영역의 비등방성을 고려한 2성분혼합물의 응고과정)

  • 유호선
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.1
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    • pp.162-171
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    • 1993
  • This paper deals with the anisotropy of the mushy region during solidification process of a binary mixture. A theoretical model which specifies a permeability tensor in terms of pricipal values is proposed. Also, the governing equations are modified into convenient forms for the numerical analysis with the existing algorithm. Some test computations are performed for soeidification of aqueous ammonium chloride solution contained in a square cavity. Results show that not only the present model is capable of resolving fundamental characteristics of the tranport phenomena, but also the anisotropy significantly affects the interdendritic flow structure, i.e., double-diffusive convection and macrosegregation patterns.

A Study on the Methodology to Ensure Long-Term Durability of Low and Intermediate Level Radwaste Disposal Concrete Structure (${\cdot}$저준위 방사성폐기물 처분 콘크리트 구조물의 장기적 내구성 확보를 위한 방안 검토)

  • Kim Young-Ki;Lee Byung-Sik;Lee Yong-Ho
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.211-220
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    • 2005
  • The concrete structure is being considered for the main engineered barrier of low and intermediate level radwaste disposal facility. Concrete of low permeability can minimize infiltration of water and effectively prevent release of nuclide to ecosystem. But if concrete degrades, structural stability of disposal structure will decrease while permeability increase, resulting in increased possibility of nuclide release due to water infiltration. Therefore disposal concrete structure degradation shall be minimized to maintain capacity of nuclide isolation. The typical causes of concrete structure degradation are sulfide attack, reinforcement corrosion due to chloride attack, leaching of calcium hydroxide, alkali-aggregate reaction and repeated freezing-thawing. The common cause of these degradation processes is infiltration of water or adverse chemicals into concrete. Based on the study of these degradation characteristics and mechanisms of concrete structure, the methodology of design and service life evaluation of concrete structure as an engineered barrier are reviewed to ensure its long-term durability.

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Effects of Blend Ratio and Heat Treatment on the Properties of the Electrospun Poly(ethylene terephthlate) Nonwovens

  • Kim Kwan Woo;Lee Keun Hyung;Lee Bong Seok;Ho Yo Seung;Oh Seung Jin;Kim Hak Yong
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.121-126
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    • 2005
  • Semicrystalline poly(ethylene terephthalate) (cPET)/amorphous poly(ethylene terephthalate) with isophthalic acid (aPET) blends with 100/0, 75/25, 50/50, 25/75, and 0/100 by weight ratios were dissolved in a mixture of trifluoroacetic acid (TFA)/methylene chloride (MC) (50/50, v/v) and electrospun via the electrospinning technique. Solution properties such as solution viscosity, surface tension and electric conductivity were determined. The solution viscosity slightly decreased as aPET content increased, while there was no difference in surface tension with respect to aPET composition. The characteristics of the electro spun cPET/aPET blend nonwovens were investigated in terms of their morphology, pore size and gas permeability. All these measurements were carried out before and after heat treatment for various blend weight ratios. The average diameter of the fibers decreased with increasing aPET composition due to the decrease in viscosity. Also, the morphology of the electrospun cPET/aPET blend nonwovens was changed by heat treatment. The pore size and pore size distribution varied greatly from a few nanometers to a few microns. The gas permeability after heat treatment was lower than that before heat treatment because of the change of the morphology.

Evaluation of Concentration Polarization at Feed in the Permeation of VOCs/$N_2$ mixtures through PDMS membrane (VOCs/질소 혼합물 증기투과시 공급액부 경계층에서의 농도분극 분석을 위한 모델식 확립)

  • 염충균;이상학;최정환;이정민
    • Membrane Journal
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    • v.11 no.2
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    • pp.74-82
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    • 2001
  • By using a phenomenological approach, model equations incorporating the resistance-in¬series concept were established to evaluate quantitatively concentration polarization in the boundary layer in feed adjacent to the membrane surface in the vapor permeation and separation of volatile organic compounds (VOCS)/$N_2$ mixture through po]y(dimethylsiloxane) (PDMS) membrane. The vapor permeations of various VOCS/$N_2$ mixtures through PDMS membrane were carried out at various feed flow rates. Chlorinated hydrocarbons, such as, methylene chloride, chlorofonn, 1,2-clichloroethane and 1,1,2-trichloroethane were used as organic vapor. By fitting the model equations to the experimental penneation data. the model parameters were detennined. respectively. Both the mass transfer coefficient of VOC across tbe boundary layer and concentration polarization modulus as a measure of the extent of concentration polarization were eitimated Quantitatively by the mooe1 equations with the determined model parameters. From the analysis on the detennined model parameters, the boundary layer resistance due to the concentration polarization of VOCs component was found to be more significant when the condensability of voe was greater. This study seeks to emphasize the importance of the boundary resistance on the vapor penneation of the vapor/gas mixtures with high permeability and high selectivity towards the minor component VOC.

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Effect of Milled Glass Fibers on Corrosion Resistance of PSC Grout Mortar (초단유리섬유가 PSC 그라우트의 부식저항성능에 미치는 영향)

  • Moon, Do-Young;Kim, Sang-Woon;Kim, Dong-Joo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.6
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    • pp.37-45
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    • 2015
  • In this experimental study, effect of milled glass fibers was investigated on corrosion resistance of PSC grout mortar. In order to check whether the mortar mixture with milled glass fibers satisfy the required properties as a PSC grout, time of flow, bleeding and compressive strength measured. The corrosion resistance were investigated through chloride ion migration test, mortar absorption test and surface resistivity measurement. It is confirmed that all proportions with milled glass fibers have better corrosion resistance than that with only OPC binder. Time of flow was reduced but the bleeding was increased to unacceptable level by using milled glass fibers. Consequently, the mix proportion with milled glass fibers for a PSC grout should be modified to have lower water/binder ratio.