• Journal of the Korean Society of Tobacco Science
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• v.28 no.2
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• pp.83-93
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• 2006

The aim of this study is to develop a simple and rapid field method for the determination of chloride content in tobacco green or cured leaves. To set up a practical process, several factors such as the proper sampling position of each leaf, the size of leaf lamina pieces for blending, the substitution of deionized water fur the extracting solution, 0.1N $HNO_3$, the submerging durations before blending, and the standing times before measuring were studied using flue-cured and burley tobacco with a stable and reproducible Chloride Meter, KRK CL-2Z. From the results, chloride contents of tobacco leaves could be analyzed with the Chloride Meter(CL-2Z) using the suspension of 14 mm diameter leaf disks after soaking in distilled water for 30 min., blending with a mini-blender for 30 seconds. The chloride contents measured in this way showed highly significant correlations with ones by the conventional potentiometric method using an ion meter-chloride electrode and $AgNO_3$ titration. In our method, the procedures such as drying, powdering and weighing samples, and using chemical reagents for extraction (0.1N $HNO_3$) and titration(0.028N $AgNO_3$) could be eliminated. These results suggest that the newly constructed method using the Chloride Meter is more efficient to determine the chloride content of tobacco leave in comparison with the one by the Ion $Meter:AgNO_3$ titration.

• Advances in concrete construction
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• v.10 no.1
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• pp.13-20
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• 2020

Steel corrosion in embedded steel causes a significant durability problems and this usually propagates to structural degradation. Large-scaled concrete structures, PSC (Pre-stressed Concrete) or RC (Reinforced Concrete) structures, are usually constructed with mass concrete and require quite a long construction period. When they are located near to sea shore, chloride ion penetrates into concrete through direct or indirect exposure to marine environment, and this leads durability problems. Even if the structures are sheltered from chloride ingress outside after construction, the chloride contents which have been penetrated into concrete during the long construction period are differently evaluated from the initially mixed chloride content. In the study, chloride profiles in cores extracted from anchorage concrete block in two large-scaled suspension bridge (K and P structure) are evaluated considering the exposure periods and conditions. Total 21 cores in tendon room and chamber room were obtained, and the acid-soluble chlorides and compressive strength were evaluated for the structures containing construction period around 3 years. The test results like diffusion coefficient and surface chloride content from the construction joint and cracked area were also discussed with the considerations for maintenance.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.1077-1080
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• 2008

Material parameters such as surface chloride content, water permeability coefficient, chloride diffusivity and critical chloride content are a substantial key parameter for understanding the durability performance of concrete and its micro-structural densification. Over the past few decades, a considerable number of studies on the durability design for marine concrete structures have been carried out. However, the results are different to each other. In order to establish a consistent durability design system of concrete, it is a precondition to define material parameters, which affect deterioration of concrete due to chloride penetration. Such parameters are surface chloride content, chloride diffusivity, and critical chloride content. Usually these parameters are assumed as temporary constant values or obtained from the experimental results for short term. However, it is necessary to define these parameters reasonably, because these significantly influence the calculation of service life of concrete. In this paper, it is introduced to define material parameters of concrete for chloride diffusion, such as surface chloride content $[Cl]_s$, water permeability coefficient K, chloride diffusivity $D_{Cl}$, critical chloride content $[Cl]_{cr}$. These are expressed as time function considering hydration evolution of hardened cement paste. The definition of the material parameters is a prerequisite to simulate chloride penetration into concrete as time elapsed.

• Korean Journal of Food Science and Technology
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• v.28 no.4
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• pp.707-713
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• 1996

Changes of sodium chloride content in Chinese cabbage were investigated at different conditions. The diffusion rate of sodium chloride into the cabbage increased with increasing the temperature of brine solution. Sodium chloride content of Chinese cabbage at the lower portion of tank was higher than that at the upper position. The more washing and dewatering, the lower sodium chloride content of the cabbage was found. Microstructure pattern of salted cabbage tissue depended upon height of tank. The changed epidermis cell was recovered after several times of washing.

• Journal of the Korea institute for structural maintenance and inspection
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• v.3 no.4
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• pp.163-171
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• 1999

In this study, we executed fundamental experiment to investigate properties of accelerated carbonation with changing chloride content of concrete used sea sand in order to examine durability. So we obtained the results of following properties of mechanics, durability, concrete with sea sand, determined concrete w/C 30%, 40%, 50%, and fine aggregate 40% and changing containing chloride 0, 0.3, 0.6, $0.9kg/m^3$ by the experiment of accelerated neutralization. The results of this study as follows: 1) As result of changing chloride content of concrete used sea sand augmented in stages $0.3kg/m^3$, accelerated carbonation was increased as increment chloride content. The increment depth was decreased as it went long term age. It was shown the chloride content effected increment of carbonation depth in concrete 2) As a result of changing W/C of concrete used sea sand augmented in stages 10% at a time from 30% to 50%, accelerated carbonation depth of concrete was increased as W/C ratio. 3) As the carbonation concrete used sea sand, compressive strength between 8 weeks and accelerated carbonation depth of 1 weeks, 2 weeks, 4 weeks, 8 weeks was inversion proportion.

• Journal of the Korean Wood Science and Technology
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• v.10 no.3
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• pp.133-134
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• 1982

This experiment has been made to investigate the absorption of watersoluble zinc chloride by Pinus densiflora S. et Z. at different moisture content, under soaking process, to decide the optimum content condition for the maximum absorption of zinc chloride by the wood tested and to investigate the concentration of zinc chloride affecting each moisture content of wood. Material was cut in the Dept. of Forest, College of Agr. S.N.U. Suwon, Korea. Sample was divided into sap and heartwood group and cut $2{\times}2{\times}2\;cm$ in size, having exact three dimensions, using the part of D.B.H. The numbers of sample were 20 pieces for each moisture content condition for both sap and heartwood. Especially, the samples were protected from exposure to keep moisture content in green condition. The ranges of moisture content tested were as the table 3 and 4. The conclusions were as follows: 1. With 3% zinc chloride solution, the rate of absorption decreased with the time increased, if the air seasoned Korean red pine (Pinus densiflora S. et Z.) was treated in steeping process. Initial absorption for 30 minutes was more than 50% of total absorpon for 24 hours. 2. Rate of absorption was same under the green condition, while rate of absorption under the moisture content 7 to 30% varied. 3. Although it was not quite proportional change in the absorption with the difference of moisture content, the great change in the absorption occured by seasoning. With exception sap green condition, sapwood twice more permeable than the heartwood in the oven dried condition and it has been observed the nearly same amount of absorption at the moisture content of 7%, 10% and 15% respectively in heartwood. 4. It was better from water in wood from view-point of absorption of zinc chloride solution, but it was difficult practically to obtain the smallest moisture content, and then it was decided that values of allowable moisture content, on the basis of mean absorption, were 15% to 20% in the sapwood, and in the heartwood, 10% to 15%. The mean absorption for each moisture content in the sap and the heartwood were as following. 5. In general, the concentration of zinc chloride after steeping was nearly same between moisture content and sap and heartwood respectively.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.117-122
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• 1999

The antiwashout concrete which is a type of specific concrete is manufactured by using a plenty of superplasticizer with the non-dispersible underwater concrete admixture, and the application of it on construction site is being increased. But when we measure choride ion content by using the potentiographic tester, because it is over total chloride ion content(0.3kg/㎥ under) of Korean Concrete Specification, the claim of construction site is being presented on the quality of antiwashout concrete. Accordingly, hte aim of this study is to verify actual chloride ion content of antiwashout concrete by chloride ion analysis due to chemical admixtures by performance of antiwashout concrete. In conclusion the actual chloride ion content of antiwashout concrete is overestimated by anion($OH^-, SO4^{-2}, S^{-2}, etc) of chemical admixtures, and is proved to be as low as that of ordinary concrete.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.6
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• pp.90-96
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• 2014

The electrical resistivity of concrete can be related to two processes involved in corrosion of reinforcement: initiation (chloride penetration) and propagation (corrosion rate). The resisistivity of concrete structure exposed to chloride indicates the risk of early corrosion damage, because a low resistivity is related to rapid chloride penetration and to high corrosion rate. Concrete resistivity is a geometry-independent material property that describes the electrical resistance, which is the ratio between applied voltage and resulting current in a unit cell. In previous study, it was realized that the resistivity of concrete depended on the moisture content in the concrete, microstructural properties, and environmental attack such as carbonation. The current is carried by ions dissolved in the pore liquid. While some data exist on the relationship between moisture content on electrical resistivity of concrete, very little research has been conducted to evaluate the effect of chloride on the conduction of electricity through concrete. The purpose of this study is to examine and quantify the effect of chloride content on surface electrical resistivity measurement of concrete. It was obvious that chloride content had influenced the resistivity of concrete and the relationship showed a linear function. That is, concrete with chloride ions had a comparatively lower resistivity. Decreasing rate of resistivity of concrete was clear at early time, however, after 50 days resistivity was constant irrespective of chloride concentration. Conclusively, this paper suggested the quantitive solution to depict the electrical resistivity of concrete with chloride content.

• Architectural research
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• v.4 no.1
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• pp.39-44
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• 2002

Recently, the coal-ash production has been increased by increase of consumption of electric power. So it is important to secure a reclaimed land from pollution and develop practical application of coal ash. This is an experimental study to compare and analyze the properties of concrete using high volume of coal ash (including fly ash and bottom ash) as a part of fine aggregate. For this purpose, the mix proportions of concrete according to replacement ratio of coal ash (10, 20, 35, 50%) were selected. And then air content, slump, setting time, bleeding content, chloride content, compressive strength and carbonation test were performed. According to test results, it was found that the bleeding content of concrete using the coal ash decreased according to increase of replacement ratio. And the chloride content of concrete using the bottom ash as a part of fine aggregate increased as the replacement ratio of bottom ash increased, but it is satisfied with the total chloride content of concrete recommended by KCI - $0.3kg/m^3$ below. Also, the compressive strength of concrete using the bottom ash was similar to that of plain concrete(BA 0) after 28days of curing and the carbonation depth of concrete increased as the replacement ratio increased. However, the carbonation depth of concrete using the fly ash decreased as the replacement ratio of fly ash increased.

• Proceedings of the Korea Concrete Institute Conference
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• 1994.10a
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• pp.87-92
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• 1994

The main objective of this study is to determine the critical chloride ion concentrations in the pore solutions causing depassivation of steel reinforcement in concrete made with cements of different $C_3A$ contents. Cement pastes with water-ratio of 0.5 were prepared using four cements with $C_3A$ contents of 0.46, 5.97, 9.14, and 9.65 percent. The pastes were allowed to hydrate in sealed containers for 28days and then objected to pore solution expression. The expressed pore fluids were analyzed for chloride and hydroxyl ion concentrations. It was found that the free cholride concentration in the pore solution decreases significantly with an increase in the $C_3A$ content of the cement. With increasing level of chloride addition, although the alsolute amount of bound chloride increase, the ratio of bound to total chlorides decreases.