• 제목/요약/키워드: Chloride Diffusion Coefficient

검색결과 269건 처리시간 0.027초

철근콘크리트 구조물 염해 내구설계에 있어서 설계확률변수의 민감도 평가 (The Sensitivity Evaluation of Probability Variables to Durability Design of the RC Structures)

  • 박동천;오상균
    • 한국항해항만학회지
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    • 제33권3호
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    • pp.235-240
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    • 2009
  • 해안철근콘크리트 구조물은 해수 또는 비래염분에 의하여 철근이 부식하게 되고 결과적으로 콘크리트에 균열로 발전하여 성능을 다하게 된다. 본 연구에서는 염해에 대한 해안 철근콘크리트 구조물의 내구성능 평가를 위하여 수치해석에 의한 결정론적 방법이 아니라 확률론에 입각한 성능평가를 위하여 확률론적 시뮬레이션 수법을 구축하였다. 시뮬레이션 수법으로는 몬테카를로법이 적용되었으며, 파괴확률에 대한 설계확률변수(표면염화물 농도, 초기 함유 염소이온농도, 철근의 피복두께, 염소이온 확산계수) 및 각각의 변동계수의 영향을 평가하였다. Fick의 확산방정식을 이용한 해석결과, 해안에서의 거리의 차 및 확산계수의 차에 의한 영향은 컸으며 상대적으로 변동계수의 영향은 그다지 높지 않다는 것을 알 수 있었다.

염소이온의 확산계수와 콘크리트의 기초물성과의 관계 (Relationship between Chloride Diffusivity and the Fundamental Properties of Concrete)

  • 최두선;최재진
    • 한국방재학회 논문집
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    • 제9권1호
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    • pp.15-20
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    • 2009
  • 해양환경 하에 건설되는 콘크리트구조물은 다양한 염해 환경에 노출되어 있으며, 이중 염소이온의 침투 및 확산으로 인한 콘크리트 중의 철근부식과 화학적 침식 등은 콘크리트구조물의 주요 성능저하 요인으로 지적되고 있다. 따라서 해수 중의 염소이온의 침투 및 확산 메커니즘을 효율적으로 평가하기 위하여 전기화학적 촉진시험으로부터 염소이온의 확산계수를 추정하였다. 또한 콘크리트의 압축강도, 투수공극량 및 염소이온의 침투깊이 등과 염소이온의 확산계수와의 상관관계를 분석하기 위하여 회귀분석을 실시하였다. 본 연구의 시험결과에 의하면, 물-시멘트비 40~60%의 범위에서 보통콘크리트의 염소이온 확산계수는 $2.5{\sim}6.6{\times}10^{-12}m^2/s$ 정도였으며, 염소이온의 확산계수와 콘크리트의 물성과의 상관관계는 선형의 상관관계가 있었다.

고로슬래그미분말 치환 콘크리트의 염화물 침투특성에 관한 연구 (A Study on the Chloride ion Penetration Characteristic of Concrete containing Ground Granulated Blast Furnace Slag)

  • 김현수;지남용
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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    • pp.997-1002
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    • 2001
  • There are two types of chloride in concrete; one is added as concrete materials' chloride when concrete's mixing, and .the other is penetrated from the air and sea water in the sea-shore area. These chlorides penetrate into concrete, and they are accumulated inside the concrete with aging. This study aimed to evaluate the chloride ion penetration resistance of concrete containing GGBFS in the sea-shore area. Therefore, the specimens made with the replacement ratios(0, 0.30, 0.45, 0.60) of GGBFS were put into 3% NaCl solution according to the chloride accelerating test of JCI-SC3, and then investigated the weight changes, compressive strength, chloride ion with the depths of the specimens by aging. The result is that the diffusion coefficient of chloride ion is decreased with the increase of replacement ratios when compared to OPC

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염해환경 콘크리트 구조물의 확률론적 내구성 해석 (A Probability-Based Durability Analysis of Concrete Structures in Chloride Containing Environments)

  • 권기준;김동백;정상화;채성태
    • 한국안전학회지
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    • 제22권3호
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    • pp.51-56
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    • 2007
  • In recent years, many research works have been carried out in order to obtain a more controlled durability and long-term performance of concrete structures in chloride containing environments. In particular, the development of new procedures for probability-based durability analysis/design has proved to be very valuable. Although there is still a lack of relevant data, this approach has been successfully applied to some new concrete structures. In this paper, the equation used for modelling of the chloride penetration was based on Fick's Second Law of Diffusion in combination with a time dependent diffusion coefficient. The probability analysis of the durability performance was performed by use of a Monte Carlo Simulation. The procedure was applied to an example based on limited data gathered in this country. The influences of each parameter on the durability of concrete structures are studied and some comments for durability design are given. The new procedure may be very useful in designing an important concrete structures in chloride containing environments. Also it may help to predict the service life of concrete structures under a given probability of failure.

기능성 방청혼화제 혼입율 변화에 따른 모르타르의 방청성능 평가 (Evaluation of anti-rust properties of mortar with functionality anti-rust agent)

  • 김상섭;이명호;윤원근;장덕배;한민철;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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    • pp.104-105
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    • 2014
  • In this study, fundamental properties of mortar with the variation of dosage of anti-rust agent has been tested to evaluate the effect of the anti-rust agent. Dosage of anti-rust agent was fixed as 0,3,6,9%, respectively. The variation of the flow, compressive strength and diffusion speed of chloride ion has been tested to evaluate the effect of the anti-rust agent. Results showed that flow has been smally increased. For the compressive strength, compressive strength increased with the increase of dosage of agent. For the diffusion speed of chloride, the speed decreased with the increase of dosage of the anti-rust agent. For the overall consideration, it could be identified that when the dosage of anti-rust agent was fixed as 3-6%, the mortar showed the optimum performances.

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Effect of Wet Curing Duration on Long-Term Performance of Concrete in Tidal Zone of Marine Environment

  • Khanzadeh-Moradllo, Mehdi;Meshkini, Mohammad H.;Eslamdoost, Ehsan;Sadati, Seyedhamed;Shekarchi, Mohammad
    • International Journal of Concrete Structures and Materials
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    • 제9권4호
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    • pp.487-498
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    • 2015
  • A proper initial curing is a very simple and inexpensive alternative to improve concrete cover quality and accordingly extend the service life of reinforced concrete structures exposed to aggressive species. A current study investigates the effect of wet curing duration on chloride penetration in plain and blended cement concretes which subjected to tidal exposure condition in south of Iran for 5 years. The results show that wet curing extension preserves concrete against high rate of chloride penetration at early ages and decreases the difference between initial and long-term diffusion coefficients due to improvement of concrete cover quality. But, as the length of exposure period to marine environment increased the effects of initial wet curing became less pronounced. Furthermore, a relationship is developed between wet curing time and diffusion coefficient at early ages and the effect of curing length on time-to-corrosion initiation of concrete is addressed.

The Effects of Cement Alkalinity upon the Pore Water Alkalinity and the Chloride Threshold Level of Reinforcing Steel in Concrete

  • ;;김기준
    • 콘크리트학회논문집
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    • 제16권4호
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    • pp.549-555
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    • 2004
  • Cement of three alkalinities (equivalent alkalinities of 0.36,0.52 and 0.97) was employed in fabricating a set of classical G109 type specimens. To-date, these have been subjected to a one week wet-one week dry cyclic pending using 15 w/o NaCl solution. At the end of the dry period, potential and macro-cell current were measured to indicate whether the top reinforcing steel was in the passive or active state. Once this bar became active, the specimen was autopsied and the extent of corrosion was documented. Subsequent to visual inspection, concrete powder samples were collected from the upper region of the top rebar trace; and at a certain times concrete cores were taken from non-reinforced specimens. Using these, determinations were made of (1) critical chloride concentration for corrosion initiation ($Cl_{th}^-$), (2) effective chloride diffusion coefficient ($D_e$), and (3) pore water alkalinity ($[OH^-]$). The pore water alkalinity was strongly related to the alkali content of cement that was used in the mix. The chloride concentration, ($Cl^-$), was greater at active than at passive sites, presumably as a consequence of electro migration and accumulation of these species at active site subsequent to corrosion initiation. Accordingly, ($Cl^-$) at passive sites was considered indicative of the threshold concentration fur corrosion initiation. The $Cl_{th}^-$ was increased with increasing Time-to-corrosion ($T_i$). Consequently, the HA(High Alkalinity) specimens exhibited the highest $Cl_{th}^-$ and the NA(Normal Alkalinity) was the least. This range exceeds what has previously been reported in North America. In addition, the effective diffusion coefficient, $D_e$, was about 40 percent lower for concrete prepared with the HA cement compared to the NA and LA(Low Alkalinity) ones.

제설제 살포에 따른 콘크리트 포장의 염화물 침투특성 (Characteristics of Chloride Penetration due to Sprinkle of the Deicing Salt on the Concrete Pavement)

  • 박진호;김명유;양은익;이성태;박해균
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.475-478
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    • 2005
  • Deicing salt has been generally used for traffic safety in winter, and the amount is increasing every year. However, deicing salt may induce the decrease of bond strength, surface scaling, and environmental pollution, etc. the purpose of this paper is to suggest the fundamental data on safety and durability for concrete structures through the estimation of chloride concentration profile and chloride diffusion coefficient. According to the test results, the critical chloride concentration($0.9\~1.2kg/m^3$)was measured at depth $23\~30mm$, and the limit chloride concentration($0.3kg/m^3$)was reached to depth 40mm. Also the surface chloride amount indicates 3.45kg per concrete unit weight, and the results showed the possibility of corrosion by deicing salt penetration.

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변색법을 활용한 해양 콘크리트 구조물의 염해평가 (Evaluation on Chloride Attack by Colormetric Method in Marine Concrete Structures.)

  • 박진호;김명유;곽상윤;양은익;박해균
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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    • pp.181-184
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    • 2005
  • When concrete structures are exposed under marine condition for a long time, the steel in concrete is corroded due to the ingression of chlorides in the seawater. Because the damages of corrosion resulting from the chloride ion are very serious, many researches have been performed. However evaluation on chloride attack of concrete structures are not fully examined, recently. Therefore, the objective of this paper is to study the applicability of colormetric method. For the purpose of this, reaction mechanism of colormetric method were investigated, and the colormetric method is applied for marine concrete structures. According to the test results, the diffusion coefficient by colormetric method is not so different to the value of chloride concentration profile test. It is confirmed that the colormetric method is useful tool for estimating the chloride of concrete structures in situ. The average chloride amount of colored parts indicates 0.9kg/$m^{3}$ per concrete unit weight.

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