• Title/Summary/Keyword: Chiral hydroxyldiamides

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Synthesis of Novel Chiral Diamino Alcohols and Their Application in Copper-Catalyzed Asymmetric Allylic Oxidation of Cycloolefins

  • Faraji, Laleh;Samadi, Saadi;Jadidi, Khosrow;Notash, Behrouz
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.1989-1995
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    • 2014
  • The small library of new enantiomerically pure (S,S)-diamino alcohols 1 and their hydroxyldiamide precursors 2 were conveniently synthesized on a gram scale from inexpensive and commercially chiral pool amino acids. The catalytic and induced asymmetric effects of the chiral ligands 1 in the asymmetric allylic oxidation of cycloolefins were investigated.