• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.433-438
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• 2011

In this study, effects of temperature, NSR, and oxygen concentration on the $NO_x$ removal efficiency of an SNCR process were investigated experimentally as well as numerically using CHEMKIN-II program. The NO removal efficiency increased with the reactor temperature under oxygen-free condition, whereas when the oxygen concentration was 4%, the NO removal efficiency showed a maximum value at $900{\sim}950^{\circ}C$. The pressure of oxygen was shown to enhance the NO removal at low temperature. Regardless of the oxygen concentration, the NO removal efficiency increased with NSR. The temperature and NSR-dependencies of the NO removal efficiency predicted by CHEMKIN-II simulations were similar to that of the experimental results.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.105-106
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• 2012

This study is numerical analysis about optimal conditions of GDICI (gasoline direct injection compression ignition) engine operation using intake preheating. Numerical modeling was performed by using the KIVA-3V Release2 code integrated Chemkin chemistry solver II. For validation of numerical model, experiments were performed on a single-cylinder engine. Throughout the numerical simulations under variable conditions, the ranges of optimal conditions were found.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.377-380
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• 2005

A study of ignition characteristics of cracked JP-7 fuel with both oxygen and air has been conducted over a wide range of pressures (1-20 atm), temperatures (1200-2000 K), and equivalence ratios (0.5-1.5). Correlations of ignition delay, of the form, $\tau=Aexp(E/RT)[F]^{a}[O_2]^{b}$ are established using the Chemkin-II package and least square analysis. The effect of $C_3$ hydrocarbons in cracked JP-7 fuel is examined by comparing the ignition delays for two different cracked compositions. A comparison for ignition delay is also made with the experimental results obtained by injecting liquid JP-7 fuel in air using a shock tube apparatus.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.89-92
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• 2004

This work describes a model development and numerical simulation of detailed combustion mechanisms of RDX/GAP/BTIN propellants. The analysis is based on the conservation equations of mass, energy, and species concentrations for both the condensed and gas phases, and takes into account finite-rate chemical kinetics and variable thermophysical properties. The model has been applied to study the combustion wave structures and burning characteristics of RDX/GAP/BTIN propellants over a broad range of pressures. Reasonably good agreement is achieved between the calculated and measured burning rate at atmospheric pressure. But the model calculation does not result in dark zone experimentally observed.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.109-112
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• 2015

This article describes a cellular instability and laminar burning velocity of simulated synthetic natural gas(SNG) including 3% hydrogen. In this study, experimental apparatus is employed using cylindrical bomb combustor, and investigation is carried out with high speed camera and Schlieren system. The cellular instability is caused by the buoyancy, hydrodynamic instability. Unstretched burning velocity can be determined by extrapolated stretch rate of zero point from measured results. These results were also compared with numerical calculation by Chemkin package with GRI 3.0, USC-II, WANG, C3 Fuel mechanism. As an experimental conditions, equivalence ratios was adjusted from 0.8 to 1.3. From results of this work, the one was found that the cellular instability has occurred by effect of thermal expansion rate and flame thickness. As the other results, unstretched laminar burning velocity was best coincided with GRI 3.0 mechanism.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.748-757
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• 2023

Numerical analysis was conducted to confirm the characteristics of extinction behavior in NH₃/CH₄ counterflow symmetrical flames. Numerical simulations were run on CHEMKIN-PRO, using the OPPDIF code, with Okafor's mechanisms, which had the lowest error rate compared to Colson's experimental data in the our previous part I study. The chemical interactions of merged flames were examined by analyzing the production rate of major chemical species and key radicals with the volume fractional percentage of ammonia and global strain rate. The interaction phenomenon of the flames could be identified by observing the main chemical reaction path of the merged flames at the stagnation plane.

• Journal of the Korean Society of Combustion
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• v.10 no.3
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• pp.10-16
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• 2005

Detailed flame structures of the counterflow flames of $CH_4/Air$ formed with $CO_2$ and $H_2O$ addition are studied numerically. The detailed chemical reactions are modeled by using the OPPDIF and CHEMKIN-II code. Only the $CO_2$ and $H_2O$ are assumed to participate in radiative heat transfer while all other gases are assumed to be transparent. The discrete ordinates method(DOM) and the narrow band based WSGGM with a gray gas regrouping technique(WSGGM-RG) are applied for modeling the radiative transfer through non-homogeneous and non-isothermal combustion gas mixtures generated by the counter flow flames. The results compared with the SNB model show that the WSGGM-RG is successful in modeling the counterflow flames with non-gray gas mixture. The numerical results show that the addition of $CO_2$ and $H_2O$ to the oxidant nozzle lowers the peak temperature and the NO concentration in flame.

• 한국연소학회:학술대회논문집
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• 1999.10a
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• pp.117-128
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• 1999

The removal of nitrogen oxides(NOx) from $N_{2}/O_{2}$ gas using a pulsed corona discharge was investigated as a function of the reduced electric field(E/N) and the energy density(J/L). A kinetic model was developed to characterize the chemical reactions taking place in a pulsed corona discharge reactor. The model calculates the fractional concentrations of radical species at each pulse-on period and utilizes the radicals to remove NOx for the subsequent pulse-off period. Electron collision reaction data are calculated using ELENDIF program to solve Boltzmann equation for electron energy distribution function, and the subsequent chemical reactions are calculated using CHEMKIN-II program to solve stiff ODE(ordinary differential equation) problems for species concentrations. The corona discharge energy per pulse and the time-space averaged E/N were obtained by fitting the model to experimental data. The model calculation shows good agreement with the experimental data, and predicts the formation of other species such as $NO_{2}$, $O_{3}$ and $N_{2}O$.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.215-218
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• 2012

In this study, syngas laminar burning velocities with various hydrogen contents were studied using both experimental measurements and kinetic simulations. The laminar burning velocities were measured by the angle method of Bunsen flame configuration and the numerical calculations including burning velocities were made using CHEMKIN Package with USC-Mech II. A large range of syngas mixture compositions such as 10:90%, 25:75%, 50:50%, 75:25% and equivalence ratio from lean condition of 0.5 to rich condition of 5.0 have been conducted. The experimental results of burning velocity were in good agreement with previous other research data and numerical simulation. Also, it was shown that the experimental measurements of laminar burning velocity linearly increased with the increasing of $H_2$ content although the flame speed of hydrogen is faster about ten times than carbon monoxide. This phenomenon is attributed to the rapid production of the hydrogen related radicals such as H and OH at the early stage of combustion, which is confirmed the linear increasing of radical concentrations on kinetic simulation.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.5
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• pp.67-77
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• 2000

Investigated was the effect of propene(C3H6) on the NO-NO2 conversion in dry exhaust gases from lean burn engine using a pulsed corona discharge. A kinetic model was developed to characterize the plasma chemistry in simulated exhausts containing propene. The model uses ELENDIF program to solve Boltzmann equation for electron energy distribution function, and CHEMKIN-II program to solve stiff ODE(ordinary differential equation) problems for species concentrations. The corona discharge energy per pulse and the time-space averaged E/N were obtained by fitting the model to experimental data. The model calculation shows good agreement for NO and NO2 concentrations with the experimental data, and predicts the formation of byproducts such as CH2O, CH3HCO, CO AND CH3NO2 Propene enhances the NOx conversion enormously at lower energy density and the NOx conversion increases with the increase of initial propene and oxygen concentration, and temperature.