• Journal of the Korean Geosynthetics Society
• /
• v.20 no.4
• /
• pp.33-41
• /
• 2021

Feldspar, along with Quartz, are the most frequently produced minerals in Korea; however, the potential value is estimated to be significantly low because of the scarce research on the development and application of material properties, except for their limited use in manufacturing minerals, glass, and paints. In this study, we analyzed the eco-friendly material and reactivity improvement characteristics of weathered feldspar through activation technique. The joint structural features observed on the surface of the weathered feldspar show that the joint arrangements are irregularly distributed, and the cavities are interconnected. Due to the irregularly connected cavities on the surface of weathered feldspar, the reaction area of the weathered feldspar is increased; hence the weathered feldspar is considered as a highly reactive pozzolan material when combined with cement. As a result of applying the thermal, mechanical, and chemical activation techniques to improve the functionality of the weathered feldspar, the cation exchange capacity, density, and uniaxial compression strength characteristics were improved. It is considered that weathered feldspar by these porous characteristics can be used as an eco-friendly construction material with excellent physical and chemical properties.

• Structural Engineering and Mechanics
• /
• v.78 no.4
• /
• pp.473-484
• /
• 2021

Similar to other structures, ultimate strength values showing the maximum load that the structure can resist without damaging has great importance on ships. Therefore, increasing the ultimate strength values will be an important benefit for the structure. Low carbon steels used in ships due to their low cost and good weldability. Improving the ultimate strength values without interfering with the chemical composition to prevent of the weldability properties of these steels would be very beneficial for ships. Grain refinement via severe plastic deformation (SPD) is an essential strengthening mechanism without changing the chemical composition of metallic materials. Among SPD methods, equal channel angular pressing (ECAP) is one of the most commonly used one due to its capacity for achieving bulk ultrafine-grained (UFG) materials. When the literature is examined, it is seen that there is no study about ultimate strength calculation in ships after ECAP. Therefore, the mean purpose of this study is to apply ECAP to a shipbuilding low carbon steel to be able to achieve mechanical properties and investigate the alteration of ship hull girder grillage system's ultimate strength via finite element analysis approach. A fine-grained (FG) microstructure with a mean grain size of 6 ㎛ (initial grain size was 25 ㎛) was after ECAP. This microstructural evolution brought about a considerable increase in strength values. Both yield and tensile strength values increased from 280 MPa and 425 MPa to about 420 MPa and 785 MPa, respectively. This improvement in the strength values reflected a finite element method to determine the ultimate strength of ship hull girder grillage system. As a result of calculations, it was reached significantly higher ultimate strength values (237,876 MPa) compared the non-processed situation (192,986 MPa) on ship hull girder grillage system.

• Journal of the Korean Applied Science and Technology
• /
• v.38 no.6
• /
• pp.1533-1542
• /
• 2021

Eco-friendly polyurethane can be defined as a highly utilized material used in various fields. The various structural properties of the synthesis of isocyanates and polyols provide versatility and customization for use in the manufacturing field. The characteristics of polyurethane vary widely from soft touch coatings to hard building materials like rocks. These mechanical, chemical and biological properties and ease of alignment are drawing tremendous attention not only in the field of research but also in related industries. In order to improve the performance of water-dispersible polyurethane materials, it can be derived through processes such as adjusting the blending of raw materials and adding additives and nanomaterials. This study highlights the basic chemical structure of eco-friendly water-dispersible polyurethane in the fields of medical science, automobiles, coatings, adhesives, paints, textiles, marine industries, wood composite materials, and clothing.

• Advances in concrete construction
• /
• v.15 no.3
• /
• pp.203-213
• /
• 2023

New techniques, technologies, and materials should be used to design and build sports stadiums. Since this century, much progress has been made in covering the roofs of sports stadiums, and the possibility of accurate computer calculation has been provided for stadiums, so by choosing a new structure, we can double the beauty and resistance of these stadiums. A stadium has an excellent and valuable design when its structure, shell, building, materials, and joinery follow a high architectural idea at all levels and scales. This article examines the mechanical performance of polymer cement strength in the construction of football stadiums, along with their structural knowledge in the form of the best examples in the world. Portland cement is one of the most used materials for constructing football stadiums. However, its production requires spending a lot of money, wasting energy, and damaging the environment. Considering the disadvantages in the production and consumption of concrete in different environments, it is necessary to find alternative materials. It should be used with cheaper, simpler technology, abundant primary resources, energy saving, less environmental damage, and better chemical and physical properties in concrete. High-strength concrete technology is considered a new development in the construction industry of concrete structures. In hardened concrete, strength and durability are two main factors, and as the compressive strength of concrete increases, concrete becomes more brittle. As a result, its tensile strength does not increase in proportion to the increase in compressive strength and has less strain tolerance. For this reason, the need to use is evident from the fibers in high-strength concrete. Fibers are used in concrete to increase tensile strength, prevent crack propagation, and significantly increase softness. The increase with the change of these resistances depends on the strength of concrete without fibers, the shape of fibers, and the percentage of fibers. This cement is obtained from the wastes of chemical and petrochemical industries and the wastes from coal combustion, which have the properties mentioned as substitutes for Portland cement.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.11 no.4
• /
• pp.527-534
• /
• 2023

This paper conducted a study on the application of ceramic materials for bridge bearing that can complement the durability of PTFE, a conventional bridge bearing friction material, and exhibit low coefficient of friction and friction behavior without lubricant. The ceramic material was zirconia (ZrO₂), and the friction behavior was evaluated according to the roughness coefficient. The roughness coefficient was divided into 0.8 and 0.027, and the average coefficient of friction was calculated to be 0.16 under 15 MPa surface pressure. Afterward, ceramic was made into friction material and applied to the bridge bearing, and performance comparison with PTFE bridge bearing was conducted through compression test and friction test. In the compression test, the ceramic and PTFE bridge bearing showed ideal compression behavior depending on the load. No fractures or defects were observed in the ceramic bridg bearing, but lubricant loss was observed in the PTFE bridge bearing. The average coefficient of friction of the ceramic bridge bearing analyzed through friction behavior was 0.16. The inherent material properties of the physical and chemical properties of ceramics, the excellent mechanical properties derived from the performance evaluation, and the coefficient of friction of 0.16 suggest that it can be considered as a friction material.

• Journal of Information Display
• /
• v.12 no.3
• /
• pp.145-152
• /
• 2011

Since the discovery of fullerenes as a class of nanostructure compounds, many potential applications have been suggested for their unusual structures and properties. The isolated pentagon rule (IPR) states that all pentagonal carbon rings are isolated in the most stable fullerene. Fullerenes $C_n$ are a class of spherical carbon allotrope group with unique properties. Electron transfer between fullerenes and other molecules is thought to involve the transfer of electrons between the molecules surrounding the fullerene cage. One class of electron transfer molecules is the methanofullerene derivatives ([6,6]-phenyl $C_{61}$-butyric acid methyl ester (PCBM), 4-(2-ethylhexyloxy)-[6,6]-phenyl $C_{61}$-butyric acid methyl ester (p-EHO-PCBM), and 4-(2-ethylhexyloxy)-[6,6]-phenyl $C_{61}$-butyric acid (p-EHO-PCBA), 10-12). It has been determined that $C_{60}$ does not obey IPR. Supramolecular complexes 1-9 and 10-12 are shown to possess a previously unreported host.guest interaction for electron transfer processes. The unsaturated, cis-geometry, thiocrown ethers, (1-9) (described as [X-UT-Y], where X and Y indicate the numbers of carbon and sulfur atoms, respectively), are a group of crown ethers that display interesting physiochemical properties in the light of their conformational restriction compared with a corresponding saturated system, as well as the sizes of their cavities. Topological indices have been successfully used to construct mathematical methods that relate structural data to various chemical and physical properties. To establish a good relationship between the structures of 1-9 with 10-12, a new index is introduced, ${\mu}_{cs}$. This index is the ratio of the sum of the number of carbon atoms ($n_c$) and the number of sulfur atoms ($n_s$) to the product of these two numbers for 1-9. In this study, the relationships between this index and oxidation potential ($^{ox}E_1$) of 1-9, as well as the first to third free energies of electron transfer (${\Delta}G_{et(n)}$, for n = 1-3, which is given by the Rehm-Weller equation) between 1-9 and PCBM, p-EHO-PCBM, and p-EHO-PCBA (10-12) as [X-UT-Y]@R(where R is the adduct PCBM, p-EHO-PCBM, and p-EHO-PCBA group) (13-15) supramolecular complexes are presented and investigated.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.06a
• /
• pp.66-66
• /
• 2008

Most of the properties of ITO films depend on their substrate nature, deposition techniques and ITO film composition. For the display panel application, it is normally deposited on the glass substrate which has high strain point (>575 degree) and must be deposited at a temperature higher than $250^{\circ}C$ and then annealed at a temperature higher than $300^{\circ}C$ in order to high optical transmittance in the visible region, low reactivity and chemical duration. But the high strain point glass (HSPG) used as FPDs is blocking popularization of large sizes FPDs because it is more expensive than a soda lime glass (SLG). If the SLG could be used as substrate for FPDs, then diffusion of Na ion from the substrate occurs into the ITO films during annealing or heat treatment on manufacturing process and it affects the properties. Therefore proper care should be followed to minimize Na ion diffusion. In this study, we investigate the electrical, optical and structural properties of ITO films deposited on the SLG and the Asahi glass(PD200) substrate by rf magnetron sputtering using a ceramic target ($In_2O_3:SnO_2$, 90:10wt.%). These films were annealed in $N_2$ and air atmosphere at $400^{\circ}C$ for 20min, 1hr, and 2hrs. ITO films deposited on the SLG show a high electrical resistivity and structural defect as compared with those deposited on the PD200 due to the Na ion from the SLG on diffuse to the ITO film by annealing. However these properties can be improved by introducing a barrier layer of $SiO_2$ or $Al_2O_3$ between ITO film and the SLG substrate. The characteristics of films were examined by the 4-point probe, FE-SEM, UV-VIS spectrometer, and X-ray diffraction. SIMS analysis confirmed that barrier layer inhibited Na ion diffusion from the SLG.

• Journal of the Korea Concrete Institute
• /
• v.19 no.3
• /
• pp.283-292
• /
• 2007

A research projects is currently being conducted to develop a nonlinear finite element analysis methods for predicting the structural behavior of reinforced concrete frame structures, exposed to fire. As part of this, reinforced concrete frames subjected to fire loads were analyzed using the nonlinear finite-element program DIANA. Two numerical steps are incorporated in this program. The first step carries out the nonlinear transient heat flow analysis associated with fire and the second step predicts the structural behavior of reinforced concrete frames subjected to the thermal histories predicted by first step. The complex features of structural behavior in fire conditions, such as thermal expansion, plasticity, cracking or crushing, and material properties changing with temperature are considered. A concrete material model based on nonlinear fracture mechanics to take cracking into account and plasticity models for concrete in compression and reinforcement steel were used. The material and analytical models developed in this paper are verified against the experimental data on simple reinforced concrete beams. The changes in thermal parameters are discussed from the point of view of changes of structure and chemical composition due to the high temperature exposure. Although, this study considers codes standard fire for reinforced concrete frame, any other time-temperature relationship can be easily incorporated.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.15 no.6
• /
• pp.3990-3996
• /
• 2014

Because the physical properties can be decreased when a Nylon 66/glass fiber composite is injected into a mold over $300^{\circ}C$, a systematic study of the thermal history in the case of re-use is needed. Nylon 66/glass fiber extrudates as a function of the extrusion number were prepared using a twin screw extruder at 305/290/273/268/265/$260^{\circ}C$. The chemical structure, thermal properties, melt index, crystal structure, Izod impact strength, and rheological properties were measured by Fourier transform infra-red (FT-IR), melt indexer, DSC, TGA, XRD, Izod impact tester, and dynamic rheometer. The FT-IR spectra indicated that the number of extrusions did not affect the chemical structure. The decrease in molecular weight with increasing extrusion number was confirmed by the melt index and the complex viscosity of extrudates. Based on the DSC and TGA results, the thermal history had no effect on the melting temperature, regardless of the number of extrusions, but the degradation temperature decreased up to $20^{\circ}C$ with increasing extrusion number. The Izod impact strengths of the extrudates were found to decrease with increasing extrusion number. No structural change after extrusion was also confirmed because there was no change in the slope and shape of the G'-G" plot.

• Korean Chemical Engineering Research
• /
• v.56 no.5
• /
• pp.718-724
• /
• 2018

In this study, the $Ni_{0.9}Co_{0.05}Ti_{0.05}(OH)_2$ precursor was prepared by the concentration gradient co-precipitation method. In order to overcome the structural change due to oxygen desorption in the cathode active material with high nickel content, the physical and electrochemical analysis of the cathode active material according to the calcination temperature were investigated. Physical properties of $Li_{1.05}Ni_{0.9}Co_{0.05}Ti_{0.05}O_2$ were analyzed by FE-SEM, XRD and TGA. The electrochemical performance of the coin cell using a cathode active material and $LiPF_6$(EC:EMC=1:2 vol%) electrolyte was evaluated by the initial charge/discharge efficiency, cycle retention, and rate capabilities. As a result, the initial capacity and initial efficiency of cathode materials were excellent with 244.5~247.9 mAh/g and 84.2~85.8% at the calcination temperature range of $750{\sim}760^{\circ}C$. Also, the capacity retention exhibited high stability of 97.8~99.1% after 50cycles.