• 제목/요약/키워드: Chemical-structural properties

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Analysis of Piezoresistive Properties of Cement Composites with Fly Ash and Carbon Nanotubes Using Transformer Algorithm (트랜스포머 알고리즘을 활용한 탄소나노튜브와 플라이애시 혼입 시멘트 복합재료의 압저항 특성 분석)

  • Jonghyeok Kim;Jinho Bang;Haemin Jeon
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.36 no.6
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    • pp.415-421
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    • 2023
  • In this study, the piezoresistive properties of cementitious composites enhanced with carbon nanotubes for improved electrical conductivity were analyzed using a deep learning-based transformer algorithm. Experimental execution was performed in parallel for acquisition of training data. Previous studies on mixture design, specimen fabrication, chemical composition analysis, and piezoresistive performance testing are also reviewed in this paper. Notably, specimens in which fly ash substituted 50% of the binder material were fabricated and evaluated in this study, in addition to carbon nanotube-infused specimens, thereby exploring the potential enhancement of piezoresistive characteristics in conductive cementitious materials. The experimental results showed more stable piezoresistive responses in specimens with fly-ash substituted binder. The transformer model was trained using 80% of the gathered data, with the remaining 20% employed for validation. The analytical outcomes were generally consistent with empirical measurements, yielding an average absolute error and root mean square error between 0.069 to 0.074 and 0.124 to 0.132, respectively.

An Experimental Study on the Fundamental Properties and Durability of Sewer Type Restorative Mortar Spread with Antibiotics (항균제를 도포한 하수시설용 단면복구 모르타르의 기초물성 및 내구특성에 관한 실험적 연구)

  • Kim, Moo-Han;Kim, Gyu-Yong;Kim, Jae-Hwan;Cho, Bong-Suk;Lee, Dong-Heck
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.3
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    • pp.195-202
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    • 2006
  • Deterioration of sewer concrete is representative that biochemical corrosion according to the $H_2S$ has growth by inhabit sulfur-oxidzing bacteria because of special environment in sewer. But in case of domestic, fundamentally, sulfur-oxidzing bacteria could moderate development of repair material method is need because of corrosion prevent method is inconsideration with carry out to improve project. In this paper, after development of spread type antibiotic with antibio-metal, antibacterial performance about sulfur-oxidzing bacteria of antibiotic and tested to estimate fundamental properties of bonding strength, abrasion contents, contents of water absorption, contents of air permeability, carbonation depth, chloride ion penetration depth and chemical resistance of spread with antibiotic restorative mortar.

Structural and Electrical Properties of Vanadium Oxide Thin Films Annealed in Vacuum (진공 어닐링한 바나듐 산화악의 구조적, 전기적 특성)

  • Choi Bok-Gil;Choi Chang-Kyu;Kwon Kwang-Ho;Kim Sung-Jin
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.1
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    • pp.1-7
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    • 2005
  • Thin films of vanadium oxide(VO/sub x/) were deposited by r.f. magnetron sputtering from V₂O/sub 5/ target with oxygen/(oxygen+argon) partial pressure ratio of 0% and 8% and in situ annealed in vacuum at 400℃ for 1h and 4h. Crystal structure, chemical composition, molecular structure, optical and electrical properties of films were characterized through XRD, XPS, RBS, FTIR, optical absorption and electrical conductivity measurements. The films as-deposited are amorphous, but 0%O₂ films annealed for time longer than 4h and 8% O₂ films annealed for time longer than 1h are polycrystalline. As the oxygen partial pressure is increased the films become more stoichiometric V₂O/sub 5/. When annealed at 400℃, the as-deposited films are reduced to a lower oxide. The optical transmission of the films annealed in vacuum decreases considerably than the as-deposited films and the optical absorption of all the films increases rapidly at wavelength shorter than about 550nm. Electrical conductivity and thermal activation energy are increased with increasing the annealing time and with decreasing the oxygen partial pressure.

Fabrication of Porous Ceramic Materials for Biomedical and Environmental Applications

  • Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.18.2-18.2
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    • 2009
  • Ceramics have some properties that are unmatched by other kind of materials like metals or polymers. The ability of high thermal and chemical resistance and in case of being superior in specific mechanical properties makes the ceramic materials suitable for arange of applications. The microstructure and morphology of a material arguably permit the use of many advanced application otherwise difficult to achieve.Porous structures have some important applications in biomedical and environmental field. For human hard tissue reconstruction and augmentation procedure suitable biomaterials are used with a desirable porosity. A range of porous bioceramics were fabricated with tailored design to meet the demand of specific applications. Channeled and interconnected porosity was introduced in alumina, zirconia, and hydroxyapatite or tri calcium phosphate ceramics by different methods like multi-pass extrusion process, bubble formation in viscous slurry,slurry dripping in immiscible liquid, sponge replica method etc. The detailed microstructural and morphological investigations were carried out to establish the unique features of each method and the developed systems. For environmental filters the porous structures were also very important. We investigated a range of channeled and randomly porous silicon based ceramic composites to enhance the material stability and filtration efficiency by taking advantage of the material chemistry of the element. Detailed microstructural and mechanical characterizations were carried out for the fabricated porous filtration systems.

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Syntheses of(Ti, Al)N Powder by the Direct Nitridation (1) (직접질화법에 의한(Ti, Al)N계 복합질화물의 합성(I))

  • Sohn, Yong-Un;Lee, Young-Ki;Hwang, Yeon;Cho, Young-Soo;Kim, Suk-Yoon
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.3
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    • pp.187-196
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    • 1995
  • TiN and AlN are ceramic materials with mechanical and chemical properties for use in structural applications at elevated temperature. The purpose of this research is to develop the technology for the synthesis of (Ti, Al)N power, which shows simultancously the excellent properties of TiN and AlN, from the mixed powder($Ti_{0.25}Al_{0.75}$, $Ti_{0.5}Al_{0.5}$ and $Ti_{0.75}Al_{0.25}$) by the direct nitriding method. The effects of variables such as temperature, mixing ratio of Al to Ti in raw material were investigated. The(Ti, Al)N powder can be easily synthesized from the mixed powder by the direct nitriding method. Among the mixed powdres, the nitriding behavior decreased with increasing the ratio of Al to Ti. This behavior is well explained by the nitriding mechanism presented in this research.

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Growth and Characterization of GaN on Sapphire and Porous SWCNT Using Single Molecular Precursor

  • Sekar, P.V. Chandra;Lim, Hyun-Chul;Kim, Chang-Gyoun;Kim, Do-Jin
    • Korean Journal of Materials Research
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    • v.21 no.5
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    • pp.268-272
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    • 2011
  • Due to their novel properties, GaN based semiconductors and their nanostructures are promising components in a wide range of nanoscale device applications. In this work, the gallium nitride is deposited on c-axis oriented sapphire and porous SWCNT substrates by molecular beam epitaxy using a novel single source precursor of $Me_2Ga(N_3)NH_2C(CH_3)_3$ with ammonia as an additional source of nitrogen. The advantage of using a single molecular precursor is possible deposition at low substrate temperature with good crystal quality. The deposition is carried out in a substrate temperature range of 600-750$^{\circ}C$. The microstructural, structural, and optical properties of the samples were analyzed by scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and photoluminescence. The results show that substrate oriented columnar-like morphology is obtained on the sapphire substrate while sword-like GaN nanorods are obtained on porous SWCNT substrates with rough facets. The crystallinity and surface morphology of the deposited GaN were influenced significantly by deposition temperature and the nature of the substrate used. The growth mechanism of GaN on sapphire as well as porous SWCNT substrates is discussed briefly.

The characteristics of AlN buffered GaN on ion beam modified Si(111) substrates (Si(111) 위에 Ion beam 처리 후 AlN layer를 완충층으로 이용하여 성장시킨 GaN의 특성)

  • Kwang, Min-Gu;Chin, Jeong-Geun;Lee, Jae-Seok;Oh, Seung-Seok;Hyun, Jin;Byun, Dong-Jin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.99-99
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    • 2003
  • The growth of GaN on Si is of great interest due to the several advantages : low cost, large size and high-quality wafer availability as well as its matured technology. The crystal quality of GaN is known to be much influenced by the surface pretreatment of Si substrate[1]. In this work, the properties of GaN overlayer grown on ion beam modified Si(111) have been investigated. Si(111) surface was treated RIB with 1KeV-N$_2$$\^$+/(at 1.9 ${\times}$ 10$\^$-5/) to dose ranging from 5${\times}$10$\^$15/ to 1${\times}$10$\^$17/ prior to film growth. GaN epilayers were grown at 1100$^{\circ}C$ for 1 hour after growing AlN buffer layers for 5∼30 minutes at 1100$^{\circ}C$ in Metal Organic Chemical Vapor Deposition (MOCVD). The properties of GaN epilayers were evaluated by X-Ray Diffraction(XRD), Raman spectroscopy, Photoluminescence(PL) and Hall measurement. The results showed that the ion modified treatment markedly affected to the structural, optical and electrical characteristic of GaN layers.

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The characteristics of AlN buffered GaN on ion implanted Si(111) (이온주입된 Si(111)에 AlN 완충층을 이용하여 성장시킨 GaN 박막의 특성)

  • 강민구;진정근;이재석;노대호;양재웅;변동진
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.165-165
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    • 2003
  • The growth of GaN on Si is of great interest due to the several advantages low cost, large size and high-quality wafer availability as well as its matured technology. The crystal quality of GaN is known to be much influenced by the surface pretreatment of Si substrate [1]. In this work, the properties of GaN overlayer grown on ion implanted Si(111)and bare Si(111) have been investigated. Si(111) surface was treated ion implantation with 60KeV and dose 1${\times}$10$\^$16//$\textrm{cm}^2$ prior to film growth. GaN epilayers were grown at 1100$^{\circ}C$ for 1 hour after growing AlN buffer layers for 15-30 minutes at 1100$^{\circ}C$ with metal organic chemical vapor deposition (MOCVD). The properties of GaN epilayers were evaluated by X-Ray Diffraction (XRD), Scanning electron microscope (SEM) Photoluminescence (PL) at room temperature and Hall measurement The results showed that the GaN on ion implanted Si(111) markedly affected to the structural, optical and electrical characteristic of GaN layers.

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Fabrication and Evaluation of Chalcogenide Glass for Molding (몰드성형용 GeSbSe계 칼코게나이드 유리 제작 및 특성 분석)

  • Park, Heung-Su;Cha, Du-Hwan;Kim, Hye-Jeong;Kim, Jeong-Ho;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.2
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    • pp.135-139
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    • 2012
  • In this study, we synthesized the chalcogenide glass($Ge_{19}Sb_{23}Se_{58}$) for infrared optics by meltquenching method and verified the effect of cooling condition on the glass properties. The structural and optical properties of the glass were analyzed by XRD, FT-IR and SEM image. The glass synthesized under the cooling temperature of $980^{\circ}C$ shows transmittance of 58% at $8\sim12{\mu}m$, which was decreased as the cooling temperature was decreased. In addition, thermal and hardness also were measured. From the analysis results, we ascertained the feasibility as a molding materials for infrared optics.

Field-emission properties of carbon nanotubes coated by zinc oxide films (산화아연막이 증착된 탄소 나노튜브의 전계방출 특성)

  • Kim, Jong-Pil;Noh, Young-Rok;Lee, Sang-Yeol;Park, Jin-Seok
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1270_1271
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    • 2009
  • In this research, gallium-incorporated zinc oxide (ZnO:Ga) thin films have been used as a coating material for enhancing the field-emission property of CNT-emitters. Multi-walled CNTs were directly grown on conical-type ($250{\mu}m$ in diameter) metal-tip substrates at $700^{\circ}C$ by inductively coupled plasma-chemical vapor deposition (ICP-CVD). The pulsed laser deposition (PLD) technique was used to produce 5wt% gallium-doped ZnO (5GZO) films with very low stress. The structural properties of ZnO and 5GZO coated CNTs were characterized by Raman spectroscopy. Field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM) were also used to monitor the variation in the morphology and microstructure of CNTs before and after 5GZO-coating. The measurement of the field emission characteristics showed that the emitter that coated the 5GZO (10nm) on CNTs exhibited the best performance: a maximum emission current of $325{\mu}A$, a threshold field of 2.2 V/${\mu}m$.

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