• Title/Summary/Keyword: Chemical wastewater treatment

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Potential valorisation of ferrous slag in the treatment of water and wastewater: A review

  • Anjali, M.S.;Shrihari, S.;Sunil, B.M.
    • Advances in environmental research
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    • v.8 no.1
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    • pp.55-69
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    • 2019
  • The generation of ferrous slag, an industrial by-product from the iron ore industry, results in serious environmental problems. The chemical compositions indicate 30-34% SiO2, 30-34% CaO, 18-22% Al2O3 and 0.5-0.6% Fe2O3. The specific gravity, moisture content and pH are in the range of 1.3-1.65, 9.1-10% and 8.5-9.0 respectively. The major part of the slag is composed of sand-size particles. The problems of disposal of slag could be minimized by considering its use in various environmental engineering applications providing additional value to the by-product. This paper mainly focuses on the potential utilization and valorisation of ferrous slag in both water and wastewater treatments. It is effective for the treatment of water and wastewater containing nutrients, heavy metals and polluted river/stormwater.

A Study on the Municipal Wastewater Treatment Using Biofilm Process (생물막공법을 이용한 도시하수처리에 관한 연구)

  • Kwak, Byung Chan;Tak, Seong Jae;Kim, Nam Cheon;HWang, Yong Woo
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.1
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    • pp.62-75
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    • 2000
  • Most of biological treatment to remove contaminants in municipal wastewater have been conducted by activated sludge process. But, the process have several probIems such as enormous site needed for construction of treatment facilities, unstable treatment due to limited ability to control load fluctuation, frequent sludge bulking and appearance of lots of surplus sludge. In this study, the experiments were performed through submerging biofilm of PEPP media in existing aeration tank with raw water from municipal wastewater treatment plant and then submerging PVDC and PEPP media, different from shape and chemical peculiarity in anoxic reactor. Throughout the experience, nutrient removal efficiency according to HRT, nitrogen phosphorous removal efficiency, behavior of nitrogen and dewatering efficiency have been compared and analysed with those of activated sludge process. As the results, BOD removal efficiency according to BOD volumetric load and F/M ratio was not found any differency in two processes, but was decreased below 90% as going along the condition of high load in activated sludge process. Kinetic coefficient was $K_{max}=1.162day^{-1}$, $K_s=53.77mg/L$, $Y=0.166mgVSS/mgBOD_{rem}$. and $K_d=0.019day^{-1}$. It was found that the removal efficiency, even though in aerobic condition, in biofilm process equipped anoxic reactor was higher than the one in activated sludge process within the range of 70~80%, and became better as HRT increased. Phosphorous removal efficiency was not found any differency in two processes. In biofilm process, treament efficiency even in conditions of high load was not decreased, because the biomass concentration could be maintained in high condition compared with activated sludge process. As HRT increased, suspended and attached biomass was increased and the other hand, F/M ratio was decreased as biomass' increasing. Biomass thickness was increased. from $10.43{\mu}m$ to $10.55{\mu}m$ as HRT increased and density of biomass within $40.79{\sim}41.16mg/cm^2$. The results also present that the dewatering efficiency of sludge generated in biofilm process was higher than in activated sludge process, and became better as HRT increased.

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Disintegration of Waste Activated Sludge by Acid Hydrolysis (산 가수분해에 의한 폐활성슬러지 분해)

  • Patchareeya Jaipakdee;Yeonghee Ahn
    • Journal of Life Science
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    • v.33 no.1
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    • pp.82-90
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    • 2023
  • Biological process is used worldwide to treat domestic and industrial wastewater. The process generally uses a mixed microbial culture of sludge. The growth of microorganisms in the sludge produces excess sludge from the wastewater treatment process. Some of the excess sludge is recycled as inoculum for wastewater treatment, but the rest is removed as waste from the process. As wastewater production is increasing worldwide every year, the number of wastewater treatment plants (WWTPs) is also in- creasing, resulting in the generation of large amount of waste sludge. The increasing amount of waste sludge from WWTPs has led to concerns about its management. Sludge disposal has been reported to account for 50~60% of the total operating costs of a WWTP. Sludge disintegration is a new technology that can minimize volume of waste sludge and recover useful components (e.g., P, N, and soluble organic compounds) from it. Various methods of sludge disintegration have been developed based on physical, chemical, and biological treatments or combinations of these. In this review, we focus on sludge disintegration by acid hydrolysis, which is less studied among sludge disintegration methods. Such information can be useful in the development and implementation of a new technology for better sludge treatment.

A study of Swine Wastewater Treatment using Photosynthetic Bacteria (광합성 세균을 이용한 돈분 폐수 처리에 관한 연구)

  • Choi, Kyung-Min;Park, Eung-Roh;Ju, Hong-Shin;Yang, Jae-Kyung;Lee, Ki-Young;Lee, Sung-Taik;Lee, Mu-Choon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.4 no.2
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    • pp.11-17
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    • 1996
  • Photosynthetic bacteria, strains KN 1-1, KN 2-1 and KN 2-3 were isolated from nature, and were studied for swine wastewater treatment. Growth of those photosynthetic bacteria were increased to 2~3 fold in organic-acid added medium(sodium acetate 1g, sodium propionate 1g and sodium butyrate 1g in Lascelles basal medium $1{\ell}$) than cultivation in Lascelles basal medium, and amount of bacteriochlorophyll a were increased to 1.5~2 fold. Chemical Oxygen Demand(COD) in swine wastewater using photosynthetic bacteria, strains KN 1-1, KN 2-1 and KN 2-3 were reduced 80%, 89% and 75%, respectively.

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TREATMENT OF HIGH-CONCENTRATION SWINE WASTEWATER BY ANAEROBIC DIGESTION AND AN AQUATIC PLANT SYSTEM

  • Kim, B.U.;Kwon, J.H.
    • Environmental Engineering Research
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    • v.11 no.3
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    • pp.134-142
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    • 2006
  • The treatment of high-strength swine wastewater by anaerobic digestion combined with an aquatic plant system was investigated. Anaerobic digestion of swine wastewater gave volatile solids (VS) removal efficiencies of 43.3%, 52.1% and 54.5% for hydraulic retention times (HRTs) of 20, 30, 40 days, respectively. The removal efficiencies of VS, total chemical oxygen demand (TCOD) and soluble chemical oxygen demand (SCOD) decreased with increasing VS volumetric loading rate (VLR). Higher organic removal efficiency was observed at longer HRTs for the same VS volumetric loading rate. As VS volumetric loading rate increased, biogas production increased and the methane content of the biogas decreased. Experiments using duckweed (Lemna species) as an aquatic macrophyte gave the following results. In the case of nitrogen, removal efficiency was above 60% and effluent concentration was below 10.0 mg/L when the influent ammonia-N loading was about $1.0\;g/m^2/day$. In the case of phosphorus, removal efficiency was above 55% and effluent concentration was below 2.0 mg/L when the influent $PO_4$-P loading was about $0.15\;g/m^2/day$. In addition, crude protein and phosphorus content of duckweed biomass increased from 15.6% to 41.6% and from 0.8% to 1.6%, respectively, as the influent nutrient concentration increased. The treatment of high-strength swine wastewater by anaerobic digestion combined with an aquatic plant system offers good performance in terms of organics and nutrient removal for relatively low operation and maintenance costs. The results indicate that under appropriate operational conditions, the effluent quality is within the limits set by Korean discharge criteria.

Validity evaluation of wastewater treatment system applying advanced treatment processes (고도처리공법이 적용된 하수처리시설에서의 공법적용의 적정성 평가)

  • Ahn, June-Shu;Park, Tae-Sool;Cho, Jung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.10
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    • pp.4055-4068
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    • 2010
  • In this study, validity of wastewater treatment system with advanced treatment processes was evaluated by studying its operational conditions by applying the advanced treatment to the wastewater treatment system which was operating for last several years. Study indicated a fair result for the removal efficiencies of BOD, T-P, and T-N for each unit operation. BOD removal efficiencies for primary clarifier, bioreactor, final effluent are 35, 87, and 48 % respectively. T-P(T-N) removal efficiencies for primary clarifier, bioreactor, final effluent are 18(23), 40(38), and 25(25) % respectively. Further investigation of bioreactor showed that various microorganism such as bacteria, protozoa, and metazoa is present in the bioreactor, and the main function of the media, adhesion (adsorption) of microorganism onto the media, is stabilized. Final effluent quality was lower than the regulation, and BOD, COD, SS, T-N, T-P were 5.5, 9.9, 4.6, 11.8, 0.99 mg/L respectively.

Effect of seeding ratio on acidogenic biokinetics in high ammonia concentration

  • Yang, Keun-Young;Shin, Seung-Gu;Hwang, Seok-Hwan
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.65-66
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    • 2005
  • Anaerobic digestion is one of the well-known methods for biological treatment handling of concentrated organic matter such as swine $wastewater.^{1)} The anaerobic digestion can reduce organic loading but also hydrolyze non-biodegradable organic $matter.^{2)}$ The feces from the scrapper-type barn are usually collected to make compost and the urine is discarded with swine-slurry wastewater by ocean-dumping or treated by biological methods. The lagoon, aerobic digestion, anaerobic digestion, SBR, $A^{2}/O$, and UCT have been applied for treating swine $wastewater.^{3)} In this study, as a result of the analysis of swine wastewater, the total and soluble chemical oxygen demand was 130g/L and 60g/L, respectively. And the volatile fatty acid as chemical oxygen demand equivalent was 45g/L, which was 75% of soluble chemical oxygen demand. Before everything else, ammonia nitrogen concentration was 6.5 g/L. From biochemical acidogenic potential test, it was concluded that the enhanced acidification process to manage swine waste should be operated in the ammonia nitrogen concentration of less than 1.2 g/L. In the result of seeding ratio experiments with artificial $wastewater^{4)}, the lag period of acidogens was taken the long time because of the inhibition by the $ammonia^{5)}$, however no difference of period by the seeding ratio was not shown. The Haldane-based biokinetics were also evaluated using a method of fourth order Runge-Kutta $approximation.^{6,7)}$ The nonlinear least squares (NLLS) method with a 95% confidence interval was also used. The ranges of maximum microbial growth rate, ${/mu_{max}}$, and half saturation coefficient, $K_{s}$, for acidogenesis of various seeding ratio with artificial wastewater were 6.1 ~ 12.6 $d^{-1}$ and 45,000 ~ 53,500 mg glucose/L, respectively. Also, the methanogenic microbial yield coefficient, Y, and microbial decay rate coefficient, $k_{d}$, and inhibition substrate concentration, $K_{si}$, for the reactors were determined to be 0.32 ~ 0.465 ${/mu}g$/mg glucose; 0.42 ~ 1.01 $d^{-1}$ and 51,500 ~ 55,600 mg glucose/L, respectively.

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Toxic Assessment on Effluents of Argo/Industrial Wastewater Treatment Plants in Jeonnam using Chemical and Biological Method (전남 농공단지 폐수처리장 방류수의 화학적/생물학적 독성평가)

  • Lee, Moon-Hee;Choi, Ik-Chang;Han, Sang-Kuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.14 no.4
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    • pp.267-273
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    • 2008
  • The purpose of this study is to investigate the distributive property of organic pollutants in effluents of argo/industrial wastewater treatment plants in Jeonnam using simultaneous analysis method of 310 chemicals. The numerous organic pollutants were detected in four sampling sites and the major chemicals were pesticides, CH type chemicals such as polycyclic compounds, CHO type chemicals such as phthalates, and CHO(N) type chemical such as aromatic amines. Moreover, 17 kinds of endocrine disrupters which include diethylptbalate were detected in each sampling sites. TU (Toxic unit) indicated cytotoxicity of samples using XTT assay, it appeared highly at A point(27.2) and D point(24.4). Also, the results from the correlation between total concentration of pollutants and TU did not correspond to the results of chemical and biological analysis.

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Rice Growth Response and Soil Quality by Domestic Wastewater Irrigation on Rice Paddy Field - Lysimeter experiment - (하수종말처리장 방류수를 논 관개용수로 처리시 벼 생육 및 토양환경 영향 조사 - 라이시미터 재배실험 -)

  • Cho, Jae-Young;Park, Seung-Woo;Son, Jae-Gwon;Park, Bong-Ju;Li, Long-Gen
    • Journal of Korean Society of Rural Planning
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    • v.12 no.2 s.31
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    • pp.49-56
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    • 2006
  • The application of domestic wastewater on rice paddies results in the accumulation of sodium(Na$^+$) to the soil. Excessive concentration of sodium may cause the deterioration of the physical characteristics of the soil, change in the osmosis of the soil, destruction of soil aggregates as well as ion toxicity due to sodium accumulation. Using domestic wastewater as irrigation water should be preceded by measures to prevent or control the soil salinization caused by sodium. Agricultural reuse of domestic wastewater were found not to cause serious problems with food safety due to heavy metals. However, pre-treatment using ultraviolet or ozone is recommended to reduce the number of bacteria and gem and for public health reasons. Using domestic wastewater has shown that reducing the standard application of chemical fertilizers by as much as 50% reduced the harvesting index by only 10%. This study has shown that it is feasible to reuse domestic wastewater on rice paddies. In order to facilitate the application, it is deemed necessary to establish wastewater treatment technologies in the future, to review criteria for recycling domestic wastewater for agricultural purposes such as conditions of soil and cropping system and to resolve conflicts with farmers and public health issues.

A study on the dye wastewater treatment by Fenton oxidation process (Fenton 산화공법을 적용한 염색폐수처리 연구)

  • Ahn, June-Shu;Park, Tae-Sool;Cho, Jung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.9
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    • pp.4274-4282
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    • 2011
  • In this study, Fenton reaction was studied for the possibility of applying as advanced treatment and its optimal condition for the removal of refractory organics from the dye wastewater. Fenton reaction was applied to remove refractory organics after the bio-treatment (secondary treatment) inside test laboratory and on-site pilot plant. Wastewater from the secondary treatment was used and its $COD_{Mn}$ was measured as 30~50mg/L. After the Fenton reaction, the optimal condition was found as pH 3~3.5, reaction time 2~2.5hr, chemical input ratio of ($FeCl_2$(33%)/$H_2O_2$(35%)) was 3 : 1. When chemical input ratio of ($FeCl_2$(33%)/$H_2O_2$(35%)) was at its optimal, amount of sludge volume ($SV_{2hr}$) was 21~28%. With pilot plant test, removal rate was heavily influenced by the hydraulic retention time(HRT), and optimum value of HRT was 2.0 hr. When pilot plant($2m^3/d$) was placed on-site and operated continuously, it showed steady and fairly good treatment of COD where COD removal rate was 60~70%, treated water showed below 20mg/L.