• Journal of Life Science
• /
• 제9권2호
• /
• pp.40-43
• /
• 1999

In the wastewater treatment experiment by anaerobic-aerobic packed bed unit, it was found that the high and stable removal efficiency of nitrogen could be obtained. The extent of nitrogen removal gradually decreased with the rise of recycle ratio and DO concentration. On the other hand, the extent of phosphorus increased with the increase of DO concentration. COD showed high removal efficiency over the entire range tested. The simulation of T-N behavior was carried out satisfactorily by using the kinetic equations for biofilm and the reactor model which considered the packed bed as a plug flow reactor.

• 청정기술
• /
• 제9권2호
• /
• pp.49-55
• /
• 2003

우리나라엣 발생되는 축산 폐수는 $130,00m^3/day$로 전체 폐수의 0.43%에 불과하지만 총 BOD(생물학적 산소요구량)의 8.6%를 차지하고 있다. 그러나 생활폐수나 산업폐수와 달라 높은 질소, 인을 함유하고 있어 강이나 호수의 부영양화의 주원인이 되고 있다. 우리나라 축산폐수는 각 농가 당 폐수 발생량이 $2.5m^3/day$에 불과해 소규모이어서 경제적인 처리 방법이 필요하다. 부유물질 제거를 위해 미세여과 공정대신 충전탑을 이용한 전처리 방법을 통해 90% 이상의 부유물질을 제거하고 이어 역삼투압 방법을 적용하면 전질소와 전인의 제거율은 95%이상이나 되어 방류수는 전질소는 200 mg/이하, 전인 1 mg/L이하로 환경부의 축산폐수 배출수 수질 허용기준인 전질소 260 mg/L, 전인 50 mg/L이하를 충분히 만족 시킬 수 있다. $2m^3/day$의 축산폐수를 처리하는데 $0.4m^2$의 역삼투압 막 면적만 필요해 효과적인 소규모 처리시설이 가능함을 밝혔다. 처리에 소모되는 전력량도 월 30 Kwh로 에너지 절약적인 공정이 가능함을 예측하였다.

• 분석과학
• /
• 제17권6호
• /
• pp.527-531
• /
• 2004

Treatment with aqueous sodium hydroxide solution plays an important role to impart certain desirable properties - feel and luster on the surface of polyester fiber. In this process alkali wastewater contains disodium terephthalate, ethylene glycol (EG) and residual sodium hydroxide. In this paper we report a new method containing the pretreatments of derivatization with benzoyl chloride and solvent extraction using pentane. The calibration curve of EG determined by GC/MS-SIM shows a good linearity in the range of 0.1 to $25{\mu}g/mL$ having the standard deviation of ${\leq}8.7%$. The recovery and the detection limit of this method are 91.9-93.7% and $0.05{\mu}g/mL$ respectively.

• 한국환경과학회지
• /
• 제7권2호
• /
• pp.209-216
• /
• 1998

Nanofiltration[NF45] and reverse osmosis membrane(HR98PP) separation treatment of dyestuff wastewater was carried out In order to separate relatively pure water from synthetic dyestuff wastewater, which consists of reactive dye, acid dye, basic dye, direct dye, and disperse dye. The experiments were performed by using the plate and frame membrane module. In the nanofiltration and reverse osmosis membrane separation, When the NaCl concentration was 0.1, 5.0, and 20.091, retention was 63.0, 46.0, 0.9%, respectively. When permeate flux was 125.0, 67.5, and 45.0 L/$m^2$ h, the osmotic pressure increased with Increasing the NaCl concentration. Permeate flux of two membranes Increased as temperature Increased due to segmental movement of polymer of the membrane and the rejection rate of dyestuff was decreased gradually. It was found that the rejection rate was about 95% in the nanofiltratlon, while the reverse osmosis membrane showed a high rejection rate of 99% under all temperature and pressures conditions.

• 한국염색가공학회지
• /
• 제9권6호
• /
• pp.26-32
• /
• 1997

In order to remove the pollutants effectively in the dye-processing wastewater by chemical precipitation, coagulation and flocculation test was carried out using several coagulants on various reaction conditions. It was found that the Ferric sulfate was best coagulant for the treatment of mixed dye-processing wastewater. When the Ferric sulfate dosage was 1,100mg/$\ell$, the COD removal rate was very high(50%), and the color was removed very effectively. The COD was decreased relatively well up to 40%, when Alum was dosed as coagulant. But it was difficult to remove the color effectively. Test results about COD removal for the Ferrous sulfate and the Ferric chloride used were mostly same as those of the Alum used. However, the color removal by the Ferrous sulfate was much better than the case of the Alum or the Ferric chloride. It was found that the COD removal was increased and the sludge yield was decreased by pH control before polymer flocculant addition, during the jar test for the Ferrous sulfate and the Ferric sulfate as a coagulant.

• Membrane and Water Treatment
• /
• 제12권2호
• /
• pp.75-82
• /
• 2021

This study aimed to prepare a W/O nonionic microemulsion system(MEs) consisting of OP-4[polyoxyethylene(4) nonylphenol], OP-7[polyoxyethylene(7) nonylphenol], 1-hexanol, D2EHPA, kerosene and HCl solution and applied to the extraction of La(III) from chloride aqueous solution within the polysulfone hollow fiber contactor (HFC),laboratory-scale experiments were carried out to investigate the recovery of La(III) using as-prepared microemulsion from the simulation wastewater containing La(III),Al(III) and Fe(III). The right weight ratio(Rs) of OP-4 to OP-7 was firstly confirmed through determination of the solubilization capacity of HCl solution(W0,HCl) in microemulsion, the effect of several factors such as the HCl concentration, temperature and effective extraction time on the extraction efficiency of La(III) was discussed. Results showed that the acceptable Rs was 4:6 to prepare the W/O MEs. The extraction yield of La(III) increased with the increasing of HCl concentration, temperature and effective extraction time and reaches to 97.3% while using five-stage modules. The recovery yield of La(III) from simulation La-bearing wastewater was 90.6%.

• 공업화학
• /
• 제20권2호
• /
• pp.213-217
• /
• 2009

폐수처리와 동시에 전기를 생산할 수 있는 새로운 대체 에너지 기술로 주목받고 있는 미생물 연료전지(microbial fuel cell, MFC)는 혐기성 조건의 산화전극(anode)에서 미생물에 의한 촉매작용을 통해 유기물질을 분해하면서 화학에너지를 전기에너지로 전환시키는 장치이다. 본 연구에서는 MFC의 성능을 파악하기 위하여 도시하수를 사용하여 폐수처리 효율과 전기생산 특성을 평가하였다. 도시하수에 탄소원으로서 acetate를 주입하였을 때 COD 제거율은 75.7%에서 88.2%로 증가하였으며 전압은 0.22 V에서 0.4 V까지 급격하게 상승하였다. 다양한 외부저항 하에서 전기생산에 미치는 산화전극과 환원전극(cathode) 사이의 전극 거리에 대한 영향 및 산화전극의 표면적에 대한 영향을 조사하였다. 최고 전력밀도는 $610mW/m^2$이었으며, 전극간 거리가 가깝고 산화전극의 표면적이 작을수록 전기발생에 효과적임을 알 수 있었다.

• Environmental Engineering Research
• /
• 제10권6호
• /
• pp.269-282
• /
• 2005

The novel behavior of ferrate(VI) has received an increased attention for its possible applications in various purposes particularly in the treatment of waste/effluent waters. It possess relatively high oxidizing capacity and the reduced ferrate(VI) into Fe(III) again an important and useful precipitant, coagulant, flocculants and likely to be a good adsorbent via the formation of ferric hydroxide for various metal cations. Moreover, the non-toxic effect makes it a 'green chemical' and further enhances its widespread uses in various purposes. Here an attempt has been made to review the applications of ferrate(VI) in the treatment of waste waters and also its possible future applications in the wastewater treatment technology.

• Membrane and Water Treatment
• /
• 제6권3호
• /
• pp.189-203
• /
• 2015

Membrane biofouling impedes wide application of membrane bioreactor (MBR) for wastewater treatment. Recently, quorum sensing (QS) mechanisms are accounted for one of major mechanisms in biofouling of MBRs. In this study, vanillin was applied to investigate reduction of biofouling in MBRs. MBR sludge was analyzed to contain QS signal molecules by cross-feeding biosensor assay and HPLC. In addition, the inhibitory activity of vanillin against bacterial quorum sensing was verified using an indicator strain CV026. The vanillin doses greater than 125 mg/L to 100 mL of MBR sludge showed 25% reduction of biofilm formed on the membrane surfaces. Two MBRs, i.e., a typical MBR as a control and an MBR with vanillin, were operated. The TMP increases of the control MBR were more rapid compared to those of the MBR with the vanillin dose of 250 mg/L. The treatment efficiencies of the two MBRs on organic removal and MLSS were maintained relatively constant. Extracellular polymeric substance concentrations measured at the end of the MBR operation were 173 mg/g biocake for the control MBR and 119 mg/g biocake for the MBR with vanillin. Vanillin shows great potential as an anti-biofouling agent for MBRs without any interference on microbial activity for wastewater treatment.

• 상하수도학회지
• /
• 제26권2호
• /
• pp.209-218
• /
• 2012

Recently, as reinforced water quality standards for wastewater has been announced, more efficient and more powerful wastewater treatment processes are required rather than the existing activated sludge process. In order to meet this demands, we evaluate Task 1-4 about lab scale $A_{2}O$　process using biofilm media. Task 1, 2, and 3 use 'Module A' which has 4 partitions (Anoxic/Anerobic/Oxic/Oxic). Task 4 uses 'Module B' which has 2 partitions including a denitrification reactor with an Inclined plug flow reactor (IPFR) and a nitrification reactor with biofilm media. The denitrification reactor of Module B is designed to be upward flow using IPFR. The result of evaluating at each Task has shown that attached growth system has better capacity of removal efficiency for organic matter and nitrogen with the exception of phosphorus.　Task 4 which has the most outstanding removal efficiency has 90.5% of $BOD_{5}$ removal efficiency, 97.8% of ${NH_4}^{+}-N$ removal efficiency, 65% of T-N removal efficiency and 92% of T-P removal efficiency with additional chemical phosphorus removal system operated at HRT 9hr, Qi:Qir 1:2, and BOD/T-N ratio 2.7.