• Title/Summary/Keyword: Chemical wastewater treatment

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Bench-Scale Evaluation of the Activated Sludge Process for Treatment of a High-Strength Chemical Plant Wastewater (활성슬러지법에 의한 고농도 중화학공장 폐수처리에 관한 연구)

  • 조영하
    • Journal of Environmental Health Sciences
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    • v.19 no.3
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    • pp.1-16
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    • 1993
  • This paper describes an investigation to determine whether the activated sludge (AS) process could be used for the treatment of wastewater at the Union Carbide Coporation (UCC) plant in Seadrift, Texas. This plant presently utilizes a waste stabilization pond (WSP) system for treatment of the wastewater. The treatment system consists of an in-plant primary WSP and two off-plant WSPs (secondary and tertiary WSPs), run in series. The total hydraulic detention time of the WSP system is approximately 150 days. Several laboratory-based treatability studies have been conducted to evaluate the performace of the WSP system and the degradability of specific chemical compounds. From an additional study, it was determined that the WSP system was stressed and occasionally operating near the limit of its treatment capacity. The existing primary WSP plays an important role in the overall treatmemt system, because it not only functions as a pH and organic-strength equalization basin, but also serves as a "preconditioning" basin by fermenting high strength organic wastes to volatile organic acids for subsequent degradation in the escondary WSP. However, in view of pending RCRA legislatin conerning the "proposed organic toxicity characteristics limits" (40 CFR Part261: Federal Register, July, 1988), it is possible that the primary WSP will have to be abandoned in favor of alternative treatment options. Therefore the main purpose of this study was to perform activated sludge treatability evaluations for the development of an alternative to the existing primary WSP treatment ststem. In addition, another purpose was to determine the degradability of bis(2-chloroethyl)ether (Chlorex or CX) and benzene(BZ) in the activated sludge process. The presence of these two chemicals in the wastewater of the plant prompted the question of whatedether they could be degraded in an activated sludge system.

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Possibility of Dyeing Wastewater Treatment using Chitin (Chitin을 이용한 염색폐수 처리가능성 연구)

  • Hwang, Sung-Kwy;Lee, Han-Seab;Hwang, Yong-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.4
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    • pp.87-93
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    • 1998
  • In spite of various applications of chitin derivatives from waste marine sources, commercial use of chitin has been limited due to resistance to chemicals and the absense of proper solvents. We prepared chitin through decalcification, bleaching and deproteination from protunus trituberculatus shells by the application of Hackman's method. Structural and chemical properties of chitin were investigated to have proper specific surface area and particle size by IR, BET and PSA. The amount of absorbed water of chitin reached equilibrium by stirring about 15 minutes. The amount of absored water of the prepared chitin were large than the commercial chitin. When prepared chitin tested on dyeing wastewater, they showed better treatment efficiency in COD, suspended solid, and color tests than the commercial chitin. The adsorption capacity increased with decreasing particle size for the prepared chitin. Treatment efficiency for color was increased as the sitirring rate increased. Results show the possibility of the prepared chitin from waste marine sources as a treatment system for dyeing wastewater.

A Study on the Characteristic Evaluation of Sewage and Industrial Wastewater Treatment Sludges by Physico-chemical Analysis (물리화학적 분석을 통한 하 ${\cdot}$ 폐수처리 슬러지류의 특성평가)

  • Kwon, Gi-Hong
    • Journal of Environmental Health Sciences
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    • v.31 no.1
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    • pp.86-93
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    • 2005
  • Because generally large amount of sludges are generated from the process of sewage and wastewater treatment, the management and controlment of those sludge has become a important issue in many researches. In this dissertation, we conducted the research to see the physico-chemical characteristics of sludges generated from various sources. Moisture of sludges were 81.5% in textile industries, 81.4% in frame metal industries, 80.7% in 1st metal industries. Volatile solid were 22.1% in hide · rubber industries, 21.9% in coke · petroleum industries. Fixed solid were 18.5% and 17.7% in the 1st metal industries and frame metal industries. High heating value by wet base were 1,850 kcal/kg in coke · petroleum industries, 1,220 kcal/kg in hide · rubber industries, but sludges from the 1st metal industries and frame metal industries were impossible to incinerate because most of those sludges were inorganic. The leaching test showed that hazardous materials was detected in nearly every kinds of sludges. Some of sludges from hide · rubber industries and frame metal industries exceeded the leaching criteria and so they were classified as specific wastes. And other sludges generated in sewage treatment plants or other industries was below the leaching criteria.

Biodegradability Index Development Based on Aerobic Biodegradation, Anaerobic Biodegradation, and Toxicity Test (호기성 분해, 혐기성 분해 및 독성을 고려한 생분해도 지표 개발)

  • Yoo, Kyu-Seon;Shin, Hang-Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.5
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    • pp.603-608
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    • 2010
  • More than 8 millions of chemical have been used for human activities and lots of chemicals can not be degraded by microbial activities in this world. To show the biodegradability of a chemical, biodegradability index (B.I.) is suggested using aerobic biodegradability by $BOD_5$/COD, anaerobic biodegradability by methane potential (M.P.) and toxicity by the luminiscent bacteria. In this study, PVA (polyvinyl alcohol), HEC (hydroxy ethyl cellulose), 2,4,6-TCP (tri-chloro phenol) and 2,4-DCP (di-chloro phenol) are used for test chemicals. Though they show little toxicity, PAV and HEC have low B.I. because they are polymers having high molecular weight. That means that there are no bacteria that has enzyme to degrade polymer molecules. Also, anaerobic treatment is suggested better than aerobic treatment from B.I. 2,4,6-TCP and 2,4-DCP show high toxicity and have low B.I. Their low biodegradabilities seem to be originated from their toxicities. If B.I. is used in wastewater treatment, better treatment process can be suggested and finally it can lead our society to make more environment-friendly chemicals.

Study of MF membrane as pretreatment option using various backwash process from wastewater reuse pilot plant (전처리 MF의 다양한 역세 공정을 적용한 하수재이용 파일럿 플랜트 연구)

  • Park, Kwang-Duck;Park, Chansoo;Lee, Chang-Kyu;Kim, Jong-Oh;Choi, June-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.3
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    • pp.335-341
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    • 2016
  • Various studies have forwarded an outstanding wastewater effluent treatment systems toward securing sustainable supply of water sources. In this paper, a broad overview of the performance of MF membrane as pretreatment option for wastewater reuse will be presented based on the literature survey and experiments conducted over the wastewater reuse pilot plant. The pilot plant was operated with a continuous data acquisition for about 300days under various chemical enhanced backwash (CEB) system with subsequent treated water quality analysis. Accordingly, assessment of the effluent revealed that the pretreated water is suitable enough to be used as an input for Reverse Osmosis (RO) unit and significant effect of CEB and concentration of NaOCl is also conceived from the analysis. Moreover, it's also observed that the application of various CEB condition over long operational hours induced a constant declination of overall performance of MF membrane.

Enhanced and Balanced Microalgal Wastewater Treatment (COD, N, and P) by Interval Inoculation of Activated Sludge

  • Lee, Sang-Ah;Lee, Nakyeong;Oh, Hee-Mock;Ahn, Chi-Yong
    • Journal of Microbiology and Biotechnology
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    • v.29 no.9
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    • pp.1434-1443
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    • 2019
  • Although chemical oxygen demand (COD) is an important issue for wastewater treatment, COD reduction with microalgae has been less studied compared to nitrogen or phosphorus removal. COD removal is not efficient in conventional wastewater treatment using microalgae, because the algae release organic compounds, thereby finally increasing the COD level. This study focused on enhancing COD removal and meeting the effluent standard for discharge by optimizing sludge inoculation timing, which was an important factor in forming a desirable algae/bacteria consortium for more efficient COD removal and higher biomass productivity. Activated sludge has been added to reduce COD in many studies, but its inoculation was done at the start of cultivation. However, when the sludge was added after 3 days of cultivation, at which point the COD concentration started to increase again, the algal growth and biomass productivity were higher than those of the initial sludge inoculation and control (without sludge). Algal and bacterial cell numbers measured by qPCR were also higher with sludge inoculation at 3 days later. In a semi-continuous cultivation system, a hydraulic retention time of 5 days with sludge inoculation resulted in the highest biomass productivity and N/P removal. This study achieved a further improved COD removal than the conventional microalgal wastewater treatment, by introducing bacteria in activated sludge at optimized timing.

Pilot scale membrane separation of plating wastewater by nanofiltration and reverse osmosis

  • Jung, Jaehyun;Shin, Bora;Lee, Jae Woo;Park, Ki Young;Won, Seyeon;Cho, Jinwoo
    • Membrane and Water Treatment
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    • v.10 no.3
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    • pp.239-244
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    • 2019
  • Plating wastewater containing various heavy metals can be produced by several industries. Specifically, we focused on the removal of copper (Cu2+) and nickel (Ni+) ions from the plating wastewater because all these ions are strictly regulated when discharged into watershed in Korea. The application of both nanofiltration (NF) and reverse osmosis (RO) technologies for the treatment of wastewater containing copper and nickel ions to reduce fresh water consumption and environmental degradation was investigated. In this work, the removal of copper (Cu2+) and nickel (Ni+) ions from synthetic water was studied on pilot scale remove by before using two commercial nanofiltration (NF) and reverse osmosis(RO) spiral-wound membrane modules (NE2521-90 and RE2521-FEN by Toray Chemical). The influence of main operating parameters such as feed concentration on the heavy metals rejection and permeate flux of both membranes, was investigated. Synthetic plating wastewater samples containing copper ($Cu^{2+}$) and nickel ($Ni^{2+}$) ions at various concentrations(1, 20, 100, 400 mg/L) were prepared and subjected to treatment by NF and RO in the pilot plant. The results showed that NF, RO process, with 98% and 99% removal for copper and nickel, respectively, could achieve high removal efficiency of the heavy metals.

Biodecolorization and Biodegradation of Dye by Fungi: A Review (곰팡이를 이용한 염료의 탈색 및 생분해)

  • Cho, Kyung-Suk;Ryu, Hee Wook
    • KSBB Journal
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    • v.30 no.5
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    • pp.203-222
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    • 2015
  • In recent years, there has been an intensive research on the application of degradative activities of fungi for treatment of various non-degradable materials such as petroleum hydrocarbons, polychlorinated biphenyls, pesticides, polycyclic aromatic hydrocarbons, dyes and so on. Chief of all, the fungal treatment technology is received the spotlight as one of the most promising alternatives to replace present methods for the treatment of dye wastewater. The present paper reviews the recent trend in research on the decolorization and biodegradation of dyes by various fungi, and improvements in bioreactors and bioprocesses involved the fungal treatment of dye wastewater. It also discusses alternatives and perspectives for the innovation of mycoremediation to treat dye wastewaters.

Evaluation of operating performance of secondary effluents treatment membrane system adapted chemical backwashing (약품역세를 적용한 하수재이용 막여과 시스템의 운전성능 평가)

  • Kim, Young-Hoon;Lee, Chang-Ha;Jeon, Min-Jung;Lee, Yong-Soo;Lee, Eui-Jong;Nam, Jong-Woo;Kim, Hyung-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.335-342
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    • 2011
  • Secondary effluent contains particle compounds which are comprised of microorganisms that occurs membrane fouling when the water is reused. This study evaluates the characteristics of membrane fouling of secondary effluent reuse. Effects of chemical backwashing are analyzed to reduce membrane fouling by regular chemical backwashing. As the result, major membrane foulants are verified EPS materials which include protein and polysaccharide that cause biofilm cake layer on the membrane. Also, sodium hypochlorite is applied to chemical backwashing. The backwashing improves recover rate when injected chemical concentration is increased and chemical backwashing cycle is amplified. Chemical backwashing cycle affects more than injected chemical concentration yet idle time does not noticeably influence on reducing membrane fouling.

Changes of Chemical Characteristics of the Industrial Wastewater Sludge in Soil (공단폐수슬러지의 토양중 화학적 특성 변화)

  • Lee, Hong-Jae;Cho, Ju-Sik;Heo, Jong-Soo
    • Journal of Environmental Science International
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    • v.5 no.4
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    • pp.525-533
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    • 1996
  • Chemical characteristics of the industrial wastewater sludge, degradation of the sludge in soil and CO2 generation and changes of nitrogen in soil treated with the sludge were investigated. The results obtained were summarized as follows: 1. Degradation rate of the sludge in soil was 26% at natural temperature, and 33% at incubation temperature at 12 weeks after treatment. 2. T-C, T-N and the C/N ratio of sludge in soil was 16.0%, 0.63% and 26, respectively, at natural temperature, and 15.0%, 0, 65% and 23, respectively, at incubation temperature at 12 weeks after treatment. 3, Camulative CO2 generation in soil treated with l%, 3% and 5% of sludge was 284, 440 and 512 mg/100 g, respectively, at natural temperature, and 440, 558 g and 654 mg/100g, respectively, at incubation temperature at 12 weeks after treatment. 4, Changes of :norganic nitrogen in soil treated with l%, 3% and 5% of sludge were 7.8, 12.8 and 16.3 mg/100g, respectively, at incubation temperature at 12 weeks after treatment. Mineralization ratio of organic nitrogen in soil treated with 1%, 3% and 5% of sludge was 10.7%, 13.6% and 15.2%, respectively, at incubation temperature at 12 weeks after treatment. 5. Chanties of pH in soil treated with 1%, 3% and 5% of Industrial wastewater sludge were in the range of 6.7~7, 5 at natural temperature, and 6.1~7.9 at incubation temperature at 12 weeks after treatment.

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