• Title/Summary/Keyword: Chemical state

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Effect of activated carbon modified with oxalic acid on the production of IPA from MX catalyzed by H3PW12O40@carbon and cobalt

  • Fang, Zhou-wen;Liu, Hua-jie;Wang, Zhi-hao;Wen, Di;Long, Xiang-li
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.87-98
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    • 2018
  • The production of IPA from the oxidation of MX is completed under the catalysis of $H_3PW_{12}O_{40}$ (HPW) loaded on carbon and cobalt. Oxalic acid is tried to modify the carbon to upgrade the catalytic activity of HPW@C catalyst. The experiments show that the best carbon is acquired by carbonizing the carbon at $450^{\circ}C$ for 2 h in $N_2$ after being soaked in a $0.20mol\;l^{-1}$ oxalic acid solution for 16 h. The IPA produced by the HPW@C catalysts prepared with the carbon modified is 58.9% over that obtained by the catalysts prepared with the original carbon.

Chemical Shift and Quadrupolar Interactions in Solids

  • Kim Jin-Eun
    • Journal of the Korean Magnetic Resonance Society
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    • v.10 no.1
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    • pp.1-37
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    • 2006
  • General expressions for solid state NMR lines are described for transitions under static, magic angle spinning, and variable angle spinning conditions in the case where the principal axis system for the anisotropic chemical shift tensor is noncoincident with that of the quadrupole coupling tensor. It is demonstrated that solid state NMR powder pattern simulation program VMAS based on the conventional grid point method of integrating over the Euler angle space is fast enough in comparison with the POWDER simulation package and Gauss-point method.

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Utilization of Some Industrial Wastes for Producing of Polymeric Composite Materials

  • Hojieva, Alohida;Rustamov, Abduvali;Ahmedov, Akmal
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.95-98
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    • 2003
  • Polymeric composite materials on the basis of some industrial wastes are obtained. Some physical parameters of experimental samples are determined. The analysis of exploitative properties of these polymer composite materials allows recommending them as a heat-insulating material in constructions.

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Single-Layer Color Cholesteric Liquid Crystal Displays

  • Lu, Shin-Ying;Lin, Yu-hui;Chien, Liang-Chy
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.982-985
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    • 2007
  • The authors report methods of fabrication singlelayer color cholesteric liquid crystal displays (CLCDs). A single-layer CLCD has been prepared from a polymerstabilized cholesteric liquid crystal. The unique feature of the polymer stabilization is in that the electrically switched colors preserve high reflectivity. A bistable single-layer CLCD has been prepared by the formation of polymer barrier walls and light-tuned cholesteric pitches to reflect blue, green and red color sub-pixels.

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Chemical Substitution Effect on Energetic and Structural Differences between Ground and First Electronically Excited States of Thiophenoxyl Radicals

  • Yoon, Jun-Ho;Lim, Jeong Sik;Woo, Kyung Chul;Kim, Myung Soo;Kim, Sang Kyu
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.415-420
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    • 2013
  • Effect of chemical substitution at the para-position of the thiophenoxyl radical has been theoretically investigated in terms of energetics, structures, charge densities and orbital shapes for the ground and first electronically excited states. It is found that the adiabatic energy gap increases when $CH_3$ or F is substituted at the para-position. This change is attributed to the stabilization of the ground state of thiophenoxyl radical through the electron-donating effect of F or $CH_3$ group as the charge or spin of the singly-occupied molecular orbital is delocalized over the entire molecule especially in the ground state whereas in the excited state it is rather localized on sulfur and little affected by chemical substitutions. Quantitative comparison of predictions based on four different quantum-mechanical calculation methods is presented.

Enhanced Virus Removal by Flocculation and Microfiltration

  • Han Binbing;Carlson Jonathan O.;Powers Scott M.;Wickramasinghe S. Ranil
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.1
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    • pp.6-9
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    • 2002
  • In this work we have investigated the feasibility of virus clearance by flocculation and tangential flow microfiltration. Chinese hamster ovary cell feed streams were spiked with minute virus of mice and then flocculated using cationic polyelectrolytes prior to tangential flow microfiltration. Our results indicate that flocculation prior to microfiltration leads to more than 100 fold clearance of minute virus of mice particles in the permeate. Today, validation of virus clearance is a major concern in the manufacture of biopharmaceutical products. Frequently new unit operations are added simply to validate virus clearance thus increasing the manufacturing cost. The results obtained here suggest that virus clearance can be obtained during tangential flow microfiltration. Since tangential flow microfiltration is frequently used for bioreactor harvesting this could be a low cost method to validate virus clearance.

Lyotropic Chromonic Liquid Crystals in Aligned Films for Applications as Polarizing Coatings

  • Schneider, Tod;Golovin, Andrii;Lee, Jong-Chan;Lavrentovich, Oleg D.
    • Journal of Information Display
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    • v.5 no.2
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    • pp.27-38
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    • 2004
  • We describe dried oriented films with anisotropic structural and optical properties prepared from the aqueous solutions of plank-like molecules, the so-called Lyotropic Chromonic Liquid Crystals (LCLCs). The dried LCLC films may be used as optical elements, such as polarizers, compensators, color filters, or retardation plates in the UV, visible, or infrared parts of spectrums. The optical quality of the films is determined by the uniformity of the molecular alignment, which often distorted by periodic variations of the director field. We describe different ways to improve the alignment properties of the films by using additives. We present compositions capable of polarizing effects in visible and UV parts of spectrum.