• Title/Summary/Keyword: Chemical stability

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Thermal Stability and Fracture Toughness of Epoxy Resins Modified with Epoxidized Castor Oil and Al2O3 Nanoparticles

  • Zhu, Lin;Jin, Fan-Long;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2513-2516
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    • 2012
  • This study examined the effects of the epoxidized castor oil (ECO) and $Al_2O_3$ content on the thermal stability and fracture toughness of the diglycidylether of bisphenol-A (DGEBA)/ECO/$Al_2O_3$ ternary composites using a range of techniques. The thermal stability of the composites was decreased by the addition of ECO and $Al_2O_3$ nanoparticles. The fracture toughness of the composites was improved significantly by the addition of ECO and $Al_2O_3$ nanoparticles. The composite containing 3 wt % $Al_2O_3$ nanoparticles showed the maximum flexural strength. Scanning electron microscopy (SEM) revealed tortuous cracks in the DGEBA/ECO/$Al_2O_3$ composites, which prevented deformation and crack propagation.

Influence of Physical Load on the Stability of Organic Solar Cells with Polymer : Fullerene Bulk Heterojunction Nanolayers

  • Lee, Sooyong;Kim, Hwajeong;Kim, Youngkyoo
    • Current Photovoltaic Research
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    • v.4 no.2
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    • pp.48-53
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    • 2016
  • We report the effect of physical load on the stability of organic solar cells under physical loads. The active layers in organic solar cells were fabricated with bulk heterojunction films (BHJ) films of poly (3-hexylthiophene) and phenyl-$C_{61}$-butyric methyl ester. The loading time was varied up to 60 s by keeping the physical load constant. Results showed that the open circuit voltage was not influenced by the physical load but other solar cell parameters were sensitive to the loading time. The fill factor was very slightly increased at 15 s, while short circuit current density was well kept for 30 s. The power conversion efficiency was reasonably maintained for 45 s but became significantly decreased by the continuous loading for 60 s.

Nonlinear Optical Polymers Possessing Thermal and Temporal Stability: Potentials and Prospect

  • Kim, Dong-Wook;Ju, Hyun-Kyung;Ahn, Soo-Mi;Yoon, Sung-Cheol;Lim, Jong-Sun;Park, Seung-Ku;Lee, Chang-Jin
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.165-165
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    • 2006
  • We prepared nonlinear optical (NLO) polymers possessing thermal and temporal stability, which were based on the polyimides appended with NLO chromophores. NLO chromophores with a terminal hydroxyl group have been synthesized by coupling between aminobenzene or julolidine donor and phenylene bridge, and then subsequent coupling between the resulting product and tricyanofuran acceptor. The chromophores were chemically bonded to the polyimides backbone through Mitsunobu reaction. The NLO polymers showed $160-170^{\circ}C$ of Tgs and were thermally stable up to $200^{\circ}C$. We obtained optical quality films by spincoating and evaluated their electro-optical properties and temporal stability.

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An Experimental Study on IMO 2nd Generation Stability Assessment in Dead Ship Condition of 13K Chemical Tanker (13K Chemical Tanker의 기관 제어 불능상태 IMO 2세대 안정성 평가에 관한 실험적 연구)

  • Lee, Sang-Beom;Moon, Byung-Young
    • Journal of the Society of Naval Architects of Korea
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    • v.59 no.2
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    • pp.89-95
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    • 2022
  • The stability of the existing ships has been evaluated through numerical calculations in the steady-state, but recently the IMO proposed a new stability assessment criteria that the stability is evaluated in the state in which environmental loads from such as waves and wind act like the loads under actual ship operating conditions. In this study, IMO 2nd generation stability assessment method and procedure were summarized for the dead ship condition, and Direct Stability Assessment (DSA) was performed on 13K chemical tanker through basin model test. The model test is performed in the ocean engineering basin to implement wave and wind loads, and environmental conditions for waves were set height and period of the incident wave, considering the regular wave and wind generation range reproducible in the ocean engineering basin. In addition, to consider the effect of wind speed, the Beaufort Scale for wind speed was applied in the model test.

Energy Stability Analysis on the Onset of Buoyancy-Driven Convection in a Horizontal Fluid Layer Subject to Evaporative Cooling

  • Kim, Min Chan
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.142-147
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    • 2019
  • The onset of buoyancy-driven convection in an initially isothermal and quiescent horizontal fluid layer was analyzed theoretically. It is well-known that at the critical Rayleigh number $Ra_c=669$ convective motion sets in with a constant-heat-flux cooling through the upper boundary. Here, based on the momentary instability concept, the dimensionless critical time ${\tau}_m$ to mark the onset of convective motion for Ra > 669 was analyzed theoretically. The energy method under the momentary stability concept was used to find the critical conditions as a function of the Rayleigh number Ra and the Prandtl number Pr. The predicted critical conditions were compared with the previous theoretical and experimental results. The momentary stability criterion gives more reasonable wavenumber than the conventional energy method.

Influence of Sediment on the Chemical Speciation of Copper and Cadmium in an Aquatic System (저질이 천연수중 구리와 카드뮴의 화학종 분포에 미치는 영향)

  • 이군자;박청길
    • Journal of Environmental Science International
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    • v.1 no.2
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    • pp.59-69
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    • 1992
  • In order to predict the distribution of chemical species of copper and cadmium in water, conditional stability constant and complexation capacity between copper or cadmium and natural aquatic sediment have been determined in a shallow lake in Haman, Kyungnam. Kinetic parameters were calculated by Langmuir isotherm equation. Conditional stability constant was log $K_{cuSed}=4.78 and log K_{cdSed}=4.45$. Complexation capacity was $1.70{\times}10^{-4}$moles/g for copper and $5.54{\times}10^{-5}$moles/g for cadmium. Accuracy of experimental values of conditional stability constant was checked by comparing the calculated concentration of the metals with the measured one. Relatively good agreement between these values was obtained. Relative errors were 8.9% for copper and 6.5% for cadmium. Data of the measured conditional stability constant were put into data base of MINEQL computer program, and concentration of various chemical species of copper and cadmium in a model aquatic system was calculated. Aquatic sediment was associated with copper at the concentration of $10^{-5M}(0.059g/\ell)$10-5M(0.059g/l) and with cadmium at the concentration of $10^{-6M}(0.018g/\ell)$, and it significantly influenced on the distribution of chemical species of the metals. This result showed that prediction of chemical species of the heavy metals in an aquatic system should be taken into account the influence of the sediment.

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