• Title/Summary/Keyword: Chemical spills

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A Comparative Analysis on the Education Contents of Domestic and Foreign Training Institutions in Response to Marine Chemical Incidents (국내외 기관별 해상화학사고 대응 교육내용에 관한 비교분석)

  • Kim, Kwang-Soo;Lee, Moonjin;Park, Jinhyung
    • Proceedings of KOSOMES biannual meeting
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    • 2017.11a
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    • pp.165-165
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    • 2017
  • As marine chemical spill incidents increase, and damages caused by chemical spills become bigger and bigger, it is required to educate and train professional personnel for response to chemical spill incidents at sea. In this study, the education contents of domestic and foreign institutions for the training of specialists in response to marine chemical accidents were examined, and a comparative analysis of education and training contents was carried out in order to utilize it in the development of domestic education and training materials for HNS response personnel in Republic of Korea.

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Statistical Analysis of Chemical Substance Transporting Accidents (화학물질 운송 화학사고의 통계 특성 분석에 관한 연구)

  • Lee, Tae-Hyung;Lee, Sang-Jae;Shin, Chang-Hyun
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.23-30
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    • 2016
  • This study analyzed the characteristics of chemical accidents, including the accidents occurring each year according to status, type of accident, accident cause for chemical substance transporting accidents. The major aim of this study was to provide information on the chemical accidents that occurred involving chemical substance transporting accidents from 2013 to July - 2016. The total incidence of chemical transporting accidents was 77 cases; 74 cases occurred by the spill & leakage type. The main cause of the accidents analyzed was traffic accidents (41 cases). Forty-six accidents were related to hazardous chemical substances. Among the 46 hazardous chemical substances involved in transporting chemical accidents, 46% of the accident substances were hydrogen chloride. For the prevention and response to accidents occurring during the transportation of chemicals, it is necessary to complement the precautions for chemical accidents caused by transportation accidents and chemical spills and leaks of chemicals. In addition, when the chemical transport of an accident occurs, it is necessary to apply a chemical transport safety system for chemical transfer.

Study fo the Characteristics Analysis of Laboratory Chemical Accidents (실험실 화학사고 특성 분석에 관한 연구)

  • Lee, Tae-Hyung;Lee, Deok-Jae;Park, Joong-Don;Shin, Chang-Hyun
    • Fire Science and Engineering
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    • v.30 no.3
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    • pp.110-116
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    • 2016
  • The major aim of this study was to provide information on the chemical accidents that occurred in laboratories over the last 3 years. The total incidence of laboratory chemical accidents was 30 cases; 25 cases occurred at educational institutions. Most accidents (19 cases) occurred due to spills and leaks. The main cause of the accidents analyzed was worker carelessness (21 cases). Twenty-two accidents were related to hazardous chemical substances. In addition, general chemical substances as well as waste liquid contributed 26% to the incidents related to the laboratory. Among the 22 hazardous chemical substances involved in laboratory chemical accident, 67% of accident substances were accident preparedness substances.

The Relationship between Workers' Safety Behaviors and Safety Climate in Chemical Industry (화학산업 작업자의 안전행동과 안전분위기의 상관관계)

  • Baek, Jong-bae;Uhm, Minyong;Kim, Ji-sun
    • Journal of the Korean Society of Safety
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    • v.30 no.5
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    • pp.100-107
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    • 2015
  • Korea government has established and enforced countermeasures about the various policy of industrial accident prevention. Recent chemical accidents included hazardous materials. Exposure to these chemicals can cause serious environmental poisoning and various health problems. The key factor causing these major accidents may be associated with the mistake in workers' safety behaviors. Some researchers noted workers' safety behaviors may be related to workers' safety climate. In this research, a survey was conducted to explore workers' safety behaviors and safety climate in a large petrochemical company in Korea. The company processes major petrochemical materials and any spills can be hazardous and cause chemical disasters. In this study, we explored one petrochemical company to investigate three hypotheses. 593 workers were surveyed for this study. We checked association between workers' safety behavior and safety climate. The survey result shows the people who have safety climate do safe behavior.

A Mathematical Model Proposed for the Prediction of the Fate of Priority Organic Pollutants Spilled in Streams: Dynamic Simulations and Sensitivity Analysis (하천에 유입된 유독성 유기오염물의 농도분포를 예측하기 위한 수학적 모형의 개발: Dynamic simulations 및 민감도 분석)

  • Ko, Kwang Baik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.2
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    • pp.265-274
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    • 1992
  • A mathematical model was proposed to predict the fate of a priority organic pollutant, anthracene, accidently spilled into a stream. The model consists of 6 differential equations with 5 input variables and 9 rate constants. Volatilization, biodegradation, adsorption/desorption, photodegradation as well as the convective inputs and outputs are included in the model. As a result of a series of dynamic simulations and sensitivity analyses under the given conditions, the concentrations of the organic chemical could be predicted within a detection limit in the stream. It was also suggested that the rate constant for diffusion/transport and adsorption rate constant are the most influential ones for predicting the chemical conentrations in dissolved and particulate phase. The model proposed appears to be a useful tool for assessing chemical spills.

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A Study on Development of Database for the Characteristics of Hazardous Chemicals (유해화학물질 특성정보 데이터베이스 구축 연구)

  • Han, Jong-Yup;Song, Ki-Sup;Kang, Sung-Hyun
    • Journal of Information Management
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    • v.28 no.2
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    • pp.1-19
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    • 1997
  • A late-comer in the marine affairs, development of ways for efficient access and utilization of information on marine environmental conservation and pollution prevention is important. The properties and removal methods of toxic chemicals have been entered into the database for 1,000 substances. The database of toxic chemicals for pollution and spills has also been fortified for the following terms: general characteristics, health hazard and response, fire hazard and response, chemical reactivity, physico-chemical properties, and other properties. The information and data running in this database are easily accessible via Internet and Korean telecommunications companies; it is also available KRISTAL databases.

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Principles of Chemical Risk Assessment: The ATSDR Perspective

  • Johnson Barry L.
    • 대한예방의학회:학술대회논문집
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    • 1994.02a
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    • pp.405-411
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    • 1994
  • Hazardous wastes released into the general environment are of concern to the public and to public health authorities. In response to this concern, the Comprehensive Environmental Response, Compensation, and Liability Act, as amended (commonly called Superfund), was enacted in 1980 to provide a framework for environmental, public health, and legal actions concerning uncontrolled releases of hazardous substances. The Agency for Toxic Substances and Disease Registry (ATSDR) was created by Superfund to address the public health issues of hazardous wastes in the community environment. Two key Agency programs, Public Health Assessments and Toxicological Profiles, are designed to assess the risk to human health of exposures to hazardous substances that migrate from waste sites or through emergency releases (e.g., chemical spills). The Agency's public health assessment is a structured process that permits ATSDR to identify which waste sites or other point sources require traditional public health actions (e.g.. human exposure studies, health studies, registries, health surveillance, health advisories). The ATSDR qualitative public health assessment complements the U.S. Environmental Protection Agency's quantitative risk assessment. For Superfund purposes, both assessments are sitespecific. ATSDR's toxicological profiles are prepared for priority hazardous substances found most frequently at Superfund sites. Each profile presents the current toxicologic and human health effects information about the substance being profiled. Each profile also contains Minimal Risk Levels (MRLs), a type of risk assessment value. This paper covers ATSDR's experience in conducting public health assessments and developing MRLs, and it relates this experience to recommendations on how to improve chemical risk assessments.

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Effectiveness of Dispersants for Very-Low-Sulfur Fuel Oil (저유황유(VLSFO)의 유처리제 효용성 연구)

  • Kim, Deuksan;Seo, Jeong Mog;Ahn, Suhyun;Lee, Heejin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.1
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    • pp.113-118
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    • 2021
  • The International Maritime Organization (IMO) has confirmed a global limit of 0.5 % for sulfur in fuel oil used on board ships with effect from January 1, 2020. Among various alternatives to respond to these regulations on sulfur content in fuel oil, such as LNG ships, SOx scrubbers, and very-low-sulfur fuel oil (VLSFO). VLSFO is preferred owing to its low investment costs. As more ships are expected to use VLSFO, VLSFO spills are expected to increase. In particular, when the seawater temperature is below the pour point of VLSFO, VLSFO solidifies when it is spilled, which makes controlling spills difficult. In this study, six types of VLSFO produced in Korea and one type of high-sulfur fuel oil (MF380) were compared in terms of the dispersibility of dispersants according to the seawater temperature conditions. The results confirmed that the six type of VLSFO did not satisfy the domestic standards for dispersant rate (60 % or more for 0.5 min, 20 % or more for 10 min). Morever, the dispersant rate of the six types of VLSFO was low compared with that of the high-sulfur fuel oil. The results of this study are expected to be used to set the direction of dispersant control in the case of VLSFO spills.

Biopile을 이용한 유류 오염토양의 복원에 관한 연구

  • 박종천;오재영;정용욱;이우범
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.310-314
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    • 2002
  • To investigate the effect of on-site bioremediation in soil that have been contaminated by hydrocarbon fuel spills, petroleum-degrading bacteria isolated from soil around petroleum chemical industry and microbial agents were constructed. We investigated biopiles for on-site bioremediation of soil contaminated (5000 mg per kg) with bunker A fuel in five independent lab-scale experiments. Five biopile units constituting the following treatments: (1) control with no nutrients and microbial agents (2) microbial agent M plus nutrients (3) microbial agent C plus nutrients (4) only microbial agent C (5) control with only nutrients. The results were highly different one another. After 30 days in treatments with optimal condition, total petroleum hydrocarbons were reduced to below 10 mg per kg of soil at the biopile units mixed with microbial agents, but control biopile units show that were reduced from 1,105 to 2,588 mg per kg of soil. Our results show that microbial agents at on-site bioremediation of fuel-contaminated soil is highly effective.

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Research on Dielectric Characteristics of Environmental-Friendly Vegetable Insulation Oil for the Pole Transformer (주상변압기 적용을 위한 친환경 식물성절연유의 절연특성 연구)

  • Kwag, Dong-Soon
    • Journal of the Korean Society of Safety
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    • v.25 no.6
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    • pp.81-85
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    • 2010
  • In recent years, environmental concerns have been raised on the use of poorly biodegradable fluids in electrical apparatus in regions where spills from leaks and equipment failure could contaminate the surroundings. The vegetable insulation oils are highly biodegradable, have negligible effect on the environment, human health and ecosystem. Therefore, to assure their safe use in electrical power systems, it may require some processing and modification to improve some of their physical, chemical, thermal and electrical properties. This paper provides a comparative results of the electrical breakdown properties of several vegetable insulation oils and mineral oil to use as dielectric fluid in environmental-friendly pole transformer. Also, the electrical breakdown property of the Nomex and kraft insulation papers in vegetable insulation oil is examined.