• Title/Summary/Keyword: Chemical species

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Isolation of Flavonol Rhamnosides from Loranthus tanakae and Cytotoxic Effect of Them on Human Tumor Cell Lines

  • Kim, Young-Kyoon;Kim, Young-Sup;Choi, Sang-Un;Ryu, Shi-Yong
    • Archives of Pharmacal Research
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    • v.27 no.1
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    • pp.44-47
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    • 2004
  • Loranthus tanakae Fr. et Sav. (Loranthaceae) is a species of mistletoe, a semiparasitic plant growing on the branches of Quercus and Betula species as host trees. In our ongoing search for bioactive compounds from endemic species in Korea, we have investigated to isolate the chemical constituents responsible for the antitumor effect of the MeOH extract of L. tanakae. The ethyl acetate soluble part of the MeOH extract demonstrated a marginal inhibition on the proliferation of the tumor cell lines such as A549 (non small cell lung), SK-OV-3 (ovary), SK-MEL-2 (melanoma), XF498 (central nerve system), and HCT-15 (colon) in vitro. Thus, the activity-guided isolation procedure upon the ethyl acetate soluble part of the extract has been carried out and finally four flavonoid rhamnopyranosides (1-4) were isolated as active principle. The structures of 1-4 were elucidated by the physicochemical and spectral data as rhamnetin 3-O-$\alpha$-L-rhamnoside (1), quercetin 3-O-$\alpha$-L-rhamnoside (2), rhamnocitrin 3-O-$\alpha$rhamnoside (3), and kaempferol 3-O-$\alpha$-L-rhamnoside (4).

Change of Predator Recognition Depends on Exposure of Predation Risk Source in Captive Breed Endangered Freshwater Fish, Microphysogobio rapidus (인공증식된 멸종위기종 여울마자의 포식 위험원 노출에 따른 포식자 인지 변화)

  • Moon-Seong Heo;Min-Ho Jang;Ju-Duk Yoon
    • Korean Journal of Ecology and Environment
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    • v.56 no.4
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    • pp.406-413
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    • 2023
  • Captive breeding and reintroduction are crucial strategies for conserving endangered species populations. However, fish raised in predator-free environments, show a lack of recognition of predationrelated stimuli such as chemical and visual signals. It is critical to recognize chemical signals from injured conspecifics, also known as alarm signals, and the order or shape of predators to indicate the spread of predation risk in the habitat. We conducted a laboratory experiment to determine and adjust the optimal exposure period to induce appropriate anti-predator behavior response to different types of stimuli (Chemical, Visual and Chemical+Visual) for the endangered species Microphysogobio rapidus. Our results demonstrate that predator avoidance behavior varies depending on the types of stimuli and the duration of predation risk exposure. First, the results showed captive-breed M. rapidus show lack of response against conspecific alarm signal (Chemical cue) before the predation risk exposure period and tend to increase response over predation risk exposure time. Second, response to predator (visual cue) tend to peak at 48 hours cumulative exposure, but show dramatic decrease after 72 hours cumulative exposure. Finally, response to the mixed cue (Chemical+visual) tend to peak prior to the predation risk exposure period and show reduced response during subsequent exposure periods. This experiment confirms the lack of responsiveness to conspecific alarm signals in captive-bred M. rapidus and the need for an optimal nature behavior enhancement program prior to release of endangered species. Furthermore, responsiveness to predator visual signal peak at 48 hours cumulative exposure, suggest an optimal predation risk exposure period of up to 48 hours.

Two-dimensional continuum modelling of an inductively coupled plasma reactor

  • Kim, Dong-Ho;Shung, Won-Young;Kim, Do-Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.2
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    • pp.128-133
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    • 2000
  • Numerical analysis of the transport phenomena in an inductively coupled plasma reactor was conducted with two-dimensional axisymmetric model including the electromagnetic field model, electron and species density models. The spatial distribution of the charged species in the ion flux to the wafer have been calculated to examine the influence of the process conditions including antenna and reactor geometry. The antenna radius had a significant influence on the plasma state and axial ion flux distribution.

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The Effect of CVD Reaction Variable on SnO2 Powder Characteristics

  • Kim, Kyoo-Ho
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.235-239
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    • 1998
  • Ultrafine $SnO_2$ powder was prepared by the diffusion mixing gas-phase reaction of $SnCl_4$(g) and water vapor. The effects of reaction variables, such as the chloride partial pressure, the reaction temperature, and the residence time is the reactor, on the powder size were examined systematically. Calculated concentration and distribution of chemical species, using the Burke-Schumann diffusion mixing model, were compared with the experimetal results. The effects of the reaction variables on the powder size were also discussed qualitatively.

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Leucine Rich Repeat Sequence of the ${\delta}$ Endotoxin Family of Bacillus thuringiensis

  • Vudayagiri, Suvarchala;Jamil, Kaiser
    • BMB Reports
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    • v.33 no.1
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    • pp.89-91
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    • 2000
  • In this investigation we report our search for the presence of Leucine Rich Repeats (LRRs) in various Bacillus thuringiensis (Bt) sub species. Leucine rich repeats are short sequence motifs present in some proteins. The consensus sequence corresponding to the LRR was present in Crystal proteins of Bacillus thuringiensis sub species. This LRR sequence has been predicted to be involved in proteinprotein interactions or receptor binding functions, hence the importance of this study.

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Point Particle Approximation for Single and Two Species Diffusion-Influenced Reactions

  • Kim, Hyojoon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1454-1456
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    • 2013
  • The fluctuations in concentrations of reactants dominate the long-time dynamics of the single (A + A ${\rightarrow}$ 0) and two species (A + B ${\rightarrow}$ 0) diffusion-influenced annihilation reactions. Although hierarchical Smoluchowski approaches can provide a systematic and flexible framework to deal with the fluctuation effects, their results are too complicated to be analytically solved. For the efficient numerical calculation of the complicated fluctuation effect terms, we show that the presented point particle approximation is not only practical but also quite accurate for most conditions in diffusion-influenced reaction systems.

Electrochemical and Spectrophotometric Studies on Polyaniline and its Degradation

  • Jung-Kyoon Chon;Byung-Hoon Min;Woon-Kie Paik
    • Bulletin of the Korean Chemical Society
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    • v.11 no.2
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    • pp.105-108
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    • 1990
  • A spectroelectrochemical study on the redox chemistry of polyaniline (PANI) was carried out by using indium-tin oxide (ITO) transparent electrode in aqueous acidic solutions. Three different PANI-derived species were observed depending on the potential. The most highly oxidized species having alternating benzenoid-quinoid structures degraded through hydrolysis reaction. The degradation products were confirmed to be p-benzoquinone (BQ) and p-diaminobenzene (PDAB) by spectrophotometry anld potentiostatic experiments. Finally, a degradation mechanism is deduced from the observed behaviour.

Spatial Distribution of Excited Argon Species in and Inductively Coupled Plasma

  • 최범석
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1172-1174
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    • 1998
  • Spatial(radial and height) distributions of excited argon species are measured for an inductively coupled plasma under five operating conditions: 1) no carrier gas, 2) carrier gas without aerosol, 3) carrier gas with desolvated aerosol, 4) carrier gas with aerosol, 5) carrier gas with aerosol and excess lithium. A complete RF power mapping of argon excited states is obtained. The excited states of argon for a typical analytical torch rapidly diffuse towards the center in the higher region of the plasma. The presence of excess lithium makes no significant change in the excited states of argon. The increase in the RF power increases the intensity of argon excited states uniformly across the radial coordinate.

Reactions of 〔(2-N, N-Dimethylaminomethyl)phenyl〕methylvinychlorosilane with t-BuLi: Synthesis and Characterization of Five Isomeric 1,3-Disilacyclobutanes.

  • Lee, Myeong Yu;Jo, Hyeon Mo;Lee, Su Heung;Kim, Jang Hwan
    • Bulletin of the Korean Chemical Society
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    • v.22 no.6
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    • pp.593-596
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    • 2001
  • The reaction of [(2-N,N-dimethylaminomethyl) pheny] methylvinychlorosiane with t-BuLi in hexane solvent gave dimers, five isomeric 1,3-disilacyslobutanes which were weparated and charaterized. In trapping experiments with various trapping agents, no corresponding silene-trapping aduct was observed. We suggest that more important species for the formation of five isomeric dimers might be the zwitterionic species generated by virtue of intramolecular donor atom rather than the silene.

Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes

  • Kim, Gwang Yeon;Jo, Yung In;Bu, Du Wan
    • Bulletin of the Korean Chemical Society
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    • v.22 no.6
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    • pp.597-604
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    • 2001
  • The reaction of [(2-N,N-dimethylaminomethyl) pheny] methylvinychlorosiane with t-BuLi in hexane solvent gave dimers, five isomeric 1,3-disilacyslobutanes which were weparated and charaterized. In trapping experiments with various trapping agents, no corresponding silene-trapping aduct was observed. We suggest that more important species for the formation of five isomeric dimers might be the zwitterionic species generated by virtue of intramolecular donor atom rather than the silene.