• Title/Summary/Keyword: Chemical shrinkage

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A Study on the Mechanical Properties of Shrink-Resistant Wool Fabric Treated with Enzyme (효소에 의한 방축가공 양모직물의 물성 변화에 관한 연구)

  • 박미라;김환철;박병기
    • Textile Coloration and Finishing
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    • v.13 no.3
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    • pp.155-164
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    • 2001
  • Textile wet-processing industry usually five rise to environmental pollution problems caused by using chemical substance. The objective of this study is to apply enzymes for wool and reduce the environmental problems. Three commercial protein degradation enzymes and a cellulose degradation enzyme as a reference were treated to prevent the shrinkage of wool fabric on laundering. Shrink resistant effects used change with the kinds of enzyme, the amount of enzyme, assistant chemicals, and the pre-treatment condition of wool fabric. When pre-treated with corona before enzyme treatment under ultrasonic condition, the weight loss was increased and strength was decreased and elongation was increased. Both corona pre-treatment and the addition of $Na_2SO_4$ also decreased shrinkage of wool fabrics on laundering. The existence of assistant chemicals increased alkali solubility of wool fabrics.

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Effects of Riser Design and Chemical Composition on the Formation of Shrinkage Cavity in Gray and Ductile Iron Castings

  • Yu, Sung-Kon
    • Journal of Korea Foundry Society
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    • v.24 no.2
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    • pp.101-107
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    • 2004
  • 회주철 및 구상흑연주철에 있어서 압탕방안 및 합금원소가 수축결함의 생성에 미치는 영향을 연구하였다. 두 종류의 압탕방안으로 실린더형상의 계단상시편을 제조하였으며 회주철의 경우 5조성(ISO 150, 200, 250, 300, 350), 구상흑연주철의 경우 6조성(SG 10, 20, 30, 40, 50, 60)을 사용하였다. 회주철 및 구상흑연주칠 공히, 1차 압탕방안의 경우 액상수축에 의한 1차수축결함이 후육부의 표면에 발생하였으며 수축결함의 내면은 매끄러웠다. 회주철의 경우 응고수축에 의한 2차수축결함은 생성되지 않았으나 구상흑연주철의 경우 모든 시편의 내부열점에 2차수축결함이 발생하였고 그 내면은 거칠었다. 2차압탕방안의 경우 회주철의 모든 시편에서는 1차 및 2차수축결함이 발생되지 않았다. 그러나 구상흑연주철의 경우 탄화물 생성원소가 첨가된 SG 40, 50 및 60의 3조성에서 2차수축결함이 열점에 생성되었다. 견고한 ���V주형을 사용하였기 때문에 주형벽이동으로 인한 표면팽창은 어느 경우에도 관찰되지 않았다.

Abrasion Resistant Paver Production Utilising Modern Brickmaking Technology: Possibilities and Difficulties

  • Ozucelik, Nazmi
    • The Korean Journal of Ceramics
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    • v.4 no.4
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    • pp.368-371
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    • 1998
  • The work aims to evaluate the necessary physical properties of Abrasion Resistant Pavers designed for high volume pedestrian and road vehicle traffic and their influence on the selection of raw materials and ceramic processes. The pavers' specifications such as high strength and ware resistance demand a careful clay preparation, slow drying, slow firing and a balanced chemical and mineralogical composition. Therefore, developing abrasion Resistant Pavers in existing modern brickmaking plants, which are designed primarily for making bricks and pavers for domestic applications, has become a challenge for manufacturers and ceramic professionals. The significance of quality control and research and development in the production of these high class pavers is also emphasised in this work through the investigation of a paver that exhibits shrinkage cracking.

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Effects of Alkaline Earth Oxides on Electrical Characteristics of Steatite Porcelain (Steatite 자기의 전기적 특성에 미치는 알칼리 토금속 산화물의 영향)

  • 이종근;이병하;전승관
    • Journal of the Korean Ceramic Society
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    • v.16 no.1
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    • pp.31-37
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    • 1979
  • The middle point of composition within the system $MgO-Al_2O_3-SiO_2$ has been studied for applicability as ceramics dielectrics. A Kyul Sung Tale of high purity, magnesia clinker of Sam-wha chemical company, C.P. aluminium oxide, calcium carbonate, red lead, barium carbonate which was made into frit were used the raw materials. A number of steatite ceramics were prepared under carefully controlled condition and the water absorption, linear shrinkage, power factor, dielectric constant and dielectric loss were measured at elevated temperature. When we used magnesia clinker as flux, the quantity of this flux was 0.05mole, sintering temperature was continued for 2 hrs. at 1, 27$0^{\circ}C$. From this conditions, we could get the data whose power factor was 0.142%, water absorption was zero, linear shrinkage was 8.76%, dielectric constant was 5.63, dielectric loss was 0.00799. When we used red lead as flux, the quantity of this flux was 0.033mole and 0.066mole, sintering temperature was continued for 2hrs. at 1, 26$0^{\circ}C$. From this conditions, we could get the data whose water absorption was zero, linear shrinkage was 8.03%, and 8.48%, power factor was 0.136% and 0.062%, dielectric loss was 0.0072 and 0.0037. When we used barium carbonate made into frit as flux, the quantity of this flux was 0.02mole, sintering temperature was continued for 2hrs. at 1, 27$0^{\circ}C$. From this conditions, we could get the data whose water absoption was zero, linear shrinkage was 8.44%, power factor was 0.138%, dielectric constant was 5.69, dielectric loss was 0.0074.

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Reduction of Proliferation and Induction of Apoptosis are Associated with Shrinkage of Head and Neck Squamous Cell Carcinoma due to Neoadjuvant Chemotherapy

  • Sarkar, Shreya;Maiti, Guru Prasad;Jha, Jayesh;Biswas, Jaydip;Roy, Anup;Roychoudhury, Susanta;Sharp, Tyson;Panda, Chinmay Kumar
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.11
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    • pp.6419-6425
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    • 2013
  • Background: Neoadjuvant chemotherapy (NACT) is a treatment modality whereby chemotherapy is used as the initial treatment of HNSCC in patients presenting with advanced cancer that cannot be treated by other means. It leads to shrinkage of tumours to an operable size without significant compromise to essential oro-facial organs of the patients. The molecular mechanisms behind shrinkage due to NACT is not well elucidated. Materials and Methods: Eleven pairs of primary HNSCCs and adjacent normal epithelium, before and after chemotherapy were screened for cell proliferation and apoptosis. This was followed by immunohistochemical analysis of some cell cycle (LIMD1, RBSP3, CDC25A, CCND1, cMYC, RB, pRB), DNA repair (MLH1, p53) and apoptosis (BAX, BCL2) associated proteins in the same set of samples. Results: Significant decrease in proliferation index and increase in apoptotic index was observed in post-therapy tumors compared to pre-therapy. Increase in the RB/pRB ratio, along with higher expression of RBSP3 and LIMD1 and lower expression of cMYC were observed in post-therapy tumours, while CCND1 and CDC25A remained unchanged. While MLH1 remained unchanged, p53 showed higher expression in post-therapy tumors, indicating inhibition of cell proliferation and induction of apoptosis. Increase in the BAX/BCL2 ratio was observed in post-therapy tumours, indicating up-regulation of apoptosis in response to therapy. Conclusions: Thus, modulation of the G1/S cell cycle regulatory proteins and apoptosis associated proteins might play an important role in tumour shrinkage due to NACT.

The appearance change and heat·moisture transfer properties of knitted fabric by yarn shrinkage (원사의 수축에 따른 다공성 편성물의 형태변화와 열·수분 전달특성)

  • Sang, Jeong-Seon;Park, Juhyun;Lee, Mee-Sik;Oh, Kyung Wha
    • The Research Journal of the Costume Culture
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    • v.25 no.6
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    • pp.880-892
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    • 2017
  • In this study, the appearance change and the heat moisture transfer properties of knitted fabric by yarn shrinkage were examined to obtain useful data on the development of thermo-sensitive functional materials. Eleven types of knitted fabric were knitted using highly bulky acrylic-blended yarn. After shrinking the specimens using dry heat treatment, the appearance change and thickness were measured. An HEC simulator was adopted for measuring the heat moisture transfer properties of specimens by yarn shrinkage. When holes were arranged vertically in the mesh structure, the specimens with 2,500 and 5,000 holes showed high percent change of hole area, appearance, and thickness. When holes were diagonally arranged in the mesh structure, the percent change of hole area in the specimen with 1,250 holes was larger than the one with 2,500 holes. However, the dimensional stability of the specimen with 2,500 holes was better because of its smaller appearance and thickness change. In the tuck structure, the percent change of hole area in the specimen with 625 and 416 holes was relatively large compared with the appearance and thickness change. Furthermore, the hole size in the tuck structure was smaller than that in the mesh structure but the percent change of hole area was larger. Therefore, it was proved that the tuck structure is more suitable than the mesh structure for developing thermo-sensitive functional materials. Heat moisture transfer property test verified that the change of hole area by yarn shrinkage enabled obtaining the thermal effect due to the distinct temperature difference in the inner layer.

Chemically Prestressed Precast Concrete Box Culvert with Expansive Additives

  • Park, Hong-Yong;Kim, Chul-Young;Park, Ik-Chang;Bae, Sang-Wook;Ryu, Jong-Hyun
    • KCI Concrete Journal
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    • v.13 no.1
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    • pp.43-51
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    • 2001
  • Although portland cement concrete is one of the most universal construction materials, it has some disadvantage such as shrinkage, which is an inherent characteristic. Because of this shrinkage, combined with the low tensile strength of the material, cracks of varying sizes can be found in every reinforced concrete. To prevent this cracking, keeping the concrete in compression by mechanical prestress has been used. This study discusses application of expansive additives for concrete to improve the serviceability of precast concrete box culvert by inducing chemical prestress. For this purpose, both expansive concrete slabs and normal concrete slabs are tested to verify the effect of expansive additives. Then the failure tests of the fullscale precast box culverts were carried out and the critical aspects of the structural behavior were investigated. The result of the material testis shows that the optimal proportion of expansive additives is 13 percent of cement weight, and the properties of expansive concrete are the same as those of normal concrete in that proportion. Both the experimental cracking load and service load of the expansive concrete members are increased in comparison with those of the normal concrete, but the ultimate load is decreased slightly. In addition to the above results, the deformation of expansive concrete member is lets than that of normal concrete member, and permanent strain which results from cyclic load is decreased. It can be concluded that the use of expansive additives to induce chemical prestress in precast concrete box culvert greatly improves the serviceability.

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Application of CAE in Injection Molding Process of Automobile Part (컴퓨터지원공학(CAE)을 활용한 자동차 부품 개선)

  • Cho, Junghwan;Chang, Woojin;Park, Young Hoon;Choe, Soonja
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.407-414
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    • 2007
  • Using the MPI (Moldflow Plastics Insight) software from Moldflow Co., the optimum conditions for producing the upper part of the automobile air cleaner were obtained for 20% talc filled polypropylene (PP). The analysis was carried out to solve the cracking problem between upper and lower parts and the improved process was proposed using the flow balance. The comparative results between the conventional process, CASE-1, with one-pin gate and the new process (CASE-2) comprising two-pin gate system are the followings. In the case of CASE-2, the shorter filling time and reduced cycle time induced an improved production and processibility. In addition, the orientation and volumetric shrinkage are similar to those observed in the lower part, but the assembly, deformation, and physical characteristics are enhanced. The problem induced by the CASE-1 did not originate from the residual stress, but from the difference in the size of the upper part air cleaner after shrinkage. Thus, the orientation problem was expected to improve by optimizing the gate structure.

Hybrid Biomaterial of PLGA Microspheres and Hyaluronic Acid as a Potential Injectable Bulking Agent for Urologic and Dermatologic Applications

  • Cho, Eui-Ri;Kang, Sun-Woong;Kim, Byung-Soo
    • 한국생물공학회:학술대회논문집
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    • 2003.10a
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    • pp.644-647
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    • 2003
  • Materials currently used as an injectable bulking agent in the dermatologic and urologic fields revealed several drawbacks such as particles migration, inflammatory reaction, allergic reaction, rapid volume shrinkage, and necessity of a donor site. In this study, we have developed injectable biomaterial comprising poly (DL- lactide-co-glycolide)(PLGA) and hyaluronic acid gel to overcome these problems. PLGA is a biocompatible synthetic material and hyaluronic acid is a common substance found in living organisms. We examined the feasibility of injection through needle and tested biocompatibility in animal model. After transplantation, injected sites and distant organs were examined histologically to verify a new tissue formation, inflammation, and particles migrations. Injected volume was maintained approximately 80 percent for 2 months. Results demonstrated that the developed material was injectable through various gauges of needles and induced a new bulking tissue formation without serious inflammatory reaction.

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Characteristics of Hydrogel Prepared from Microbial Poly($\gamma$-glutamic acid) by Chemical Crosslinker

  • Park, Jong-Soo;Choi, Seong-Hyun;Choi, Woo-Young;Yoon, Min-Ho
    • Journal of Applied Biological Chemistry
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    • v.48 no.4
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    • pp.213-217
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    • 2005
  • Microbial hydrogel was prepared with poly(${\gamma}$-glutamic acid) produced from Bacillus subtilis BS62 using crosslinking reagent, ethylene glycol diglycidyl ether (EGDE), and its physico-chemical characteristics were examined. Hydrogel which prepared from 10 grams of 10% PGA solution with $600\;{\mu}l$ of EGDE at $50^{\circ}C$ for 17 h swelled 4,320 times its dry weight, and time to reach swelling equilibrium in deionized water at 4 to $45^{\circ}C$ range was about 20 h. Swollen hydrogel shrunk in ionic solutions, and rate of shrinkage was higher in calcium chloride solution than sodium chloride solution. Swelling rate of hydrogel increased 1.3-fold of initial swelling rate for 30 min at $80^{\circ}C$.