• Title/Summary/Keyword: Chemical sensing

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C-V Response Properties of Alcohol Vapor Sensors Based on Porous Silicon (다공질 실리콘 알코올 가스 센서의 C-V 응답 특성)

  • Kim, Seong-Jeen;Lee, Sang-Hoon;Choi, Bok-Gil;Sung, Man-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.6
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    • pp.592-597
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    • 2004
  • Porous silicon(PS) has received much attention as a sensitive material of chemical sensors because of its large internal surface area. In this work, we fabricated gas-sensing devices based on the porous silicon layer which could be applicable to the measurement of blood alcohol content(BAC), and estimated their electrical properties. The structure of the sensor is similar to an MIS (metal-insulator-semiconductor) diode and consists of thin Au/oxidized PS/PS/p-Si/Al, where the p-Si substrate is etched anisotropically to reduce the thickness. We measured C-V curves from two types of the samples with the PS layer treated by the different anodization current density of 60 or 100 mA/cm$^2$, in order to compare the sensitivity. As a result, the magnitude and variation of capacitances from the devices with the PS formed under the current density of 100 mA/cm$^2$ were found to be more detectable due to the larger internal surface.

Possible application of single-walled carbon nanotube transistors for humidity sensor (단겹 탄소나노튜브 트랜지스터의 나노습도센서 응용가능성 연구)

  • Na, Pil-Sun;Kim, Hyo-Jin;Lee, Young-Hwa;Lee, Jeong-O;Kim, Jin-Hee
    • Journal of Sensor Science and Technology
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    • v.14 no.5
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    • pp.331-336
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    • 2005
  • The influence of water molecule on the electrical properties of single-walled carbon nanotube field effect transistors (SWNT-FETs) was reported. Conductance suppression was observed with the increase of the humidity. This can be explained by doping of the SWNT-FETs, which has p-type semiconductor characteristic, with the water molecules acting as an electron donor. However, after 65 % of humidity, conductance of the SWNT-FETs started to increase again, due to the opening of electron channels. Upon annealing at $400^{\circ}C$ in Ar atmosphere, conductance increases more than 500 %, and the threshold voltage shifts toward further positive gate voltages. The results of this experiment support possible application of single-walled carbon nanotubes for humidity sensing material.

Information Strategy Planning for Digital Infrastructure Building with Geo-based Nonrenewable Resources Information in Korea: Conceptual Modeling Units

  • Chi, Kwang-Hoon;Yeon, Young-Kwang;Park, No-Wook;Lee, Ki-Won
    • Proceedings of the KSRS Conference
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    • 2002.10a
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    • pp.191-196
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    • 2002
  • From this year, KIGAM, one of Korean government-supported research institutes, has started new national program for digital geologic/natural resources infrastructure building. The goal of this program is to prepare digitally oriented infrastructure for practical digital database building, management, and public services of numerous types of paper maps related to geo-scientific resources or geologic thematic map sets: hydro-geologic map, applied geologic map, geo-chemical map, airborne radiometric/magnetic map, coal geologic map and off-shelf bathymetry map and so forth. As for digital infrastructure, several research issues in this topic are composed of: ISP (Information Strategy Planning), geo-framework modeling of each map set, pilot database building, cyber geo-mineral directory service system, and web based geologic information retrieval system upgrade which services Korean digital geologic maps scaled 1:50K. In this study, UML (Unified Modeling Language)-based data modeling of geo-data sets by and in KIGAM, among them, is mainly discussed, and its results are also presented in the viewpoint of digital geo-modeling ISP. It is expected this model is further progressed with the purpose of being a guidance or framework modeling for geologic thematic mapping and practical database building, as well as other types of national thematic map database building.

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SAXS and AFM Study on Porous Silicon Prepared by Anodic Etching in HF-based Solution (SAXS와 AFM에 의한 HF-용액내 양극 에칭에 의해 제조된 기공성 실리콘의 구조연구)

  • Kim, Eu-gene;Kim, Hwa-Joong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1218-1223
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    • 2004
  • Porous silicon materials have been shown to have bright prospects for applications in light emitting, solar cell, as well as light- and chemical-sensing devices. In this report, structures of porous silicon prepared by anodic etching in HF-based solution with various etching times were studied in detail by Atomic Force Microscopy and Small Angle X -ray Scattering technique using the high energy beam line at Pohang Light Source in Korea. The results showed the coexistence of the various pores with nanometer and submicrometer scales. For nanameter size pores, the mixed ones with two different shapes were identified: the larger ones in cylindrical shape and the smaller ones in spherical shape. Volume fractions of the cylindrical and the spherical pores were about equal and remained unchanged at all etching times investigated. On the whole uniform values of the specific surface area and of the size parameters of the pores were observed except for the larger specific surface area for the sample with the short etching time. The results implies that etching process causes the inner surfaces to become smoother while new pores are being generated. In all SAXS data at large Q vectors, Porod slope of -4 was observed, which supports the fact that the pores have smooth surfaces.

A comprehensive optimization model for integrated solid waste management system: A case study

  • Paul, Koushik;Chattopadhyay, Subhasish;Dutta, Amit;Krishna, Akhouri P.;Ray, Subhabrata
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.220-237
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    • 2019
  • Solid waste management (SWM) is one of the poorly rendered services in developing countries - limited resources, increasing population, rapid urbanization and application of outdated systems leads to inefficiency. Lack of proper planning and inadequate data regarding solid waste generation and collection compound the SWM problem. Decision makers need to formulate solutions that consider multiple goals and strategies. Given the large number of available options for SWM and the inter-relationships among these options, identifying SWM strategies that satisfy economic or environmental objectives is a complex task. The paper develops a mathematical model for a municipal Integrated SWM system, taking into account waste generation rates, composition, transportation modes, processing techniques, revenues from waste processing, simulating waste management as closely as possible. The constraints include those linking waste flows and mass balance, processing plants capacity, landfill capacity, transport vehicle capacity and number of trips. The linear programming model integrating different functional elements was solved by LINGO optimization software and various possible waste management options were considered during analysis. The model thus serves as decision support tool to evaluate various waste management alternatives and obtain the least-cost combination of technologies for handling, treatment and disposal of solid waste.

Digital Olfactory Based Dementia Screening and Cognitive Enhancer Content (후각 바이오 정보 기반 치매 가상증강콘텐츠 기술 동향)

  • Choi, J.W.;Chang, S.J.;Bang, J.H.;Lee, H.R.;Kim, J.S.
    • Electronics and Telecommunications Trends
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    • v.34 no.4
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    • pp.89-97
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    • 2019
  • The olfactory bio technology is largely based on its corresponding recognition technology and smell stimulus that acquires, analyzes, and processes volatile organic compounds present in chemical molecules, which are present in the breath or air evoked by an electronic nose artificially imitating the human biological nose. The olfactory bio technology is also based on a scent display technology that automatically diverges various digital flavors based on aesthetics, concentration, duration, and intensity information required to enhance the sensibility using a computer. Recently, attempts have been made to apply noninvasive screening of dementia by sensing, analyzing, encoding, and transmitting bio information obtained through an olfactory interface, both domestically and externally; further, the olfactory medical content technology has been applied to delay or reduce the onset of dementia. In this study, we will focus on early screening of dementia using olfactory biology information and dementia cognitive enhancer content that delays or reduces the onset of dementia.

Effect of Adhesion layer on the Optical Scattering Properties of Plasmonic Au Nanodisc (접착층을 고려한 플라즈모닉 금 나노 디스크의 광산란 특성)

  • Kim, Jooyoung;Cho, Kyuman;Lee, Kyeong-Seok
    • Korean Journal of Metals and Materials
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    • v.46 no.7
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    • pp.464-470
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    • 2008
  • Metallic nanostructures have great potential for bio-chemical sensor applications due to the excitation of localized surface plasmon and its sensitive response to environmental change. Unlike the commonly explored absorption-based sensing, the optical scattering provides single particle detection scheme. For the localized surface plasmon resonance spectroscopy, the metallic nanostructures with controlled shape and size have been usually fabricated on adhesion-layer pre-coated transparent glass substrates. In this study, we calculated the optical scattering properties of plasmonic Au nanodisc using a discrete dipole approximation method and analyzed the effect of adhesion layer on them. Our result also indicates that there is a trade-off between the surface plasmon damping and the capability of supporting nanostructures in determining the optimal thickness of adhesion layer. Marginal thickness of Ti adhesion layer for supporting Au nanostructures fabricated on a silica glass substrate was experimentally analyzed by an adhesion strength test using a nano-indentation technique.

Effects of Pd Nanoparticles on Single-Walled Carbon Nanotubes as High-Sensitivity Hydrogen Gas Sensors (덴드리머와 팔라듐 나노입자를 이용한 단일벽 탄소나노튜브 고성능수소센서)

  • Lee, Jun Min;Ju, Seonghwa;Joe, Jin Hyoun;Kim, Sung-Jin;Lee, Wooyoung
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.342-346
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    • 2010
  • Pd nanoparticles (NPs) were successfully functionalizedon the surfaces of single-walled carbon nanotubes (SWNTs) by dendrimer-mediated synthesis. The hydrogen sensing properties of the Pd NPs functionalized SWNTs were investigated. Pd NPs-dendrimer-SWNTs sensors show much better speedsand superior recovery rates but lower sensitivity compared to Pd NPs-functionalized SWNTs directly fabricated due to the existence of dendrimers. Pyrolysis of the dendrimers by heat treatment resulted in a fast response time and high sensitivity owing to the reduced length of the dendrimers. These results demonstrate that the heat treatment of dendrimers in Pd NPs-dendrimer-SWNTs sensors can enable significant electrical conductance modulation upon exposure to extremely low concentrations (10 ppm) of hydrogen gas ($H_2$) in air.

Characteristics, mathematical modeling and conditional simulation of cross-wind layer forces on square section high-rise buildings

  • Ailin, Zhang;Shi, Zhang;Xiaoda, Xu;Yi, Hui;Giuseppe, Piccardo
    • Wind and Structures
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    • v.35 no.6
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    • pp.369-383
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    • 2022
  • Wind tunnel experiment was carried out to study the cross-wind layer forces on a square cross-section building model using a synchronous multi-pressure sensing system. The stationarity of measured wind loadings are firstly examined, revealing the non-stationary feature of cross-wind forces. By converting the measured non-stationary wind forces into an energetically equivalent stationary process, the characteristics of local wind forces are studied, such as power spectrum density and spanwise coherence function. Mathematical models to describe properties of cross-wind forces at different layers are thus established. Then, a conditional simulation method, which is able to ex-tend pressure measurements starting from experimentally measured points, is proposed for the cross-wind loading. The method can reproduce the non-stationary cross-wind force by simulating a stationary process and the corresponding time varying amplitudes independently; in this way the non-stationary wind forces can finally be obtained by combining the two parts together. The feasibility and reliability of the proposed method is highlighted by an ex-ample of across wind loading simulation, based on the experimental results analyzed in the first part of the paper.

Capacitance Enhancement and Evaluation of Gold-Deposited Carbon Nanotube Film Ion-Selective Electrode (금 입자 증착된 탄소나노튜브의 커패시턴스 증가 및 박막형 이온 선택성 전극으로서의 특성 평가)

  • Do Youn Kim;Hanbyeol Son;Hyo-Ryoung Lim
    • Journal of Powder Materials
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    • v.30 no.4
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    • pp.310-317
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    • 2023
  • Small-film-type ion sensors are garnering considerable interest in the fields of wearable healthcare and home-based monitoring systems. The performance of these sensors primarily relies on electrode capacitance, often employing nanocomposite materials composed of nano- and sub-micrometer particles. Traditional techniques for enhancing capacitance involve the creation of nanoparticles on film electrodes, which require cost-intensive and complex chemical synthesis processes, followed by additional coating optimization. In this study, we introduce a simple one-step electrochemical method for fabricating gold nanoparticles on a carbon nanotube (Au NP-CNT) electrode surface through cyclic voltammetry deposition. Furthermore, we assess the improvement in capacitance by distinguishing between the electrical double-layer capacitance and diffusion-controlled capacitance, thereby clarifying the principles underpinning the material design. The Au NP-CNT electrode maintains its stability and sensitivity for up to 50 d, signifying its potential for advanced ion sensing. Additionally, integration with a mobile wireless data system highlights the versatility of the sensor for health applications.