• Title/Summary/Keyword: Chemical sensing

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Humidity-Sensitive Properties of Self-Assembled Polyelectrolyte System

  • Lee Chil-Won;Kim Jong-Gyu;Gong Myoung-Seon
    • Macromolecular Research
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    • v.13 no.3
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    • pp.265-272
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    • 2005
  • Polyelectrolyte membranes for humidity-sensing were fabricated using a layer-by-layer adsorption process based on the spontaneous self-assembly of alternating layers of cationic and anionic polymers on a silanized ITO patterned glass substrate. The substrate is dipped successively into dilute solutions of a polyanion and a polycation. The homopolymers and copoymers of diallyldimethylammonium chloride (DDA), allylamine hydrochloride (AA), 2-[(methacryloyloxy)ethyl]trimethyl ammonium chloride (METAC) and vinylbenzyl tributyl phosphonium chloride(VTBPC) were used as the polycations. In this experiment, it was found that the resistance varied according to the chemical structure of the polycation. The resistance varied from $10^7$ to $10^5$ $\Omega$, as the humidity was increased from 60 (relative humidity) to $95\%$RH, which is the range of RH values required for a dew sensor operating at high humidity.

A target-specific bioassay for screening of bioactive AHL-analogues from natural products

  • Kim, Young-Hee;Kim, Jung-Sun;Park, Sung-Hoon
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.411-414
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    • 2002
  • Acylated homoserine lactones (AHLs) are membrane-permeant signal molecules responsible for biofilm formation of gram-negative bacteria via a unique mechanism known as quorum sensing. A target specific bioassay employing the AHL-responsive Agrobacterium tumefaciens reporter strain has been developed to identify new AHL-like compounds from natural products, which could be developed into antifouling compounds. By varying the X-gal concentration, incubation time, solvent for sample preparation and the sample loading procedure, it was possible to detect low level AHLs up to $10^1nM$. The length of the acyl chain of the AHLs was found to affect the sensitivity of this bioassay.

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ZnO Nanowire-film Hybrid Nanostructure for Oxygen Sensor Applications

  • Jeong Min-Chang;Oh Byeong-Yun;Myoung Jae-Min
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.2
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    • pp.58-61
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    • 2006
  • Carefully designed ZnO nanowire-film hybrid nanostructure, composed of a bottom ZnO film, ZnO nanowire arrays, and a top ZnO film, was consecutively fabricated by adjusting the supersaturation conditions using a metal-organic chemical vapor deposition (MOCVD) to utilize the vertically aligned ZnO nanowires as the oxygen sensors. The decrease of current flow through ZnO nanowire arrays increasing oxygen pressure showed the high potential for the application of the ZnO hybrid nanostructure to the oxygen sensors. In addition, it was confirmed that the oxygen sensing characteristics of this hybrid nanostructure were attributed to the defects near the surface of the nanowires.

Application of Ion-Selective Electrodes to Measure Ionic Concentrations of Macronutrients in Hydroponics (수경재배 시 다량 이온 농도 측정을 위한 이온 선택성 전극의 응용)

  • Kim, Min-Su;Park, Tu-San;Cho, Seong-In
    • Journal of Biosystems Engineering
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    • v.32 no.1 s.120
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    • pp.37-43
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    • 2007
  • This study was carried out to investigate the applicability of PVC membrane-based ion-selective electrodes for macronutrients (K, Ca, and N) by measuring of potassium, calcium, nitrate ions in hydroponic nutrient solution. The capabilities of two ion-selective membranes with varying chemical compositions for each ion were evaluated in terms of sensitivity, selectivity, and lifetime to choose sensing elements suitable for measuring typical ranges of nutrient concentrations in hydroponic solutions. The selected calcium and nitrate ion-selective membranes showed effectively sensitive responses to calcium and nitrate ions with lifetimes of 25 and 15 days, respectively. The addition of a cation additive to the potassium membrane cocktail allowed its sensitivity to be increased whereas its lifetime was reduced from 30 days to 10 days.

A REVIEW FOR DEVELOPING THERMODYNAMIC MODEL OF COMS CPS

  • Chae, Jong-Won;Han, Cho-Young;Yang, Koon-Ho
    • Proceedings of the KSRS Conference
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    • 2007.10a
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    • pp.179-182
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    • 2007
  • COMS (Communication, Ocean and Meteorological Satellite) is a geosynchronous satellite and has been developing by KARI and Astrium for Ka-band communication, ocean observation and meteorological observation. COMS Chemical Propulsion System (CPS) uses a bipropellant propulsion subsystem, which is applied for transferring COMS from GTO to GEO (mission orbit) and implementing station-keeping manoeuvres. In this paper COMS CPS is briefly introduced for understanding. A few of mathematical thermodynamic modelings of bipropellant propulsion system in literatures are reviewed and authors has studied those models for developing a computer program, which predicts variations of thermodynamic properties such as temperature and pressure histories in the helium pressurant tank, MMH propellant tank and NTO propellant tank during LAE firing and on-orbit manoeuvrings. The CPS thermodynamic model may be used to compute pressurant and propellant masses and to size tank volumes.

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Global Search Strategy using Enhanced Bacteria Chemotaxis algorithm (개선된 Bacteria Chemotaxis 알고리즘을 이용한 전역적 탐색 기법)

  • Park Jong Won;Park J.E.;Oh K.W.
    • Proceedings of the Korean Information Science Society Conference
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    • 2005.11b
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    • pp.790-792
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    • 2005
  • 함수 최적화는 주어진 자원의 한도 내에서 최대의 이익 흑은 최소의 손실을 내는 최선의 결정을 내리는 것을목표로 한다. 본 논문은 $M{\ddot{u}}ller$의 연구를 바탕으로 박테리아의 주화성을 형상화한 'Chemical Sensing Bacteria Chemotaxis'라는 알고리즘을 제안한다. 이 알고리즘은 multimodal 환경에서의 전역 탐색을 목표로 한다. 또한 실험을 통해, 제안 알고리즘의 타당성을 분석하고, 결과적으로 제안 알고리즘이 기존의 자연계 기반의 알고리즘에 비해 경쟁력이 있음을 입증하였다.

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Fabrication and Characterization of Electrostatically Actuated Microcantilever Mass Sensors (정전기력으로 구동되는 마이크로 캔틸레버 질량 센서의 제작과 특성)

  • Lee, Jung-Chul;Choi, Bum-Kyoo
    • Journal of Sensor Science and Technology
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    • v.20 no.1
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    • pp.40-45
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    • 2011
  • Microcantilevers have been actively used in probe-based microscopy and gravimetric sensing for biological or chemical analytes. To integrate actuation or detection schemes in the structure, typical fabrication processes include several photolithographic steps along with conventional MEMS fabrication. In this paper, a simple and straightforward way to fabricate and operate silicon microcantilever mass sensors is presented. The fabricated microcantilever sensors which can be electrostatically actuated require only two photolithographic steps. Resonant characteristics of fabricated microcantilevers are measured with a custom optical-lever and results show size-dependent quality factors. Using a $40\;{\mu}m$ long, $7\;{\mu}m$ wide, and $3\;{\mu}m$ thick cantilever, we achieved subfemtogram mass resolution in a 1 Hz bandwidth.

CO gas sensing characteristics of ZnO and ZnO-CuO thick films prepared by acquous precipitation (액상침전법으로 제조된 ZnO와 ZnO-CuO후막의 일산화탄소 감응특성)

  • 전석택;최우성;백승철
    • Electrical & Electronic Materials
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    • v.9 no.9
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    • pp.925-932
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    • 1996
  • Using the d.c. 2-probe method, we have examined the temperature dependence of CO gas sensitivity of pure ZnO and ZnO CuO thick films prepared by the acqueous precipitation. At 200ppm CO gas, pure ZnO thick film shows the maximum sensitivity of -6.5 at 300.deg. C. On the other hand, the maximum sensitivity of 1-5 mol% and 10-15 mol% CuO added ZnO thick films are 2.8-2.5 and 1.6, respectively. Therefore, the sensitivity of pure ZnO thick film is about three times larger than those of ZnO-CuO thick films. We suggest that the promotion of maximum sensitivity is caused by low packing and the increase of chemical adsorptions for $O_{2}$ gas.

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Sensing Behavior and Long-Term Stability of Polyaniline Sensor Coated with Poly(vinylidenefluoride) for Methanol Vapors (폴리비닐리덴플루오라이드로 코팅한 폴리아닐린센서의 메탄올에 대한 감응 특성과 장기안정도 고찰)

  • Sohn Sung-Ok;Kim Jung-Suk;Huh Jeung-Soo
    • Korean Journal of Materials Research
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    • v.14 no.4
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    • pp.260-264
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    • 2004
  • The problem of polyaniline (PANi) sensor has been poor mechanical and chemical stability under atmosphere condition. In order to overcome these problems, the PANi sensor coated with polyvinylidenefluoride ($PVF_2$) was employed. The morphology of $PVF_2$ coated-PANi layer was showed smooth and transparent properties at 15% concentration of coating solution. The resistance of $PVF_2$ coated-PANi was kept at constant value and had a good stability at long-term periods in presence of humidity.

Fabrication and Characterization of DBR Porous Silicon Chip for the Detection of Chemical Nerve Agents

  • Jung, Kyoungsun
    • Journal of Integrative Natural Science
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    • v.3 no.4
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    • pp.237-240
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    • 2010
  • Recently, number of studies for porous silicon have been investigated by many researchers. Multistructured porous silicon (PSi), distributed Bragg reflector (DBR) PSi, has been a topic of interest, because of its unique optical properties. DBR PSi were prepared by an electrochemical etch of $P^{{+}{+}}$-type silicon wafer of resistivity between 0.1 $m{\Omega}cm$ with square wave current density, resulting two different refractive indices. In this work, We have fabricated a simple and portable organic vapor-sensing device based on DBR porous silicon and investigated the optical characteristics of DBR porous silicon. DBR porous silicon have been characterized by FT-IR, Ocean optics 2000 spectrometer. The device used DBR PSi chip has been demonstrated as an excellent gas sensor, showing a great senstivity to a toxic vapor (TEP, DMMP, DEEP) at room temperature.