• Journal of Sensor Science and Technology
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• v.29 no.4
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• pp.220-226
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• 2020

Graphene has been widely considered a promising candidate for high-quality chemical sensors, owing to its outstanding characteristics, such as sensitive gas adsorption at room temperature, high conductivity, high flexibility, and high transparency. However, the main drawback of a graphene-based gas sensor is the necessity for external heaters due to its slow response, incomplete recovery, and low selectivity at room temperature. Conventional heating devices have limitations such as large volume, thermal safety issues, and high power consumption. Moreover, metal-based heating systems cannot be applied to transparent and flexible devices. Thus, to solve this problem, a method of supplying the thermal energy necessary for gas sensing via the self-heating of graphene by utilizing its high carrier mobility has been studied. Herein, we provide a brief review of recent studies on self-activated graphene-based gas sensors. This review also describes various strategies for the self-activation of graphene sensors and the enhancement of their sensing properties.

• Proceedings of the KSRS Conference
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• 2008.10a
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• pp.66-67
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• 2008

Most mineral resources are located in subsurface but mineral exploration starts with a step of investigation in wide-area to find evidence of buried ores. Conventional technique for exploration on wide-area as a preliminary survey is an observation using naked eyes by geologist or chemical analysis using lots of samples obtained from target area. Hyperspectral remote sensing can overcome those subjective and time consuming survey and can produce mineral resources distribution map. Precise resource map requires information of mineral distribution in a subpixellevel because mineral is distributed as rock components or narrow veins. But most hyperspectral data is composed of pixels of several meters or more than ten meters scale. We reviewed subpixel unmixing algorithms which have been used for geological field and tested detection ability with Hyperion imagery, geological map and seven spectral curves of mineral and rock specimens which were obtained from study areas.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.434-434
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• 2011

Electrochemical method have been employed in this work to modify the chemical vapour deposited nitrogen doped hydrogen amorphous diamond-like carbon (N-DLC) film to fabricate nickel and copper nano particle modified N-DLC electrodes. The electrochemical behaviour of the metal nano particle modified N-DLC electrodes have been characterized at the presence of glucose in electrolyte. Meanwhile, the N-DLC film structure and the morphology of metal nano particles on the N-DLC surface have been investigated using micro-Raman spectroscopy, X-ray photoelectron spectroscopy and atomic force microscopy. The nickel nano particle modified N-DLC electrode exhibits a high catalytic activity and low background current, while the advantage of copper modified N-DLC electrode is drawn back by copper oxidizations at anodic potentials. The results show that metal nano particle modification of N-DLC surface could be a promising method for controlling the electrochemical properties of N-DLC electrodes.

• Journal of Sensor Science and Technology
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• v.21 no.3
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• pp.180-185
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• 2012

${\gamma}$-ray radiolysis was used to functionalize networked ZnO nanowires with Au nanoparticles. The networked ZnO nanowires were prepared through a vapor phase selective growth method. The sensing performances of the Au-functionalized ZnO nanowires were investigated in terms of $NO_2$, CO and benzene gases. The Au-funtionalized ZnO nanowire sensors showed an applicable, reliable capability to detect the gases, indicating their potential in chemical gas sensors.

• The Korean Journal of Ceramics
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• v.5 no.2
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• pp.110-114
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• 1999

NOx sensing properties of $Ba_2WO_5$ were investigated by varying the sintering temperature in an effort to study the effects of the neck-width on gas sensitivity. $Ba_2WO_5$ sintered at $800^{\circ}C$, which exhibits neck-controlled conduction provides highest sensitivity of 47 and 29 at $500^{\circ}C$ to NO and $NO_2$, respectively. The samples sintered beyond $800^{\circ}C$ show sintering temperature-independent gas sensitivity. This may be because the grain boundary control is dominant at lower sintering temperatures and open neck control is dominant at higher sintering temperatures than $800{\circ}C$. The NOx sensing mechanism of $Ba_2WO_5$ was briefly discussed.

• Proceedings of KOSOMES biannual meeting
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• 2017.11a
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• pp.159-159
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• 2017

• Proceeding of EDISON Challenge
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• 2013.04a
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• pp.77-88
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• 2013

The computational study on the fluoride ion binding with bis(bora)calix[4]arene has been performed using density functional theory and ONIOM model. The computed structure and fluorescent behavior of bis(bora)calix[4]arene was corresponded to experiment value. The binding energy for fluoride anion is computed to be 28.05kJ/mol in the chloroform solution. We also predicted that this sensing mechanism is only valid for fluoride ion in halogens. By analyzing molecular orbitals, binding with fluoride ion reduces energy differences between HOMO and LUMO, which leads to fluorescent sensing.

• Korean Journal of Remote Sensing
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• v.6 no.1
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• pp.49-62
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• 1990

The study is aimed to analize the spectral characteristics of igneous and sedimentary rocks in their reflectance curves obtained from CARY 17-D Spectrophotometer, and correlation between chemical complsition and HHRR data. The reflectance is higher in acidic igneous rocks, while lower in basic igneous rocks. Especially acidic plutonic rocks show sharp absorption bands at 1.4 and 1.9 $\mu\textrm{m}$ due to water inclusion in felsic minerals and basic rocks a broad absoption band near 1.mu.m due to Fe$^{++}$ ion in mafic minerals. Sandstones generally have higher reflectance than siltstones and shales, and show strong absorption at 1.4 and 1.9 $\mu\textrm{m}$. Arkosic sandstones have lower reflectance at blue band due to Fe$^{+++}$ ion exsolved from feldspars. The HHRR data have a positive correlation with SiO$_2$ and $K_2$O, while they have a negative correlation with FeO and MgO.

• Journal of Sensor Science and Technology
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• v.30 no.4
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• pp.210-217
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• 2021

Gas sensors based on semiconducting metal oxides have attracted considerable attention for various applications owing to their facile, cheap, and small-scale manufacturing processes. Hematite (α-Fe₂O₃) is widely considered as a promising candidate for a gas-sensing material owing to not only its abundance in the earth's crust and low price but also its chemical stability and suitable bandgap energy. However, only a few studies have been performed in this direction because of the low gas response and sluggish response of hematite-based gas sensors. Nanostructures present a representative solution to both overcome these disadvantages and exploit the desirable features to produce high-performance gas sensors. However, several challenges remain for adopting gas sensors based on metal oxide nanostructures, such as improving cost efficiency and facilitating mass production. This review summarizes the recent studies on gas sensors based on hematite nanostructures. It also provides useful insights into various strategies for enhancing the gas-sensing properties of gas sensors based on hematite nanostructures.

• Bulletin of the Korean Chemical Society
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• v.31 no.3
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• pp.624-629
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• 2010

The synthesis and evaluation of a novel calix[4]arene-based fluorescent chemosensor 1 for the detection of I. is described. The fluorescent changes observed upon addition of various anions show that 1 is selective for I. over other anions. Addition of I. results in ratiometric measurements with 1 : 1 complex ratio.