• Bulletin of the Korean Chemical Society
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• 제24권3호
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• pp.265-266
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• 2003

• 한국토양비료학회지
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• 제42권Spc호
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• pp.33-39
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• 2009

논토양에서 지속가능한 농업생산 및 환경보호를 위한 양분관리는 토양의 화학반응들에 따른 지표들을 활용하는 것이다. 이 연구는 동일비료 영년시험 결과와 2000년부터 2002년까지 수행된 논토양 유형별 질소수준 시험 결과 등을 토대로 하여, 논토양의 화학작용 및 이와 관련된 양분공급력 지표들을 조사하였다. 논토양의 화학작용은 영양성분의 흡탈착 및 유기물질의 분해를 통한 수소, 전자, 이산화탄소의 생성작용과 이들 물질에 의한 화학작용 등으로 구성되었다. 이러한 토양의 화학작용을 고려한 양분공급력 지표들은 다음과 같았다. 질소의 공급력 지표는 토양유기물 또는 토양단백질이었으며, 인산의 공급력 지표는 유효인산함량이었고, 칼륨의 공급력 지표는 양이온교환용량과 치환성 양이온함량이었다. 한국에서는 논토양의 시비 추천식은 이러한 양분공급력 지표들을 사용하여 설정한 것으로 나타나 환경을 보전하면서 농업생산을 지속적으로 유지할 수 있는 것으로 판단된다.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.941-952
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• 2012

In the present contribution the Encounter Theory (ET) (the prototype of the classical Collision Theory in rarefied gases) concepts for widely occurring diffusion assisted irreversible bulk reactions A + A ${\rightarrow}$ C and A + B ${\rightarrow}$ C in liquid solutions examined by the authors in the literature are analyzed and compared with each other for these different types of reactions. It is shown that for a particular case of equal initial concentrations $[A]_0=[B]_0$ in the reaction A + B ${\rightarrow}$ C, when the kinetics of both reactions A + A ${\rightarrow}$ C and A + B ${\rightarrow}$ C in the framework of formal chemical kinetics and ET are the same, the accumulation of macroscopic correlations breaking the concepts of independent encounters and leading to the Generalized Encounter Theory (GET) are drastically different. The influence of the force interaction and the decay of nonstable reactants on the time behavior the macroscopic correlations is also briefly discussed.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2153-2161
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• 2007

The transition metal-induced in situ generation of carbene complexes from alkynes having a carbonyl or imino group as a nucleophilic functionality has been investigated. These reactive carbenoid species are generated with high atom efficiency through a 6-endo-dig cyclization mode based on the electrocyclization of vinylidene complexes or a 5-exo-dig cyclization mode in π-alkyne complexes, and have been found to serve as versatile intermediates in catalytic carbene transfer reactions. Highlighted and reviewed in this account are the generation and preparation of pyranylidene, furylcarbene, pyrrolylcarbene, and vinylcarbene complexes and their application to [3,3]sigmatropic rearrangement of acylcyclopropylvinylidenes, catalytic cyclopropanation reactions, [2,3]sigmatropic rearrangement or condensation reactions via ylides, ring-opening and substitution reactions with heteroaromatic compounds, and catalytic isomerization of oligoynes.

• Bulletin of the Korean Chemical Society
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• 제27권3호
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• pp.345-354
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• 2006

Ionic liquids are alternative reaction media of increasing interest and are regarded as an eco-friendly alternatives, of potential use in place of the volatile organic solvents typically used in current chemical processing methods. They are emerging as the smart and excellent solvents, which are made of positive and negative ions that they are liquids near room temperature. The nucleophilic substitution reaction is one of the important method for inserting functional groups into a carbon skeleton. Many nucleophilic substitution reactions have been found with enhanced reactivity and selectivity in ionic liquid. In this review, some recent interesting results of nucleophilic substitution reactions such as hydroxylations, ether cleavages, carbon-X (X= carbon, oxygen, nitrogen, fluorine) bond forming reactions, and ring opening of epoxides in ionic liquids are discussed.

• Bulletin of the Korean Chemical Society
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• 제27권4호
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• pp.463-472
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• 2006

The preparation of enatiomerically enriched homoallylic alcohols through asymmetric addition of chiral allylic transfer reagents and allylating reagents with chiral catalysts to the carbonyl functionalities represents an important chemical transformation. Excellent progress has been made over past decade in the development and application of catalytic asymmetric allylic transfer reactions. In this account, our efforts for the various intermolecular allylic transfer reactions such as allylation, propargylation, allenylation, and dienylation utilizing accelerating strategy and sequential allylic transfer reactions to achieve multiple stereoselection mainly using transition metal catalysts are described.

• Bulletin of the Korean Chemical Society
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• 제27권4호
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• pp.539-544
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• 2006

Proton transfer reactions and ion-molecule reactions of bifunctional ethanes of $H_2NCH_2CH_2NH_2$, $H_2NCH_2CH_2OH$, and $HOCH_2CH_2OH$ were studied using Fourier transform mass spectrometry (FTMS). The rate constants for proton transfer reactions between the fragment ions and neutral molecules were obtained from the temporal variation of the ion abundances. The rate constants were consistent with the heats of reaction. The fastest proton transfer reactions were the reactions of $CH_2N^+$, $CHO^+$, and $CH_3O^+$ for $H_2NCH_2CH_2NH_2$, $H_2NCH_2CH_2OH$, and $HOCH_2CH_2OH$, respectively. The $[M+13]^+$ ion was formed by the ion-molecule reaction between $H_2C=NH_2 ^+$ or $H_2C=OH^+$ and the neutral molecule. The major product ions generated from the ion-molecule reactions between the protonated molecule and neutral molecule were $[2M+H]^+$, $[M+27]^+$, and $[M+15]^+$.

• Journal of Photoscience
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• 제2권2호
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• pp.83-87
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• 1995

Luminscence spectra and decay of crystalline hexahydro-1,3,5-trinitro-1,3,5-s-tetrazine (RDX) are observed at 90 K and the effects of photochemical reaction on the luminescence of RDX are investigated. The uv light from high power Hg lamp is used for the photochemical reaction of RDX. While no significant changes are observed in the luminescence spectra after the photochemical reaction, the intensity profile of the spectra changes with the progress of chemical reactions. The biexponential decay of luminescence is modified by chemical reactions. Features of the electronic states of crystalline RDX are discussed in relation to the luminescence.

• 대한화학회지
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• 제18권6호
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• pp.447-452
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• 1974

多數의 熱共重合 反應組들에 對하여 pseudo molecular complex 形成이 可能한가를 理論的으로 調査하였던바 例外없이 pseudo molecular complex 形成이 가능하였다. 卽, pseudo molecular complex 形成이 共重合反應組들의 共通性임을 발견하였다. 그래서 熱共重合反應은 pseudo molecular complex를 경유하여 反應이 進行하는 하나의 可能한 開始機構를 提案하였다.

• Bulletin of the Korean Chemical Society
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• 제30권12호
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• pp.2935-2937
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• 2009

Asymmetric glycolate alkylation reactions in the solid phase were investigated for the first time with good stereoselectivities being obtained by using a Wang resin supported 2-imidazolidinone chiral auxiliary.