• Title/Summary/Keyword: Chemical protective clothing

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Comparative Study on the Protective Functions of Clothes (의복의 보호론에 관한 이론적 고찰)

  • Lim Sook Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.9 no.3
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    • pp.71-78
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    • 1985
  • This research is designed to systemize the protection theory as well as to supplement the missing theory by organizing various studies on the protective functions of celothes by domestic and foreign scholers of clothing. Human environments is classified two standpoints : (1) Physical environments, and (2) man built psychological environments including socio-physical environments, socio-biological environments, behavioral environments, socio-psychological environments and institution environments. Clothes acting as a physical protection might be of (1) extreme air temperature: Parka; (2) high relative humidity: raincoat; (3) air movement: windbreaker; (4) radiation: space suit; (5) atmospheric pressure: deep sea diver suit; (6) mechanical agent: bullet proof vest; (7) physical agent: (8) chemical agent: (9) biological agent: surgeon's gown, cap, and mask. Also dresses act to support the body comfort, health and the well-being; corset for bad back patient, wrist band for people with weak wrist, bottom half of pressure suit for people with low blood pressure. Clothes acting as a psychological protection might be of (1) influence of magic and of spirits: (2) moral danger; (3) the general unfriendliness of the world as a whole; a reassurance against the lack of love. Clothes should provide the maximum of satisfaction in accordance with the full recognition of reality. The reality should aim at the formulation of general laws concerning the most pleasing forms, colors, and styles to suit. The complex physiological anatomical and psychological aspects of individual personalities.

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Design of Daily Training Protocol for Field Crews Wearing Chemical Protective Clothing for Firefighting and Analysis of Activity (소방용 화학보호복 착용 현장대원의 일상 훈련용 프로토콜 설계 및 활동성 분석)

  • Kim, Si-Kuk;Lim, Woo-Sub;Hong, SungChul
    • Fire Science and Engineering
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    • v.32 no.4
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    • pp.110-121
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    • 2018
  • The present article is concerned with a study on the daily training protocol for field crews wearing chemical protection clothing for firefighting and the analysis of activity. To improve coping ability of & secure safety for firefighting crews initially incorporated in the fields of chemical accident & chemical terror, 10 steps in total of daily training protocol have been designed. The designed protocol is largely composed of the extensive activity protocol for daily adaptation of firefighting chemical protection clothing (steps 1, 2, 6, 7 & 9), the precision operation protocol utilizing hands (steps 3, 4 & 5), and the protocol requiring strong physical burdens (steps 8 & 10). According to the measurement results for activity as a result of the protocol, the average maximum heart rate upon wearing the firefighting chemical protection clothing was shown to increase by step 1 20.32%, step 2 18.69%, step 3 25.23%, step 4 34.77%, step 5 27.44%, step 6 30.24%, step 7 25.33%, step 8 22.25%, step 9 22.80% and step 10 20.85% compared with the time of not wearing them. The average maximum breathing rate was shown to increase by step 3 1.92%, step 4 4.11%, step 5 1.24%, step 6 3.95%, step 7 0.93%, step 8 10.23%, step 9 3.36% and step 10 15.10%, except for steps 1 & 2.

Comparative Study of Detoxification Properties of 3-Aminopropyl trimethoxysilane and Chitosan treated Cotton Fabric (3-아미노프로필트리메톡시실란과 키토산 처리 면직물의 제독 특성 비교 연구)

  • Kwon, Woong;Kim, Changkyu;Jeong, Euigyung
    • Textile Coloration and Finishing
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    • v.32 no.2
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    • pp.96-102
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    • 2020
  • Recently, it was reported that chitosan or APTMS(3-aminopropyltrimethoxysila ne) treatment to cotton using the simple pad-dry-cure method has potential to prepare textile materials for military chemical warfare protective clothing. However, it is not confirmed which method is more efficient. Therefore, this study aims to quantitatively compare detoxification properties of chitosan treated cotton fabric with those of APTMS treated cotton fabric. Detoxification properties were evaluated using the well-known organic phosphorous nerve agent stimulant, diisopropylfluorophosphate(DF P). With the same amount of chitosan and APTMS on the surface of the cotton fabrics, APTMS treated cotton fabric exhibited 10% higher detoxification properties than chitosan treated cotton fabric based on the rate of DFP hydrolysis and half-live of DFP calculated from the DFP decontamination ratios of the treated cotton fabrics through time. Therefore, APTMS treatment can be more efficient method to prepare the textile materials for military protective clothing than chitosan treatment.

Chemical Warfare Agent Simulant Decontamination of Chitosan Treated Cotton Fabric (키토산 처리 면직물의 군사용 화학 작용제 모사체 분해 연구)

  • Kwon, Woong;Han, Minwoo;Jeong, Euigyung
    • Textile Coloration and Finishing
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    • v.32 no.1
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    • pp.51-56
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    • 2020
  • This study aims to pursue the multi-functional textile finishing method to detoxify chemical warfare agent by simply treating the well-known antimicrobial agent, chitosan, to cotton fabric. For this purpose, DFP(diisopropylfluorophosphate) was sele cted as a chemical warfare agent simulant and cotton fabric was treated with 0.5, 1.0, and 2wt% chitosan solution in 1wt% acetic acid. DFP decontamination properties of the chitosan treated cotton fabrics were evaluated and compared with the untreated cotton fabric. The chitosan treated cotton fabrics showed better DFP decontamination than the untreated cotton. Decontamination properties of the chitosan treated cotton fabrics improved with the increased chitosan solution used. Especially, the cotton fabrics treated with 2wt% chitosan solution showed 5 times more DFP decontamina tion than the untreated cotton fabrics. This suggested that the chitosan treated fabric has potential to be used as a material for protective clothing with chemical warfare agent detoxifying and antimicrobial properties.

Dichloromethane-Induced Chemical Burn of the Hand: A Report of Two Cases (다이클로로메테인에 의한 수부의 화학 화상: 2예)

  • Han, Song Hyun;Kim, Seung Min;Kim, Cheol Keun;Kim, Soon Heum;Jo, Dong In
    • Journal of the Korean Burn Society
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    • v.22 no.2
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    • pp.53-57
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    • 2019
  • Dichloromethane is widely used as a solvent in paint removers. Unlike inhalation injury, contact injury caused by dichloromethane is not well known. Two patients who had undergone skin grafting to treat chemical burn of the hand caused by dichloromethane exposure were evaluated, and a literature review was done. Two healthy men aged 37 and 40 years visited our hospital with chief complaints of pain on the hands due to dichloromethane exposure. The patients had not worn protective clothing. Multiple bullae were initially noted. On the next day, fluctuation in bullae and purulent discharge were observed, and central eschar change was noted. On the 18th day after the burn, escharectomy and full-thickness skin graft were performed. Therefore, workers who use dichloromethane should wear protective clothing at workplaces. If exposed to the chemical, the worker should be instructed to do a quick wash and visit the hospital.

Chemical Protective Clothing in Textile Industry (섬유산업에서의 화학 방호복)

  • Ahn, Young-Moo;Kim, Charles J.
    • Textile Coloration and Finishing
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    • v.9 no.4
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    • pp.54-61
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    • 1997
  • 우리나라는 60대 이후 급속한 경제성장으로 산업구조가 고도화, 다양화되어 각종 설비 및 곳아 물량이 증가되었고 유해물질의 사용증가 등으로 인하여 재해발생의 요인도 증가되어 91년도 까지 257만명의 근로자가 산업현장에서 재해를 당하였으며, 최근에는 직업병을 포함한 산업재해 문제가 심각한 사회문제로 제기되고 있다. 현재 우리나라의 경우 산업안전보건법, 가스안전 관련법, 공장입지법 등으로 안전대책에 대해서 시행을 하고 있지만 화학공장에서 발생하는 예기치 않은 사고로 주변사회에 미치는 피해를 방지하거나 피해의 범위를 축소하기 위한 제도적인 장치가 아직 미흡한 실정이고 안전관련법들도 최소한의 필요한 조치사항만을 규정하고 있을 뿐, 공학적인 접근에 의한 구체적인 적용방법이 마련되어 있지 못한 실정이다. 따라서 섬유공장이 내재하고 있는 독극물에 의한 잠재적 위험성을 정량화하여 안전대책의 강구를 위한 방호복에 관한 연구가 매우 시급하다고 생각된다.

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Development of Antibacterial Hood and Filter for Medical Powered Air Purifying Respirators (PAPR) (의료용 전동공기청정호흡기(PAPR)용 항균성 후드 및 필터 개발)

  • Eunjoo Koh;Nahyun Cho;Yong Taek Lee
    • Membrane Journal
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    • v.33 no.6
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    • pp.398-408
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    • 2023
  • This work developed a hood and filter for antibacterial protective clothing for medical powered air purifying respirators (PAPR) that can be used in medical settings and quarantine against infectious diseases such as Zika virus, Middle East respiratory syndrome (MERS), and coronavirus disease-19 (COVID-19). The hood material of the protective clothing was made of polypropylene spunlace nonwoven fabric (SFS) was used for withstand wind pressure and external physcial pressure. Forthermore, in order to reduce the user's risk of infection, phytoncide-based materials were used on the outer-surface of the hood to achieve a 99.9% antibacterial effect, and the inner-surface were treated with hydro-philic materials to improve absorbency by 25%. In addition to evaluating the artificial blood penetration resistance, dry mi-croorganism penetration resistance, wet bacteria penetration resistance, and bacteriophage penetration resistance required for medical protective clothing hoods, it received a passing evaluation of levels 2-6. Meanwhile, as a result of evaluating the performance of the antibacterial treated spunlace high efficiency particulate air (HEPA) filter, excellent antibacterial properties, dust removal rate, and differential pressure effect were confirmed. All performance evaluations were conducted by an accredited certification body in accordance with the medical PAPR certification standards.

A Study on Monitoring Techniques for Dermal Exposure to Hazardous Chemicals

  • Lee, Su-Gil;Lee, Nae-Woo
    • International Journal of Safety
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    • v.8 no.1
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    • pp.18-23
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    • 2009
  • Due to dermal exposure to hazardous chemicals causing potential adverse health symptoms through skin absorption, dermal monitoring has had an important role in assessing such exposure. This paper overviews comparatively a number of studies of dermal monitoring with different methodologies such as surface monitoring, skin wiping, skin washing, adhesive methods and tape stripping, fluorescence and infrared spectroscopy, skin patches, pads and clothing, video exposure monitoring and dermal exposure assessment toolkits and models. However, there is a lack of information on the relationship between exposure levels and adverse health symptoms. Therefore, more specific strategies for dermal exposure monitoring should be developed and standardized with further development of biological and ocular monitoring.

A Study on the Adsorption Properties of Diisopropyl Methyl Phosphonate on Chromium-Based Metal-Organic Frameworks Using Acetic Acid as a Modulator (아세트산을 조절인자로 제작한 크롬 기반 금속유기골격체의 diisopropyl methyl phosphonate 흡착 특성 연구)

  • Sangjo Jeong
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.596-602
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    • 2023
  • Chromium-based metal-organic frameworks (MIL-101(Cr)) were synthesized, and their potential use as a filling material for gas masks or protective clothing was assessed through adsorption experiments using diisopropyl methyl phosphate (DIMP) as a simulant for chemical warfare agents. MIL-101(Cr) was prepared using acetic acid (MIL-101(Cr)-A) and sodium hydroxide (MIL-101(Cr)-N) as modulators. The use of acetic acid as a modulator resulted in a larger specific surface area and a higher DIMP adsorption capacity. MIL-101(Cr)-A absorbed approximately 160% of its own weight of moisture when exposed to an environment with a relative humidity of 90% for 10 days, surpassing other adsorbents such as activated carbon. The DIMP adsorption capacity of MIL-101(Cr)-A decreased to about 40% of its initial adsorption capacity after 24 hours of exposure to an environment with a relative humidity of 90%. However, this capacity is still higher compared to that of activated carbon used in commercial gas masks, suggesting a high potential for future use as a filling material for gas masks or protective clothing.

A Study on Selecting Personal Protective Equipment for Listed Hazardous Chemicals (2): Analysis Using an Exposure Risk Matrix (사고대비물질 개인보호구 선정에 관한 연구(2): 노출위해성 매트릭스에 의한 분석)

  • Han, Don-Hee;Chung, Sang-Tae;Kim, Jong-Il;Cho, Yong-Sung;Lee, Chung-Soo
    • Journal of Environmental Health Sciences
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    • v.42 no.6
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    • pp.430-437
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    • 2016
  • Objectives: The new Chemical Control Act from the Korean Ministry of Environment (2014-259) simply states only in basic phrases that every worker handling the listed chemicals should wear personal protective equipment (PPE) and does not consider the different hazard characteristics of particular chemicals or work types. The purpose of this study was to produce an exposure risk matrix and assign PPE to the categories of this matrix, which would be useful for revising the act to suggest PPE to suit work types or situations. Methods: An exposure risk matrix was made using hazard ranks of chemicals and workplace exposure risks in the previous study. For the 20 categories of exposure risk matrix PPE, levels A, B, C, D as classified by OSHA/EPA were assigned. After 69 hazardous chemicals were divided into 11 groups according to their physiochemical characteristics, respirators, chemical protective clothing (CPC), gloves and footwear were suggested on the basis of the assigned PPE levels. Results: PPE table sheets for the 11 groups were made on the basis of work types or situations. Full facepiece or half-mask for level C was recommended in accordance with the exposure risk matrix. Level A was, in particular, recommended for loading or unloading work. Level A PPE should be worn in an emergency involving hydrogen fluoride because of the number of recent related accidents in Korea. Conclusion: PPE assignment according to the exposure risk matrix made by chemical hazards and work type or situation was suggested for the first time. Each type of PPE was recommended for the grouped chemicals. The research will be usefully used for the revision of the Chemical Control Act in Korea.