• Title/Summary/Keyword: Chemical product

Search Result 2,832, Processing Time 0.036 seconds

Improvement of Diesel Engine Performance for Alternative Fuel Oil (대체연료를 사용할 경우의 디젤기관의 성능향상에 관한 연구)

  • 고장권
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.16 no.5
    • /
    • pp.97-110
    • /
    • 1992
  • Rape-seed oil has high viscosity and high rubber content like other vegetable oils. When crude rape-seed oil obtained by a general oil extraction process is used in a diesel engine, automization condition during injection is not good and a large amount of combustion product is doposited in a combustion chamber. The improvement of a diesel engine is required to use rape-seed oil as a diesel engine fuel. In this study, the physical and chemical properties and combustion characteristics of rape-seed oil were investigated. The auxiliary aid was developed to improve automization condition and the effect of the auxiliary injection aid on the performance of a diesel engine was determined. The results are as follows. 1) Oil content of rape-seed is 45%. The exraction rate is 33%. The resuls show higher values compared to those of other vegetable oils. 2) The viscosity of rape-seed oil is 50.8 cSt and nearly 14 times of diesel oil viscosity. 3) The heating value and flash point of rape-seed oil are 9720kcal/Kg and 318$^{\circ}C$, respectively. 4) In case rape-seed oil is used as fuel, brake horse power, specific fuel consumption and brake thermal efficiency are compared to those of diesel oil. The results of rape-seed oil show 3.6%, 12.7% and 3.1% higher values. 5) Particle size of injection fuel with the auxiliary injection aid on the performance of a diesel engine was determined. The results are as follows. 1) Oil content of rape-seed is 45%. The extraction rate is 33%. The results show higher values compared to those of other vegetable oils. 2) The viscosity of rape-seed oil is 50.8 cSt and nearly 14 times of diesel oil viscosity. 3) The heating value and flash point of rape-seed oil are 9720kcal/Kg and 318.deg.C, respectively. 4) In case rape-seed oil is used as fuel, brake horse power, specific fuel consumption and brake thermal efficiency are compared to theose of diesel oil. The results of rape-seed oil show 3.6%, 12.7% and 3.1% higher values. 5) Particle size of injection fuel with the auxiliary injection aids is 100.mu.m smaller than that od injection fuel without the aid. 6) Brake horse power and brake thermal efficiency with the auxiliary injection aid increase 5.07% and 6.07%, respectively. However, specific fuel consumption decreases 3.85% with the auxiliary injection aid.

  • PDF

Effects of propolis extracts on the immune response in cultured flounder, Paralichthys olivaceus (Propolis extracts가 양식넙치의 면역활성능에 미치는 영향)

  • Nam, Hyun Ju;Park, Kyung Il;Choi, Min Soon
    • Journal of fish pathology
    • /
    • v.27 no.1
    • /
    • pp.47-56
    • /
    • 2014
  • Propolis is a beehive product with a very complex chemical composition, widely used in folk medicine because of its several therapeutic activities. This study was conducted to measure the efficacy of propolis on non-specific defense reactions, specific immune response, and protection levels against pathogen challenge with Streptococcus iniae. in vitro and in vivo. In vitro, the phagocytic activity and NBT assay of peripheral blood leukocytes (PBL) were evaluated in a various propolis extractsconcentrations (0, 10, 50, 100, 150, 250 and $500{\mu}g/ml$). The optimal concentration showing activation of propolis extracts was determined to $100{\mu}g/ml$. In vivo, they were divided into four groups (PBS, propoli extractss, vaccine, propolis extracts + vaccine) in vivo. Fish were received i.p. injection of either PBS or propolis extracts, and in the presence or absence of formalin inactivated S. iniae ($1{\times}10^8$ CFU/fish), respectively. The level of haematocrit is not affected among experimental groups. The phagocytic activity and the NBT reduction activities of head kidney phagocyte were markedly (p<0.05)augmented in the propolis extracts groups than in the PBS-control group, respectively. The level of serum lysozyme activity was significantly (p<0.05) increased in the propolis extracts treated groups than in the PBS-control group. The agglutinin titer was significantly (p<0.05) enhanced in the vaccine+propolis extracts group than in the vaccine group, but there was no difference between PBS-control and propolis treated group. The results of the present study suggest that propolis extracts seems to be a promising compounds of non-specific immune stimulator, also being able to use a good adjuvant.

Physical Properties of Chitosan Film made from Crab Shell (꽃게 껍질에서 분리제조한 키틴산 필름의 물성에 관한 연구)

  • Cho, Jeong-Suk;Han, Jeong-Jun;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
    • /
    • v.24 no.6
    • /
    • pp.574-580
    • /
    • 1992
  • Chitin was isolated from the residue of enzymatically hydrolyzed crab, Portunus trituberculatus, and further deacetylated by alkaline boiling to make chitosan. The physical properties of chitosan solution and its film forming properties were examined. The functional characteristics of chitosan film were compared to those of cellophane, polyvinyl chloride (PVC) and polyethylene (PE) films. The proximate chemical composition of chitin obtained from crab residue was 6.95% nitrogen, 0.3% crude ash and 4.57% moisture and the product yield was 12.8% based on a dry material basis. The degree of deacetylation of chitosan was $79{\sim}92%$ and $70{\sim}86%$ as determined by IR spectroscopy, and $70{\sim}86%$ as determined by colloid titration method each respectively. The chitosan at 1% acetic acid solution showed distinct pseudoplastic flow behavior. The flow behavior index and consistency index were 0.8886, 0.2084 $MPa{\cdot}s^n$ for 0.4% solution and 0.8498, 0.6190 $MPa{\cdot}s^n$ for 0.8% solution, respectively. The chitosan film had the highest tensile strength $(888 kg/cm^2)$ and water permeability $(100\;g/m^2{\cdot}24\;hrs)$ among the tested films, but relatively low elongation property (49%). It showed the similar tear strength (90kg/cm) and light permeability (87.7%) to other films tested in spite of the relatively high haze value (12.5%). As the thickness of chitosan film increased from 0.025 to 0.050 mm, the tensile strength of film decreased distictively, and the degree of elongation, tear strength, and water permeability of film also decreased slightly. Whereas the light permeability of film did not change and the haziness of film slightly increased by the increase of film thickness.

  • PDF

Effect of alkaline activators on the fresh properties and strength of silico-manganese fume-slag activated mortar

  • Nasir, Muhammad;Johari, Megat Azmi Megat;Yusuf, Moruf Olalekan;Maslehuddin, Mohammed;Al-Harthi, Mamdouh A.
    • Advances in concrete construction
    • /
    • v.10 no.5
    • /
    • pp.403-416
    • /
    • 2020
  • This study investigated the effect of alkaline activators - NaOHaq (NH) (NH: 0-16 M) and Na2SiO3aq (NS) (NS/NH: 0-3.5) in the synthesis of silico-manganese fume (SMF) and ground blast furnace slag (BFS) blended alkali-activated mortar (AASB). The use of individual activator was ineffective in producing AASB of sufficient fresh and hardened properties, compared to the synergy of both activators. This may be attributed to incomplete dissolution and condensation of oligomers required for gelation of the binder. An inverse relationship was noted among the fresh properties and the NH concentration or NS/NH ratio. This was influenced by the dissolution and condensation of silicate monomers under polymerization process. The maximum 28-day strength of ~45 MPa, setting time of 60 min and flow of 182 mm was obtained with the use of combined activators (10M-NH and NS/NH=2.5). The combined activators at NS/10M-NH=2.5 constituted SiO2/Na2O, H2O/Na2O and H2O/SiO2 molar ratio of 1.61, 17.33 and 10.77, respectively. This facilitated the formation of C-S-H, C/K-A-S-H and C-Mn-S-H in the framework together with an increase in the crystallinity due to more silicate re-organization within the aluminosilicate chain. On comparison of the high concentrated with mild alkali synthesized product, it revealed that the concentration of OH- and Si monomers together with alkali metals influenced the dissolution of precursors and embedment of the constituent elements in the polymeric matrix. These factors eventually contributed to the microstructural densification of the mortar prepared with NS/10M-NH=2.5 thereby enhancing the compressive strength.

Chemical Composition of Special Poultry (Pheasant, Chungdung Wild Duck, and Ogol Fowl) Meatp (특수가금(꿩, 청둥오리, 오골계)육의 영양성분)

  • Kim, Ki Jun;Oh, Hong Rock;Oh, Man Jin
    • Korean Journal of Agricultural Science
    • /
    • v.23 no.1
    • /
    • pp.90-98
    • /
    • 1996
  • In order to obtain the basic information for new food product development from pheasant, wild duck(chhungdung), and Ogol fowl, which are called as special poultry, general components,fatty acid amino acid and minerals composition were analyzed. 1). The general compositions were 71.2-74.1% of water, 23.3-26.4% of protein, 1.0-2.4% fat, and 1.1-1.4% of ash in the pheasant, 73.8-76.4% of water, 18.6-19.6% of protein, 2.7-6.8% of fat, and 0.8-1.6% of ash in the wild duck, and 71.4-72.3% of water, 20.8-22.7% of protein, 1.9-6.3% of fat, and 1.0-1.2% of ash in the Ogol fowl, repectively. 2).In the pheasant and wild duck meat, the composition of unsaturated and saturated fatty acid were 60-64%,36-40%, respectively, and olec, palmitic, linolec, and stearic acid were most abundant in this order. But, in Ogol fowl, 72-76% and 24-28% were belong to the unsaturated fatty acid, respectively. 3). Amino acid contents in its order of relative amount were glutamic acid, alanine, aspatic acid, and glycine for the pheasant, glutamic acid, glycine, alanine, and aspatic acid for the wild duck, and lysine, glutamic acid, and aspatic acid for the Ogol fowl, repectively. 4).The mineral composition in the pheasant and wild duck were potassium, phosphorus, sodium, magnesium, and calcium, but in the Ogol fowl, potassium, sodium, magnesium, phosphorus, calcium were the most abundant in this order, repectively.

  • PDF

An Edible Gintonin Preparation from Ginseng

  • Choi, Sun-Hye;Shin, Tae-Joon;Lee, Byung-Hwan;Hwang, Sung-Hee;Kang, Ji-Yeon;Kim, Hyun-Joong;Park, Chan-Woo;Nah, Seung-Yeol
    • Journal of Ginseng Research
    • /
    • v.35 no.4
    • /
    • pp.471-478
    • /
    • 2011
  • Ginseng, the root of Panax ginseng, is one of the oldest herbal medicines. It has a variety of physiological and pharmacological effects. Recently, we isolated a subset of glycolipoproteins that we designated gintonin, and demonstrated that it induced transient change in intracellular calcium concentration $([Ca^{2+}]_i)$ in cells via G-protein-coupled receptor signaling pathway(s). The previous method for gintonin isolation included multiple steps using methanol, butanol, and other organic solvents. In the present study, we developed a much simple method for the preparation of gintonin from ginseng root using 80% ethanol extraction. The extracted fraction was designated edible gintonin. This method produced a high yield of gintonin (0.20%). The chemical characteristics of gintonin such as molecular weight and the composition of the extract product were almost identical as the gintonin prepared using the previous extraction regimen involving various organic solvents. We also examined the physiological effects of edible gintonin on endogenous $Ca^{2+}$-activated $Cl^-$ channel activity of Xenopus oocytes. The 50% effective dose was $1.03{\pm}0.3\;{\mu}g$/mL. Finally, since gintonin preparation through ethanol extraction is easily reproducible, gintonin could be commercially applied for ginseng-derived functional health food and/or drug following the confirmations of in vitro and in vivo physiological and pharmacological effects of gintonin.

Rare ginsenoside Ia synthesized from F1 by cloning and overexpression of the UDP-glycosyltransferase gene from Bacillus subtilis: synthesis, characterization, and in vitro melanogenesis inhibition activity in BL6B16 cells

  • Wang, Dan-Dan;Jin, Yan;Wang, Chao;Kim, Yeon-Ju;Perez, Zuly Elizabeth Jimenez;Baek, Nam In;Mathiyalagan, Ramya;Markus, Josua;Yang, Deok-Chun
    • Journal of Ginseng Research
    • /
    • v.42 no.1
    • /
    • pp.42-49
    • /
    • 2018
  • Background: Ginsenoside F1 has been described to possess skin-whitening effects on humans. We aimed to synthesize a new ginsenoside derivative from F1 and investigate its cytotoxicity and melanogenesis inhibitory activity in B16BL6 cells using recombinant glycosyltransferase enzyme. Glycosylation has the advantage of synthesizing rare chemical compounds from common compounds with great ease. Methods: UDP-glycosyltransferase (BSGT1) gene from Bacillus subtilis was selected for cloning. The recombinant glycosyltransferase enzyme was purified, characterized, and utilized to enzymatically transform F1 into its derivative. The new product was characterized by NMR techniques and evaluated by MTT, melanin count, and tyrosinase inhibition assay. Results: The new derivative was identified as (20S)-$3{\beta},6{\alpha},12{\beta}$,20-tetrahydroxydammar-24-ene-20-O-${\beta}$-D-glucopyranosyl-3-O-${\beta}$-D-glucopyranoside(ginsenoside Ia), which possesses an additional glucose linked into the C-3 position of substrate F1. Ia had been previously reported; however, no in vitro biological activity was further examined. This study focused on the mass production of arduous ginsenoside Ia from accessible F1 and its inhibitory effect of melanogenesis in B16BL6 cells. Ia showed greater inhibition of melanin and tyrosinase at $100{\mu}mol/L$ than F1 and arbutin. These results suggested that Ia decreased cellular melanin synthesis in B16BL6 cells through downregulation of tyrosinase activity. Conclusion: To our knowledge, this is the first study to report on the mass production of rare ginsenoside Ia from F1 using recombinant UDP-glycosyltransferase isolated from B. subtillis and its superior melanogenesis inhibitory activity in B16BL6 cells as compared to its precursor. In brief, ginsenoside Ia can be applied for further study in cosmetics.

Development of a Biofungicide Using a Mycoparasitic Fungus Simplicillium lamellicola BCP and Its Control Efficacy against Gray Mold Diseases of Tomato and Ginseng

  • Shin, Teak Soo;Yu, Nan Hee;Lee, Jaeho;Choi, Gyung Ja;Kim, Jin-Cheol;Shin, Chul Soo
    • The Plant Pathology Journal
    • /
    • v.33 no.3
    • /
    • pp.337-344
    • /
    • 2017
  • To develop a commercial product using the mycoparasitic fungus Simplicillium lamellicola BCP, the scale-up of conidia production from a 5-l jar to a 5,000-l pilot bioreactor, optimization of the freeze-drying of the fermentation broth, and preparation of a wettable powder-type formulation were performed. Then, its disease control efficacy was evaluated against gray mold diseases of tomato and ginseng plants in field conditions. The final conidial yields of S. lamellicola BCP were $3.3{\times}10^9conidia/ml$ for a 5-l jar, $3.5{\times}10^9conidia/ml$ for a 500-l pilot vessel, and $3.1{\times}10^9conidia/ml$ for a 5,000-l pilot bioreactor. The conidial yield in the 5,000-l pilot bioreactor was comparable to that in the 5-l jar and 500-l pilot vessel. On the other hand, the highest conidial viability of 86% was obtained by the freeze-drying method using an additive combination of lactose, trehalose, soybean meal, and glycerin. Using the freeze-dried sample, a wettable powder-type formulation (active ingredient 10%; BCP-WP10) was prepared. A conidial viability of more than 50% was maintained in BCP-WP10 until 22 weeks for storage at $40^{\circ}C$. BCP-WP10 effectively suppressed the development of gray mold disease on tomato with control efficacies of 64.7% and 82.6% at 500- and 250-fold dilutions, respectively. It also reduced the incidence of gray mold on ginseng by 65.6% and 81.3% at 500- and 250-fold dilutions, respectively. The results indicated that the new microbial fungicide BCP-WP10 can be used widely to control gray mold diseases of various crops including tomato and ginseng.

Numerical simulation of gasification of coal-water slurry for production of synthesis gas in a two stage entrained gasifier (2단 분류층 가스화기에서 합성가스 생성을 위한 석탄 슬러리 가스화에 대한 수치 해석적 연구)

  • Seo, Dong-Kyun;Lee, Sun-Ki;Song, Soon-Ho;Hwang, Jung-Ho
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2007.11a
    • /
    • pp.417-423
    • /
    • 2007
  • Oxy-gasification or oxygen-blown gasification, enables a clean and efficient use of coal and opens a promising way to CO2 capture. The coal gasification process of a slurry feed type, entrained-flow coal gasifier was numerically predicted in this paper. The purposes of this study are to develop an evaluation technique for design and performance optimization of coal gasifiers using a numerical simulation technique, and to confirm the validity of the model. By dividing the complicated coal gasification process into several simplified stages such as slurry evaporation, coal devolatilization, mixture fraction model and two-phase reactions coupled with turbulent flow and two-phase heat transfer, a comprehensive numerical model was constructed to simulate the coal gasification process. The influence of turbulence on the gas properties was taken into account by the PDF (Probability Density Function) model. A numerical simulation with the coal gasification model is performed on the Conoco-Philips type gasifier for IGCC plant. Gas temperature distribution and product gas composition are also presented. Numerical computations were performed to assess the effect of variation in oxygen to coal ratio and steam to coal ratio on reactive flow field. The concentration of major products, CO and H2 were calculated with varying oxygen to coal ratio (0.2-1.5) and steam to coal ratio(0.3-0.7). To verify the validity of predictions, predicted values of CO and H2 concentrations at the exit of the gasifier were compared with previous work of the same geometry and operating points. Predictions showed that the CO and H2 concentration increased gradually to its maximum value with increasing oxygen-coal and hydrogen-coal ratio and decreased. When the oxygen-coal ratio was between 0.8 and 1.2, and the steam-coal ratio was between 0.4 and 0.5, high values of CO and H2 were obtained. This study also deals with the comparison of CFD (Computational Flow Dynamics) and STATNJAN results which consider the objective gasifier as chemical equilibrium to know the effect of flow on objective gasifier compared to equilibrium. This study makes objective gasifier divided into a few ranges to study the evolution of the gasification locally. By this method, we can find that there are characteristics in the each scope divided.

  • PDF

A Study on the Application of SAW Process for Thin Plate of 3.2 Thickness in Ship Structure (선체외판부 3.2T 박판에 대한 SAW 용접 적용에 관한 연구)

  • Oh, Chong-In;Yun, Jin-Oh;Lim, Dong-Young;Jeong, Sang-Hoon;Lee, Jeong-Soo
    • Proceedings of the KWS Conference
    • /
    • 2010.05a
    • /
    • pp.51-51
    • /
    • 2010
  • Recently just as in the automobile industry, shipbuilders also try to reduce material consumption and weight in order to keep operating costs as low as possible and improve the speed of production. Naturally industry is ever searching for welding techniques offering higher power, higher productivity and a better quality. Therefore it is important to have a details research based on the various welding process applied to steel and other materials, and to have the ability both to counsel interested companies and to evaluate the feasibility of implementation of this process. Submerged-arc welding (SAW) process is usually used about 20% of shipbuilding. Similar to gas metal arc welding(GMAW), SAW involves formation of an arc between a continuously-fed bare wire electrode and the work-piece. The process uses a flux to generate protective gases and slag, and to add alloying elements to the weld pool and a shielding gas is not required. Prior to welding, a thin layer of flux powder is placed on the work-piece surface. The arc moves along the joint line and as it does so, excess flux is recycled via a hopper. Remaining fused slag layers can be easily removed after welding. As the arc is completely covered by the flux layer, heat loss is extremely low. This produces a thermal efficiency as high as 60% (compared with 25% for manual metal arc). SAW process offers many advantages compared to conventional CO2 welding process. The main advantages of SAW are higher welding speed, facility of workers, less deformation and better than bead shape & strength of welded joint because there is no visible arc light, welding is spatter-free, fully-mechanized or automatic process, high travel speed, and depth of penetration and chemical composition of the deposited weld metal. However it is difficult to application of thin plate according to high heat input. So this paper has been focused on application of the field according to SAW process for thin plate in ship-structures. For this purpose, It has been decided to optimized welding condition by experiments, relationship between welding parameters and bead shapes, mechanical test such as tensile and bending. Also finite element(FE) based numerical comparison of thermal history and welding residual stress in A-grade 3.2 thickness steel of SAW been made in this study. From the result of this study, It makes substantial saving of time and manufacturing cost and raises the quality of product.

  • PDF