• Title/Summary/Keyword: Chemical process

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Parameter and Tolerance Designs of the Chemical Reaction Process (화학반응 공정에서의 공정조건 및 허용차설계)

  • 안종석;윤원영
    • Journal of Korean Society for Quality Management
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    • v.30 no.1
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    • pp.97-117
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    • 2002
  • We apply Taguchi method to the process optimization problem of chemical reaction process, and some case studies are done to find out the way for cost reduction and quality improvement The parameter and tolerance designs of Taguchi mettled are done with operation data of a chemical process and we propose a procedure how to use and analyze the operation data to find the optimal process conditions and tolerance limits. In order to use the continuous values in experiment conditions, it is suggested how to determine the interval of each level by discrete values and to treat any missing values caused from discrete 4 levels.

Evaluation on Safety of Stainless Steels in Chemical Decontamination Process with Immersion Type of Reactor Coolant Pump for Nuclear Reactor (침적식 화학적 제염 공정 시 원자로 냉각재 펌프용 스테인리스강의 안전성 평가)

  • Kim, Seong-Jong;Han, Min-Su;Kim, Ki-Joon;Jang, Seok-Ki
    • Corrosion Science and Technology
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    • v.10 no.5
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    • pp.167-174
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    • 2011
  • Due to commercialization of nuclear power, most countries have taken interest in decontamination process of nuclear power plant and tried to develop a optimum process. Because open literature of the decontamination process are rare, it is hard to obtain skills on decontamination of foreign country and it is necessarily to develop proper chemical decontamination process system in Korea. In this study, applicable possibility in chemical decontamination for reactor coolant pump (RCP) was investigated for the various stainless steels. The stainless steel (STS) 304 showed the best electrochemical properties for corrosion resistance and the lowest weight loss ratio in chemical decontamination process with immersion type than other materials. However, the pitting corrosion was generated in both STS 415 and STS 431 with the increasing numbers of cycle. The intergranular corrosion in STS 431 was sporadically observed. The sizes of their pitting corrosion also increased with increasing cycle numbers.

Scale-up Fabrication of Flat Sheet Membrane by Using a Roll-to-Roll Process (롤투롤 공정을 활용한 평판형 분리막의 대면적 제조 연구)

  • Dong Hyeok Baek;Youngmin Yoo;In-Chul Kim;You-In Park;Seung-Eun Nam;Young Hoon Cho
    • Membrane Journal
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    • v.34 no.1
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    • pp.79-86
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    • 2024
  • The flat sheet membrane, one of the representative forms of polymeric membranes, is widely used from material research in laboratories to commercial membrane production due to its ease of fabrication. Porous polymeric flat sheet membranes used in microfiltration and ultrafiltration are mainly fabricated through phase separation processes, utilizing non-solvent-induced and vapor-induced phase separation methods. However, due to the nature of phase separation processes, variations between samples can easily occur depending on the surrounding environment and the experimenter, making it difficult to ensure reproducibility. Therefore, for scaling up and ensuring reproducibility of developed membrane fabrication technologies, there is a need for a controlled environment continuous large-area production device, such as a roll-to-roll manufacturing system. This research compared the changes in membrane characteristics due to differences in manufacturing environments when scaling up laboratory-scale fabrication technologies to roll-to-roll processes using knife and slot die coaters. By optimizing the continuous manufacturing process factors, uniformity of the membrane was ensured during large-area production.

Oxygen Control in CdS Thin Film by UV Illumination in Chemical Bath Deposition (용액성장법에서 자외선 조사를 이용한 CdS의 산소함량 제어)

  • Baek, Hyeon-ji;Oh, Ji-A;Seo, Young-Eun;Shin, Hye-Jin;Cho, Sung-Wook;Jeon, Chan-Wook
    • Current Photovoltaic Research
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    • v.7 no.2
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    • pp.33-37
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    • 2019
  • In this paper, we compared the performance of $Cu(In,Ga)(S,Se)_2$ (CIGSSe) thin film solar cell with CdS buffer layer deposited by irradiating 365 nm UV light with 8 W power in Chemcial Bath Deposition (CBD) process. The effects of UV light irradiation on the thin film deposition mechanism during CBD-CdS thin film deposition were investigated through chemical and electro-optical studies. If the UV light is irradiated during the solution process, the hydrolysis of Thiourea is promoted even during the same time, thereby inhibiting the formation of the intermediate products developed in the reaction pathway and decreasing the pH of the solution. As a result, it is suggested that the efficiency of the CdS/CIGSSe solar cell is increased because the ratio of the S element in the CdS thin film increases and the proportion of the O element decreases. This is a very simple and effective approach to control the S/O ratio of the CdS thin film by the CBD process without artificially controlling the process temperature, solution pH or concentration.

A Study of Deburring using Electro-Chemical Method (전해연마를 이용한 버 제거에 관한 연구)

  • Kang D. C.;Jeon B. H.;Oh S. I.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.05a
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    • pp.217-220
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    • 2001
  • In the shearing process the burr or rollover must be minimized in order to improve the quality of product. The burr size can be minimized by control of several process parameters. But removal of all burrs are impossible. Most mechanical type deburring methods (vibrating bowls, rotating barrels, shot blasting, for example.) will remove large burrs, other methods use chemical (electro-chemical deburring) or heat (thermal energy deburring). The electro-chemical deburring process removes burrs by the deplating method. Electro-chemical deburring equipment is requires a small capital investment than other methods(mechanical or thermal methods). Electro-chemical deburring method need to many parameters for control such as a time, voltage and concentration of electrolyte. In this paper shows relations of these parameters by experiment.

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An Analysis on the Material Removal Mechanism of Chemical-Mechanical Polishing Process Part I: Coupled Integrated Material Removal Modeling (화학-기계적 연마 공정의 물질제거 메커니즘 해석 Part I: 연성 통합 모델링)

  • Seok, Jong-Won;Oh, Seung-Hee;Seok, Jong-Hyuk
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.2 s.19
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    • pp.35-40
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    • 2007
  • An integrated material removal model considering thermal, chemical and contact mechanical effects in CMP process is proposed. These effects are highly coupled together in the current modeling effort. The contact mechanics is employed in the model incorporated with the heat transfer and chemical reaction mechanisms. The mechanical abrasion actions happening due to the mechanical contacts between the wafer and abrasive particles in the slurry and between the wafer and pad asperities cause friction and consequently generate heats, which mainly acts as the heat source accelerating chemical reaction(s) between the wafer and slurry chemical(s). The proposed model may be a help in understanding multi-physical interactions in CMP process occurring among the wafer, pad and various consumables such as slurry.

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Effect of Water and Aluminum Sulfate Mole Ratio on Pore Characteristics in Synthesis of AlO(OH) Nano Gel by Homogeneous Precipitation (균일침전에 의한 AlO(OH) 나노 겔 합성에서 물/황산알루미늄의 몰 비가 세공특성에 미치는 영향)

  • Choe, Dong-Uk;Park, Byung-Ki;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.43 no.9 s.292
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    • pp.564-568
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    • 2006
  • AlO(OH) nano gel is used in precursor of ceramic material, coating material and catalyst. For use of these, not only physiochemical control for particle morphology, pore characteristic and peptization but also studies of synthetic method for preparation of advanced application products were required. In this study, AlO(OH) nano gel was prepared through the aging and drying process of aluminum hydroxides gel precipitated by the hydrolysis reaction of dilute NaOH solution and aluminum sulfate solution. In this process, optimum synthetic condition of AlO(OH) nano gel having excellent pore volume as studying the effect of water and aluminum sulfate mole ratio on gel precipitates has been studied. Water and aluminum sulfate mole ratio brought about numerous changes on crystal morphology, surface area, pore volume and pore size. Physiochemical properties were investigated as using XRD, TEM, TG/DTA, FT-IR, and $N_2$ BET method.

Design of cylinder using chemical milling (케미컬 밀링을 이용한 실린더 설계)

  • Lee, Jong-Woong;Yoo, Joon-Tae;Jang, Young-Soon;Yi, Yeong-Moo;Cho, Gwang-Rae
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.504-509
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    • 2004
  • Chemical machining(CHM) is a special process which material removed by contact of strong etchant. The application as industrial process was started from aircraft industry after 2nd world war. Chemical milling, one of the CHM process, initially became commercial bussiness and it was called chem-mill. Even today, this process widely used to remove the material from aircraft wings and fuselage panel in aircraft industry. In this study, it is attempted to design the cylinder pattern which minimize the weight within the allowable stress using chemical milling.

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Performance and Characterization of Ceramic Membrane by Phase Inversion-Extrusion Process with Polymer Binder Mixing (상전이-압출 알루미나 분리막 제조 공정에서 혼합 고분자 바인더 적용에 따른 성능 및 특성 평가)

  • Sojin Min;Ahrumi Park;Yongsung Kwon;Daehun Kim;You-In Park;Seong-Joong Kim;Seung-Eun Nam
    • Membrane Journal
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    • v.33 no.6
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    • pp.439-446
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    • 2023
  • Ceramic membranes are generally used for various industrial processes operating under extreme conditions because of its high thermal and chemical stability. However, due to the trade-off phenomenon of permeability and mechanical strength, preparation of high permeability-high strength membrane is necessary. In this study, the change in characteristics and performances of ceramic membranes was analyzed depending on the type of polymer binder and its mixing ratio. Because the solubility between solvent and polymer binder was higher in PSf (polysulfone) than in PES (polyethersulfone), the viscosity and discharge pressure of the PSf-based dope solution were higher than those of PES-based dope solution. When PSf was used as a polymer binder, ceramic membrane showed high mechanical strength and low water permeability due to the dense structure. On the other hand, in case of PES, the mechanical strength was slightly reduced and the water permeability was increased. It was confirmed that the optimum mixing ratio of the PSf and PES with high water permeability and mechanical strength was 9:1.

Effect of Pad Buffing process on Material Removal Characteristics in Silicon Chemical Mechanical Polishing (실리콘 연마에서 패드 버핑 공정이 연마특성에 미치는 영향)

  • Park, Ki-Hyun;Jeong, Hae-Do;Park, Jae-Hong;Kinoshita, Masaharu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.4
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    • pp.303-307
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    • 2007
  • This paper investigated the effect of the pad buffing process on the material removal characteristics and pad stabilization during silicon chemical mechanical polishing. The pads surface were controlled by the buffing process using a buffer made by the sandpaper. The buffing process is based on abrasive machining by using a high speed sandpaper. The controlled pad by the buffing process show less deformation deviation and stable material removal rate during the CMP process. In addition, the controlled pad ensure better uniformity of removal rate than comparative pads. As a result of monitoring, the controlled pad by the buffing process demonstrated constant and stable friction force signals from initial polishing stage. Therefore, the tufting process could control the pad surface to be uniform and improve the performance of the polishing pad.