• Bulletin of the Korean Chemical Society
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• 제25권6호
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• pp.873-877
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• 2004

The relationship between the behaviors of c.c.lipase back-extraction and their percolation phenomena by using AOT reverse micellar systems (RVMS) has been studied by the addition of a small amount of additives to organic phase such as thiols and nonionic-surfactants focusing on micelle-micelle interactions. The values of ${\beta}_t$ defined by the variation of percolation processes and back-extraction behaviors of c.c.lipase have a good linear correlation. The hydrophobicity of additive molecules suppressing the cluster formation of reverse micelles (high values of ${\beta}_t$) improved the back-extraction behavior of c.c.lipase. The back-extraction fraction and its rate of c.c.clipase are increased with decreasing of the value of hydrophilic lipophilic balance (HLB) and increasing of the hydrophobicity per additive molecules added to reverse micellar systems (RVSM) in the same additives concentration.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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• pp.167-169
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• 2002

Selective, highly stable determination of serotonin was achieved in cyclic voltammetric measurement carried out at electrochemically treated conductive boron-doped diamond electrode. Boron-doped diamond electrodes were prepared on single crystal Si wafers by microwave plasma chemical vapor deposition and $B_2O_3$ was dissolved in acetone/methanol(9:1) mixture solution so that the B/C weight ratio ca. $10^4ppm$. Serotonin is a kind of indoleamines, which secreted from adrenal marrow cells. The serious problem to detection of serotonin is the interference phenomena of electroactive constituent, including AA. In this study, electrochemical treatment of HDD was carried out to discriminate between serotonin and AA responses. Experimental results showed that the peak potential of AA oxidation shift to the positive direction and the oxidation peak of serotonin was unchanged.

• 한국세라믹학회지
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• 제17권2호
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• pp.80-88
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• 1980

The sintering phenomena and piezoelectric properties of PZT ceramics of composition $Pb(Zr_{0.54} Ti_{0.46})O_3$ were investigated when a small quantity of $La_2O_3$ , $LaMnO_3$, $LaCrO_3$ were added. The unwanted chemical composition change in PZT during sinterin porces du to PbO evaporation poses a severe problem in PZt manufacturinig. It is observed tat an addition of small amount of $LaMnO_3$ to PZT markedly decreases the evaporation of PbO during sintering . The green compact of (1-x) PZT.xLaMnO3(x=0.02~0.10) could be sintered of under O2 atmosphere alone with no significant loss of PbO. The planar coupling factor kp of the sintered $0.98Pb(Zr_{0.54} Ti_{0.46})O_{3.0.02}LaMnO}3$ is similar to that of commercial PZT 6A. Microstructure investigation shows that part of sintering process of $Pb(Zr, Ti)O_3$.$LaMnO_3$ system progresses via liquid phase sintering. It is believed that the evaporation of PbO in PZT sintering is restricted by the addition of $LaMnO_3$ due to the above phenomena. Furthermore the solid solution of $LaMnO_3$ in PZT causes diffuses phase transition.

• 한국화재소방학회논문지
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• 제8권1호
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• pp.9-20
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• 1994

본 논문은 수직평판 위에 형성된 층류 확산화염의 현상적인 문제를 파악하는 수치적 연구를 수행하였다. 수치적 방법으로는 Keller-box method를 사용하였다. 지배방정식은 매우 얇은 화염면 가정을 도입하여 간단화 시킬 수 있으며, 에너지와 화학성분 식은 Schvab-Zeldovich 변수를 이용하여 무차원화 하였다. 물리적 공간은 연소영역과 전파영역으로 나누었고, 복사열전달을 고려하였다. 연구의 결과, 층류확산 화염의 전형적인 현상들이 관찰되었으며, code의 신뢰성을 확인할 수 있었으며, 이를 통해 복사열손실의 영향에 따른 제반 현상들을 파악하여 비교, 분석할 수 있었다.

• 자원환경지질
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• 제26권1호
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• pp.67-81
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• 1993

This dissertation is a basic research on the degradation of rocks and aims at clarifying the relations between the progression of degree of weathering and the variation of chemical composition. The author wants to make clear the degradation of rocks and the process of formation of sedimentary rocks from a standpoint of elucidation of migration of elements. This study is considered to be significant not only as a part of research on the distribution of earth crust materials but as the petrogenesis of rocks. The chemical studies on the weathered rocks have been started relatively early and there are not a few researches on them: Goldich, 1938; Harris, et al., 1966; Ruxton, 1968; Berner, et al., 1982; Kanuss, 1983; Lasaga, 1984; Siagel, 1984. The degree of migration of elements in weathering is the composite result of various factors. Because, at the present time, it is difficult to clarify the individual and composite effects of each factor theoretically and quanititatively, we must accumulate empirical data and use them relatively. In such consideration the author acquired some data of chemical weathering from the chemical analysis of granitic and basaltic rocks in and around Fukuoka city, Japan and granitic rocks in and around Chonju and Iri cities, Korea. Because both rock types studied can be considered as representative materials of acidic and basic rocks compsing the earth crust, it is significant to examine the phenomena of weathering of both rock types. The following results are obtained from the analysis and examinations of chemical compositions of the original and weathered rocks. The loss rate of major elements has no uniformity, but the following relation holds in general; Ca, Na> K, Si> Mg> Fe, Al. As weathering proceeds, the ratio of $Al_2O_3/CaO$ shows increasing phenomena, and that of $Na_2O/CaO$ decreasing. The range of migration of composition is broad in basaltic rocks but narrow in granitic rocks. The reason is that the chemical weathering of basaltic rocks progresses more easily than that of granitic rocks. The chemical weathering potenitial index of basaltic rocks in larger than that of granitic rocks. The reason is that the chemical weathering of basaltic rocks proceeds more easily than that of granitic rocks. In weathering, the decrease of mobile cations such as $Ca^{2+}$, $Na^{2+}$, $Mg^{2+}$ and the increase of $H_2O$ in basaltic rocks are more obvious than in granitic rocks.

• Nuclear Engineering and Technology
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• 제29권2호
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• pp.158-166
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• 1997

Integrated performance test of Chemical and Volume Control System was successfully performed in 1994. However, an extensive effort to correct hardware and software problems in the letdown line was required mainly due to the lack of adequate simulation code to predict the test accurately. Although the LTC computer code was used during the YGN 3'||'&'||'4 NSSS design process, the code can not satisfactorily predict the test due to it insufficient letdown line modeling. This study developed a numerical model to simulate the letdown test by modifying the current LTC code, and then verified the model by comparing with the test data. The comparison shows that the modified LTC computer code can predict the transient behavior of letdown system lese very well. Especially, the model was verified to be able to predict the "Stiction (composition of stick and friction)" phenomena which caused instantaneous fluctuations in the letdown backpressure and flowrate. Therefore, it is concluded that the modified LTC computer code with the ability of calculating the "Stiction" phenomena will be very useful for future plant design and test predictions.predictions.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 D
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• pp.1419-1421
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• 1998

Many kind of factors have influence on the electrical properties of polymer such as mechanical stress, impurity, additives, chemical blend, interfacial phenomena and so on. In this study, we lay emphasis on interfacial phenomena which is important part in insulating design of power cable. The electrical conduction characteristics of XLPE film are investigated as a function of different electrode materials in MIM Interfaces.

• 한국분무공학회지
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• 제18권2호
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• pp.94-99
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• 2013

The spherically-symmetric burning of an isolated droplet is a dynamic problem that involves the coupling of chemical reactions and multi-phase flow with phase change. For the improved understanding of these phenomena, this paper presents the numerical results on the n-heptane droplet combustion conducted at a 1 atm ambient pressure in three different initial droplet diameter ($d_0$). The main purpose of this study is to provide basic information of droplet burning, extinction and flame behavior of n-heptane and improve the ability of theoretical prediction of these phenomena. To achieve these, the numerical analysis was conducted in terms of normalized droplet diameter ($d/d_0$), flame diameter ($d_f$) and flame standoff ratio (FSR) under the assumptions that the droplet combustion can be described by both the quasi-steady behavior for the region between the droplet surface and the flame interface and the transient behavior for the region between the flame interface and ambient surrounding.

• Journal of Welding and Joining
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• 제17권1호
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• pp.116-123
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• 1999

The $CO_2$ welding with 100% $CO_2$ shielding gas is commonly used because of its cost and efficiency. Arc phenomena of the $CO_2$ welding is influenced by various factors such as chemical compositions of welding wire, shielding gas, welding condition and welding power source etc. In this study, arc phenomena is investigated by using two type of FCW(titania type, semi-metal type). Then, the welding quality and optimum welding condition can be selected. From this study, the following results were obtained; 1) In low current range(140A), FCW up to welding voltage(22V) resulted in a typical short circuit transfer. 2) In high current range(320A), the arc stability in titania FCW of a typical globular transfer is better than that of semi-metal FCW.

• 한국안전학회지
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• 제7권2호
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• pp.57-62
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• 1992

In this thesis, the electrification phenomenon was studied by measurement of charging current and discharging current in polymers when the carriers generated by corona discharge were supplied to the surface of polymers. Corona charging current of PVC, polar and noncrystalline polymer, was larger than that of nonpolar and amorphous polymers. Corona charging current on the specimen of naked upper surface (CIM) was larger than charging current on the specimen of electrode made. Carrier injection differed from interfacial phase of polymer surFace. The transfer phenomenon vaned with chemical structure of polymer and then the polar effect of PVC was remarkable because of large electron affinity of Cl. In the characteristics of discharging current of PVC, the abnormal current was observed. It was supposed that this phenomena presented the trap of injected carriers in PVC and that static electricity phenomenon was generated by trap.