• Title/Summary/Keyword: Chemical phenomena

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A Numerical Analysis of Supersonic Intake Buzz in an Axisymmetric Ramjet Engine

  • Yeom, Hyo-Won;Sung, Hong-Gye;Yang, Vigor
    • International Journal of Aeronautical and Space Sciences
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    • v.16 no.2
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    • pp.165-176
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    • 2015
  • A numerical analysis was conducted to investigate the inlet buzz and combustion oscillation in an axisymmetric ramjet engine with wedge-type flame holders. The physical model of concern includes the entire engine flow path, extending from the leading edge of the inlet center-body through the exhaust nozzle. The theoretical formulation is based on the Farve-averaged conservation equations of mass, momentum, energy, and species concentration, and accommodates finite-rate chemical kinetics and variable thermo-physical properties. Turbulence closure is achieved using a combined scheme comprising of a low-Reynolds number k-${\varepsilon}$ two-equation model and Sarkar's compressible turbulence model. Detailed flow phenomena such as inlet flow aerodynamics, flame evolution, and acoustic excitation as well as their interactions, are investigated. Mechanisms responsible for driving the inlet buzz are identified and quantified for the engine operating at subcritical conditions.

Nanodeformation Behaviors of the Single Crystal Silicon and the Pyrex glass 7740 during Nanoscratch (나노스크래치 공정에서 단결정 실리론 및 파이렉스 7740 의 나노변형거동)

  • 신용래;윤성원;강충길
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.10a
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    • pp.363-366
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    • 2003
  • In nanomachining processes, chemical effects are more dominant factor compared with physical deformation. For example, during the nanoscratch on a silicon surface in the atmosphere, micro protuberances are formed due to the mechanochemical reaction between the diamond tip and the surface. On the contrary, in case of chemically stable materials, such as ceramics or glasse, the surface protuberance are not formed. The purpose of this study is to understand effects of the mechanochemical reaction between tip and surfaces on deformation behaviors of hard-brittle materials. Nanometerscale elasoplastic deformation behavior of single crystal silicon (100) was characterized with the surface protuberance phenomena, and compared with that of borosilicate (Pyrex glass 7740).

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Hydriding Failure Analysis Based on PIE Data

  • Kim Yong-Soo
    • Nuclear Engineering and Technology
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    • v.35 no.5
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    • pp.378-386
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    • 2003
  • Recently failures of nuclear fuel rods in Korean nuclear power plants were reported and their failure causes have been investigated by using PIE techniques. Destructive and physico-chemical examinations reveal that the clad hydriding phenomena had caused the rod failures primarily and secondarily in each case. In this study, the basic mechanisms of the primary and the secondary hydriding failures are reviewed, PIE data such as cladding inner and outer surface oxide thickness and the restructuring of the fuel pellets are analyzed, and they are compared with the predicted behaviors by a fuel performance code. In addition, post-defected fuel behaviors are reviewed and qualitatively analyzed. The results strongly support that the hydriding processes, primary and secondary, played critical roles in the respective fuel rods failures and the secondary hydriding failure can take place even in the fuel rod with low linear heat generation rate.

Core-Shell Polymerization with Hydrophilic Polymer Cores

  • Park, Jong-Myung
    • Macromolecular Research
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    • v.9 no.1
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    • pp.51-65
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    • 2001
  • Two-stage emulsion polymerizations of hydrophobic monomers on hydrophilic seed polymer particles were carried out to make core-shell composite particles. It was found that the loci of polymerization in the second stage were the surface layer of the hydrophilic seed latex particles, and that it has resulted in the formation of either eccentric core-shell particles with the core exposed to the aqueous phase or aggregated nonspherical composite particles with the shell attached on the seed surface as many small separated particles. The driving force of these phenomena is related to the gain in free energy of the system in going from the hydrophobic polymer-water interface to hydrophilic polymer-water interface. Thermodynamic analysis of the present polymerization system, which was based on spreading coefficients, supported the likely occurrence of such nonspherical particles due to the combined effects of interfacial free energies and phase separation between the two polymer phases. A hypothetical pathway was proposed to prepare hydrophilic core-hydrophobic shell composite latex particles, which is based on the concept of opposing driving and resistance forces for the phase migration. It was found that the viscosity of the monomer-swollen polymer phase played important role in the formation of particle morphology.

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Electrochemistry Characterization of Metal Using Corrosion Inhibitors Containing Amide Functional Group (아미드 작용기를 가진 부식억제제를 사용한 금속의 전기화학적 특성)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.1
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    • pp.48-56
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    • 2011
  • In this study, we investigated the C-V diagrams and metal surface related to the electrochemistry characterization of metal(nickel, SUS-304). We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150, 200 and 250 mV/s. As a result, the C-V characterization of metal using N,N-dimethylacetamide and N,N-dimethylformamide inhibitors appeared irreversible process caused by the oxidation current from the cyclic voltammogram. After adding organic corrosion inhibitors, adsorption film constituted, and the passive phenomena happened. According to the results by cyclic voltammetry method, it was revealed that the addition of inhibitors containing amide functional group enhances the corrosion resistance properties.

NONCOMPETITIVE NMDA RECEPTOR ANTAGONISTS INHIBIT APOMORPHINE-INDUCED CLIMBING BEHAVIOR IN RESERPINE-TREATED MICE

  • Kim, Hack-Seang;Rhee, Gyu-Seek;Park, Woo-Kyu
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1996.04a
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    • pp.247-247
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    • 1996
  • Previous work in our laboratory has shown that noncompetitive N-methyl-D-aspartate (NMDA) receptor antagonists, MK-801, ketamine, dextrorphan and dextromethorphan cause a pronounced inhibition of apomorphine-induced cage climbing behavior in intact mice, suggesting the involvement of NMDA receptors in the glutamatergic modulation of dopaminergic function at the postsynaptic dopamine (DA) receptors: Therefore, in order to definitively establish the involvement of NMDA receptor in the apomorphine-induced dopaminergic response at the postsynaptic DA receptor, it is necessary to investigate whether or not the noncompetitive NMDA receptor antagonists would inhibit these phenomena not only in intact mice but also in the mice that are devoid of any involvement of indirect dopaminergic function. To minimize the risk of any indirect involvement of NMDA antagonists with DA neurons, vesicular DA stores were first depleted with reserpine.

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PSCAD/EMTDC Model of PEMFC for Power System Analysis (전력계통 해석을 위한 PEMFC의 PSCAD/EMTDC 모델)

  • Lee, Jong-Su;Kim, Hak-Man;Lee, Byoung-Kuk;Shin, Myong-Chul
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.1
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    • pp.9-14
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    • 2009
  • The modelling of PEMFC(Proton Exchange Membrane Fuel Cell) has been studied in many kinds of methods. But there are some limitations in application of the developed models to analyze transient phenomena of power systems. The PSCAD/EMTDC is very popular simulation tool in power system areas. To analyze power systems interconnected to PEMFCs, the PSCAD/EMTDC model of the PEMFCs is needed. In this paper, we developed a PSCAD/EMTDC model of PEMFC based on electro-chemical characteristic equations of PEMFC. Also, we performed simulations using the developed model in the PSCAD/EMTDC program and tested appropriateness of the proposed models. The simulations showed good results.

A Numerical Study of Heat and Mass Transfer Phenomena for Thermal Protection Material (열보호재료의 열 및 물질전달 현상에 관한 수치해석적 연구)

  • Kim, Jung-Hoon;Kwon, Chang-Oh;Seo, Jeong-Il;Bai, Cheol-Ho;Song, Dong-Joo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.9
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    • pp.1201-1212
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    • 1999
  • A numerical analysis is performed to predict the thermal response and ablation rate for charring or non-charring material which is designed to be used as thermal protection system (TPS). The numerical program composed of in-depth energy balance equation and the aerotherm chemical equilibrium (ACE) program. The ACE program calculates various thermochemical state from ablation products. The developed numerical program is verified by comparing the reported results from literature. The sensitivity tests for input parameters are performed. The thermal behavior of ablating material is mainly affected by density of ablating material, convective heat transfer coefficient and recovery enthalpy of flow field.

Turing, Turing Instability, Computational Biology and Combustion (Turing, Turing 불안정성 그리고 수리생물학과 연소)

  • Kim, J.S.
    • Journal of the Korean Society of Combustion
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    • v.8 no.1
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    • pp.46-56
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    • 2003
  • The present paper is concerned with the development of the computational biology in the past half century and its relationship with combustion. The modem computational biology is considered to be initiated by the work of Alan Turing on the morphogenesis in 1952. This paper first touches the life and scientific achievement of Alan Turing and his theory on the morphogenesis based on the reactive-diffusive instability, called the Turing instability. The theory of Turing instability was later extended to the nonlinear realm of the reactive-diffusive systems, which is discussed in the framework of the excitable media by using the Oregonator model. Then, combustion analogies of the Turing instability and excitable media are discussed for the cellular instability, pattern forming combustion phenomena and flame edge. Finally, the recent efforts on numerical simulations of biological systems, employing the detailed bio-chemical knietic mechanism is discussed along with the possibility of applying the numerical combustion techniques to the computational cell biology.

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Study on the 316LVM Stainless Steel for Surgical Implant Materials (생체용 316LVM 스테인레스강 개발에 관한 연구)

  • Sin, Myeong-Cheol;Lee, Gyu-Hwan;Lee, Han-Gu
    • Journal of Biomedical Engineering Research
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    • v.3 no.2
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    • pp.71-82
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    • 1982
  • The 316LVM stainless steel that is widely used in surgical implant has been studied. The objective of this study is to develop the domestic production of the surgical implant materials. In the work, the metalllirgical phenomena, physical and chemical properties and biocompatibility of the materials are investigated. According to the experimental observation, corrosion resistance is strongly depended on the -ferrite structure and passive film, and mechanical properties are mainly depended on the cold reduction ratio. The -ferrite structure is minimized in the 16.651 Cr and 14%Ni contents, and yield strength is 104 kg/mm$^2$ at 45% cold reduction. Biocompatibility is excellent in the mouse body test for six weeks.

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