• 대한설비공학회지:설비저널
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• 제8권1호
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• pp.10-13
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• 1979

The study for bubbling phenomena to influence heat transfer in gas - liquid contactors. The sparged contactor is gaining importance for gas-liquid chemical reactions. In this paper, correlations between Reynolds number and heat transfer coefficient were studied and experimental expressions were also obtained over broth of areas, namely, laminar area and turbulent area respectively.

• 한국세라믹학회지
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• 제49권1호
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• pp.29-36
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• 2012

In many applications of functional oxides originally homogeneous materials are exposed to gradients in the chemical potential of oxygen. Prominent examples are solid oxide fuel cells (SOFCs) or oxygen permeation membranes (OPMs). Other thermodynamic potential gradients are gradients of electrical potential, temperature or uni-axial pressure. The applied gradients act as generalized thermodynamic forces and induce directed fluxes of the mobile components. These fluxes may lead to three basic degradation phenomena of the materials, which are kinetic demixing, kinetic decomposition, and morphological instabilities.

• Korea-Australia Rheology Journal
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• 제13권1호
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• pp.19-27
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• 2001

In this symposium paper, the migration and hydrodynamic diffusion of non-colloidal, spherical particles suspended in polymer solutions are considered under Poiseuille or torsional flows. The migration phenomena in polymer solutions are compared with those in Newtonian fluids and the effect of fluid elasticity is discussed. The experimental results on particle migration in dilute polymer solution reveal that even a slight change in the rheological property of the dispersing medium can induce drastic differences in flow behavior and migration of particles, especially in dilute and semi-concentrated suspensions.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2005년도 춘계학술발표회
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• pp.103-104
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• 2005

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2002년도 동계연구발표회 논문개요집
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• pp.42-43
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• 2002

Spintronics is a rapidly expanding research area because of recent developments in the physics of spin-dependent phenomena. For use as spintronic materials, dilute magnetic semiconductors (DMS) are of considerable interest as spin injectors for spintronic devices.$^{[1]}$ Many researchers have studied DMS, in which transition metal atoms are introduced into the lattice, thus inserting local magnetic moments into the lattice. (omitted)

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2005년도 추계학술발표회
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• pp.93-94
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• 2005

• Korean Chemical Engineering Research
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• 제52권6호
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• pp.826-833
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• 2014

해양 중소규모 가스전의 경제성에 대한 화두가 던져진 이후 전통 석유의 가격변동과 세계적인 환경규약 등에 맞물려 석유화학관련 산업계에서는 이를 효과적으로 대처하고 천연가스를 활용할 수 있는 공정을 개발하고자 하였다. 이에 Fischer-Tropsch 반응을 기반으로 하는 해상 GTL 공정(offshore gas-to-liquid process)이 제안되었고 부유시스템 platform으로 공정을 적용시키고자 마이크로채널 반응기가 떠오르고 있다. 본 논문에서는 단일 마이크로채널 반응기를 Fischer-Tropsch 반응을 기반으로 하여 Matlab과 ASPEN Hysys를 연동하여 모사하고 이로 얻어진 반응열을 도입해 상용 전산유체역학(computational fluid dynamics, CFD) 소프트웨어인 ANSYS fluent로 멀티 마이크로채널 반응기 모델을 제작하였다. 그리고 4가지의 설계변수인 냉각채널 넓이, 높이, 냉각채널과 반응채널의 간격, 냉각채널 간의 간격을 설정하고 이들의 변화에 따른 열유동을 3가지의 변수인 열유속, 냉각 및 반응채널의 최대온도의 변화를 시각화하여 그 경향성을 확인하였다. 경향성 분석 결과, 냉각채널의 넓이와 높이는 짧을수록 총 열유속이 높아졌으며 최대온도 역시 높아졌으나 냉각채널과 반응채널의 간격은 열유동에 거의 영향을 미치지 못하였다. 냉각채널 간의 간격은 짧을수록 총 열유속이 높아졌으며 최대온도는 낮아졌다. 따라서 적절한 냉각채널의 넓이와 높이를 제안하고 짧은 간격의 냉각채널 구조를 도입하여 반응채널의 열량을 충분히 제거할 수 있는 반응기설계에 대한 휴리스틱을 제안할 수 있었다. 이처럼 멀티채널 반응기의 모델을 설계하고 이로부터 적절한 변수를 선택해 그 경향성을 확인할 수 있는 방법을 통해 설계 단계에서부터 적절한 반응기 구조에 대한 제안을 하는데 도움을 줄 것이다.

• 한국세라믹학회지
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• 제22권6호
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• pp.5-8
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• 1985

Graphite has been oxidized to graphite hydrogen sulfate in concentrated $H_2SO_4$. Anodic oxidation and chemical oxidation of graphite in $H_2SO_4$ generally leads to the formation of intercalation compounds of the ionic salt type through incorporation of $H_2SO_4^-$ions and $H_2SO_4$ molecules into the graphite. Several other reactions also accur at various points of the charging cycle. But there is no satisfactory kinetics and mechanism of intercalationin graphite. We have studied them with anodic oxidation and chemical oxidation. We found six distinct phenomena between 2nd stage and 1st stage in chemical oxidation. We examined them in detail by the following in the measurements electrical oxidation. X-ray diffractions UV-Vis spectroscopy density measurements. We could obtained a equation for kinetic according to the reaction rate from this results and mechanism of intercalation between 2nd stage and 1st stage with hydrogen sulfate in graphite. Three thesis were written for the mechanism of intercalation compounds in graphite with hydrogen sulfate ; first thesis is anodic oxidation second thesis is chemical oxidation and definition of transit phase between 2nd etc the third thesis is the kinetic mechanism of intercalation compounds in graphite with Hydrogen sulfate. This thesis is the first paper among three thesis as anodic oxidation.

• 한국자동차공학회논문집
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• 제11권6호
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• pp.51-58
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• 2003

A cycle simulation method is developed by coupling a commercial code, Ricardo's WAVE, with the SENKIN code from CHEMKIN packages to predict combustion characteristics of an HCCI engine. By solving detailed chemical kinetics the SENKIN code calculates the combustion products in the combustion chamber during the valve closing period, i.e. from IVC to EVO. Except the combustion chamber during the valve closing period the WAVE code solves thermodynamic status in the whole engine system. The cycle simulation of the complete engine system is made possible by exchanging the numerical solutions between the codes on the coupling positions of the intake port at IVC and of the exhaust port at EVO. This method is validated against the available experimental data from recent literatures. Auto ignition timing and cylinder pressure are well predicted for various engine operating conditions including a very high ECR rate although it shows a trend of sharp increase in cylinder pressure immediate after auto ignition. This trend is overpredicted especially for EGR cases, which may be due to the assumption of single-zone combustion model and the limit of the chemical kinetic model for the prediction of turbulent air-fuel mixing phenomena. A further work would be needed for the implementation of a multi-zone combustion model and the effect of turbulent mixing into the method.

• 한국입자에어로졸학회지
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• 제11권4호
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• pp.99-105
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• 2015

The possible existence forms of particle aggregates in liquid medium are classified into four different types according to their morphological characteristics, including the single particles that are separated from each other, the linear aggregates in which all component particles are located in a line, the planar aggregates where all particles are arranged on a plane, and the volumetric aggregates where all particles forms a three-dimensional space. These particle aggregates with different space morphologies have different fractal dimensions and different influence on the rheological phenomena of the solid-liquid system. The effects of various aggregates on the suspension viscosity are analyzed and related with the particle concentration, and then a mathematical model is presented to determine the fractal dimensions of various aggregates by measuring the apparent viscosity of the solid-liquid system. In the model, the viscous fractal dimension is developed as a new concept, the fractal dimensions of different aggregates can be obtained separately and then the relative components of various aggregates experimentally analyzed.