• Korean Journal of Materials Research
• /
• v.23 no.4
• /
• pp.227-232
• /
• 2013

Al-based alloys have recently attracted considerable interest as structural materials and light weight materials due to their excellent physical and mechanical properties. For the investigation of the potential of Al-based alloys, a surface porous $Al_{88}Cu_6Si_6$ eutectic alloy has been fabricated through a chemical leaching process. The formation and microstructure of the surface porous $Al_{88}Cu_6Si_6$ eutectic alloy have been investigated using X-ray diffraction and scanning electron microscopy. The $Al_{88}Cu_6Si_6$ eutectic alloy is composed of an ${\alpha}$-Al dendrite phase and a single eutectic phase of $Al_2Cu$ and ${\alpha}$-Al. We intended to remove only the ${\alpha}$-Al phase and then the $Al_2Cu$ phase would form a porous structure on the surface with open pores. Both acidic and alkaline aqueous chemical solutions were used with various concentrations to modify the influence on the microstructure and the overall chemical reaction was carried out for 24 hr. A homogeneous open porous structure on the surface was revealed via selective chemical leaching with a $H_2SO_4$ solution. Only the ${\alpha}$-Al phase was successfully leached while the morphology of the $Al_2Cu$ phase was maintained. The pore size was in a range of $1{\sim}5{\mu}m$ and the dealloying depth was nearly $3{\mu}m$. However, under an alkaline NaOH, aqueous solution, an inhomogeneous porous structure on the surface was formed with a 5 wt% NaOH solution and the morphology of the $Al_2Cu$ phase was not preserved. In addition, the sample that was leached by using a 7 wt% NaOH solution crumbled. Al extracted from the Al2Cu phase as ${\alpha}$-Al phase was dealloyed, and increasing concentration of NaOH strongly influenced the morphology of the $Al_2Cu$ phase and sample statement.

• Resources Recycling
• /
• v.10 no.5
• /
• pp.29-35
• /
• 2001

This study was carried out to recover gold, silver and valuable metals from the printed circuit boards (PCBs) of waste computers. PCBs samples were crushed under 1 mm by a shredder and separated into 30% conducting and loft nonconducting materials by an electrostatic separator. The conducting materials contained valuable metals which were then used as feed materials for magnetic separation. 42% of magnetic materials from the conducting materials was removed by magnetic separation as nonvaluable materials and the others, 58% of non magnetic materials, was used as leaching samples containing 0.227 mg/g Au and 0.697 mg/g Ag. Using the materials of leaching from magnetic separation, more than 95% of copper, iron, zinc, nickel and aluminium was dissolved in 2.0M sulfuric acid solution, added with 0.2M hydrogen peroxide at $85^{\circ}C$. Au and Ag were not extracted in this solution. On the other hand, more than 95% of gold and 100% of silver were leached by the selective leaching with a mixed solvent (0.2M($NH_4$)$_2$$S_2$$O_3$,0.02M $CuSO_4$,0.4M $NH_4$OH). Finally, the residues were reacted with a NaCl solution to leach Pb whereas sulfuric acid was used to leach Sn. Recoveries reached 95% and 98% in solution, respectively.

• Journal of The Korean Society of Grassland and Forage Science
• /
• v.22 no.2
• /
• pp.85-92
• /
• 2002

This study was conducted to investigate the effects of application levels of swine waste and chemical fertilizer on productivity of corn and nitrogen and phosphorus leaching in Lysimeter containing sandy loam soil. Main Plots were consisted of two types of swine waste, such as swine slurry(SS) and compost of swine manure fermented with sawdust(CSMFS), and chemical fertilizer(CF) and the subplots were consisted of application levels of N-fertilezer, such as 100kgN/ha, 200kgN/ha and 400kgN/ha. Lysimeters were constructed with 1m depth, 30cm diameter. The results obtained were summarized as follows ; 1. Dry matter(DM) yield of com enhanced as increased application levels of SS, CSMFS and CF. DM yield reveals that there is an increase in order CS > SS > CSMFS. 2. Nitrogen contents of the whole corn enhanced as increased application levels of SS, CSMFS and CF. Nitrogen content reveals that there is an increase in order CS > SS > CSMFS. 3. $NO_3^{-}$ and P contents in the leaching water increased as increased application levels of SS, CSMFS and CF. $NO_3^{-}$ content was highly elevated in the concentrated rainy season in the experimental early stage. However, P content was affected with the rainfall. The maximum $NO_3^{-}$ and P contents in the leaching water were 14.8ppm and 0.26ppm, respectively.ively.

• Journal of The Korean Society of Grassland and Forage Science
• /
• v.40 no.2
• /
• pp.117-122
• /
• 2020

This study was conducted to figure out the productivity of Italian ryegrass(IRG) and leaching water characteristics based on horse manure compost level in Jeju. This study was conducted for about six months. Six treatments were established : non-fertilizer(NF), chemical fertilizer 100%(CF), horse manure compost 50% and chemical fertilizer 50% combination(Combination), horse manure compost with 50% of nitrogen (50%), 100% of nitrogen(100%), 150% of nitrogen(150%). The highest amount of dry matter yield of IRG was revealed in CF(11,965±564 kg/ha), and both 150% and Combination were second(p<0.05). Nitrate leaching tended to increase until the third analysis and then decreased. There were not significantly differences among mean nitrate concentrations. The findings of the study suggest that horse manure compost with 50% of nitrogen be applied for IRG as basal fertilization and then 50% of chemical fertilizer be applied as top fertilization.

• Nuclear Engineering and Technology
• /
• v.55 no.8
• /
• pp.2773-2784
• /
• 2023

It is essential to evaluate the blasting-enhanced permeability (BEP) feasibility of a low-permeability sandstone-type uranium deposit. In this work, the mineral composition, reservoir physical properties and rock mechanical properties of samples from sandstone-type uranium deposits were first measured. Then, the reformability evaluation method was established by the analytic hierarchy process-entropy weight method (AHP-EWM) and the fuzzy mathematics method. Finally, evaluation results were verified by the split Hopkinson Pressure Bar (SHPB) experiment and permeability test. Results show that medium sandstone, argillaceous sandstone and siltstone exhibit excellent reformability, followed by coarse sandstone and fine sandstone, while the reformability of sandy mudstone is poor and is not able to accept BEP reservoir stimulation. The permeability improvement and the distribution of damage fractures before and after the SHPB experiment confirm the correctness of evaluation results. This research provides a reformability evaluation method for the BEP of the low-permeability sandstone-type uranium deposit, which contributes to the selection of the appropriate regional and stratigraphic horizon of the BEP and the enhanced ISL of the low-permeability sandstone-type uranium deposit.

• Journal of the Korean GEO-environmental Society
• /
• v.2 no.1
• /
• pp.15-22
• /
• 2001

The key part in risk assessments for disposal sites of solidified/stabilized (S/S) wastes is to predict the contaminant transport from the S/S wastes to the environment under dynamically changing field conditions after characterizing chemical leaching properties of the ash, to evaluate the risk from the predictions, and finally to decide the risk is acceptable. In this paper, a risk assessment framework for disposal and reuse of S/S wastes was developed considering two limiting cases of contaminant leaching. Two types of waste characterization procedures that can determine waste-specific variables for the two limiting cases were developed and verified by applying them to a landfill site of the Municipal Solid Waste incinerator ash solidified/stabilized by cement.

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.42 no.2
• /
• pp.55-62
• /
• 2000

In order to make the reasonable irrigation plan in the unripended tidal reclaimed paddy fields, the estimation of irrigation water requirements by soil textures and water management methods for the normal growth of crops is very important . This study was carried out to determine leaching requirements before cultivating crops. For the purpose of this study, the physical and chemical properties of soil samples used in the desalinization experiments were analyzed, and change of salinity by supplying water and leaching water were investigated in the experimental field with lysimeters. As a result considering the soil textures, desalinization effects of good drainage soils(S1) were better than those of poor drainage soils (S2). In the changes of salinity of the soils with supplying water by water management methods, among the good grainage soils with culvert treatment(S1CW), salinity of S1CW3 with 1, 120mm and S1W4 with 1, 440mm supplying water were 2.6dS/m and 1.1dS/m respectively, and salinity of S1NW4 with 1.680mm among those non-culvert treatment (S1NW) was 3.0dS/m, less than critical salanity value 3.0dS/m. On the other hand, of the poor drainage soils with cultvert treatment , salinity of S2CW3 was ranged 9.4-6.0dS/m with supplied water, and that of non-culverted treatment S2NW as 12.3-8.4dS/m.

• Korean Journal of Agricultural Science
• /
• v.41 no.4
• /
• pp.369-377
• /
• 2014

This study was carried out to evaluate the effect of rice husk (RHB) and food waste biochar (FWB) on upland soil with sandy loam texture, in terms of physico-chemical analysis, lettuce seed germination test, and orgainc carbon leaching experiment. RHB and FWB had different physico-chemical properties each other. Carbon to nitrogen ratio (C/N ratio) of RHB was 32, showing two times higher than that of FWB. FWB had high salt and heavy metal content, compared to RHB. This is probably due to different ingredients and production processing between two biochars each other. Results of germination test with Lettuce showed lower germination rate when FWB was applied because of higher salt concentration compared to control and RHB. Organic carbon leaching test using saturated soil column (${\Phi}75{\times}h75mm$) with $10MT\;ha^{-1}$ biochar application rate, showed higher saturated hydraulic conductivity in rice husk biochar treatment column, compared to control and food waste biochar treatment. The highest total organic carbon concentration in column effluent was lower than those in both of rice husk biochar and food waste biochar, whereas the differences was negligible after 9 pore volumes of effluent. Consequently, biochars from byproducts such as rice husk and food waste in sandy loam textured upland soil could enhance a buffer function such as reduction of leaching from soil, but the harmful ingredient to crops such as high salt and heavy metals could limit the agricultural use of biochars.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.18 no.4
• /
• pp.509-516
• /
• 2020

An important property of glass and ceramic solid waste forms is processability. Tellurite materials with low melting temperatures and high halite solubilities have potential as solid waste forms. Crystalline TiTe3O8 was synthesized through a solid-state reaction between stoichiometric amounts of TiO2 and TeO2 powder. The resultant TiTe3O8 crystal had a three-dimensional (3D) structure consisting of TiO6 octahedra and asymmetric TeO4 seesaw moiety groups. The melting temperature of the TiTe3O8 powder was 820℃, and the constituent TeO2 began to evaporate selectively from TiTe3O8 above around 840℃. The leaching rate, as determined using the modified American Society of Testing and Materials static leach test method, of Ti in the TiTe3O8 crystal was less than the order of 10-4 g·m-2·d-1 at 90℃ for durations of 14 d over a pH range of 2-12. The chemical durability of the TiTe3O8 crystal, even under highly acidic and alkaline conditions, was comparable to that of other well-known Ti-based solid waste forms.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2005.10a
• /
• pp.83-84
• /
• 2005