• Title/Summary/Keyword: Chemical laboratory

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Crystal Structure, Fluorescence Property and Theoretical Calculation of the Zn(II) Complex with o-Aminobenzoic Acid and 1,10-Phenanthroline

  • Zhang, Zhongyu;Bi, Caifeng;Fan, Yuhua;Zhang, Xia;Zhang, Nan;Yan, Xingchen;Zuo, Jian
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1697-1702
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    • 2014
  • A novel complex [$Zn(phen)(o-AB)_2$] [phen: 1,10-phenanthroline o-AB: o-aminobenzoic acid] was synthesized and characterized by elemental analysis and X-ray diffraction single-crystal analysis. The crystal crystallizes in monoclinic, space group P2(1)/c with $a=7.6397(6){\AA}$, $b=16.8761(18){\AA}$, $c=17.7713(19){\AA}$, ${\alpha}=90^{\circ}$, ${\beta}=98.9570(10)^{\circ}$, ${\gamma}=90^{\circ}$, $V=2.2633(4)nm^3$, Z = 4, F(000) = 1064, S = 1.058, $Dc=1.520g{\cdot}cm^{-3}$, $R_1=0.0412$, $wR_2=0.0948$, ${\mu}=1.128mm^{-1}$. The Zn(II) is six coordinated by two nitrogen and four oxygen atoms from the 1,10-phenanthroline and o-aminobenzoic acid to furnish a distorted octahedron geometry. The complex exhibits intense fluorescence at room temperature. Theoretical studies of the title complex were carried out by density functional theory (DFT) B3LYP method. CCDC: 898291.

Hyper Functionalized Nanoparticle Technology and their Applications

  • Lee, Sun-Jong;Jung, Yeon-Jae;Lee, Jung-Min;Lee, Jun-Young;Kim, Jung-Hyun
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.83-84
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    • 2006
  • In aqueous phase, we directly prepared conducting and photoluminescent nano-structured particles by oxidation polymerization. Thiophene(PT) was initiated by $FeCl_{3}/H_{2}O_{2}$ (catalyst/oxidant) combination system. And, polydispersed core-shell poly(styrene/thiophene) and polyaniline(PANI)-coated multi core-shell polystyrene latex particles were successfully prepared by oxidative and radical polymerization. The resulting latex particles have fine improved luminescence and conductive efficiency and dispersion state due to the PT and PANI shell. Hyper functionalized nanoparticle would be expected to increase the processibility in various electrical and electro-optical fields.

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Heavy Metals In The Nagdong Estuary

  • Lee, Soo-Hyung;Lee, Dong-Soo;Kim, Eun-Soo;Kwak, Hi-Sang;Lee, Kwang Woo
    • 한국해양학회지
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    • v.16 no.1
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    • pp.24-30
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    • 1981
  • In order to investigate water pollution of heavy metals in the Nagdong Estuary, samples were collected five times from August 1978 to April 1979 every other month, and analyzed for Cd, Cu, Pb and Zn by atomic absorption spectrophotometry. The results showed no significant heavy metal pollution in most parts of the studied areas, except near the outfalls of the Sasang Industrial Complex. In general, the heavy metal contents were higher in the dry season than in the rainy season due to the dilution effect of river water flow. Distribution of heavy metals in the dissolved and the particulate fractions were also investigated.

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Controlled synthesis of mesoporous codoped titania nanoparticles and their photocatalytic activity

  • Mathis, John E.;Kidder, Michelle K.;Li, Yunchao;Zhang, Jinshui;Paranthaman, M.P.
    • Advances in nano research
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    • v.4 no.3
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    • pp.157-165
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    • 2016
  • The photocatalytic (PC) activity of anatase titania nanoparticles can be improved through codoping with transition metals and nitrogen. In addition, the PC activity can also be improved by creating monodisperse, mesoporous nanoparticles of titania. The question naturally arose as to whether combining these two characteristics would result in further improvement in the PC activity or not. Herein, we describe the synthesis and photocatalytic characteristics of codoped, monodisperse anatase titania. The transition metals tested in the polydisperse and the monodisperse forms were Mn, Co, Ni, and Cu. In each case, it was found that the monodisperse version had a higher PC activity compared to the corresponding polydisperse version.