• Title/Summary/Keyword: Chemical hydrogen storage

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Hydrogen Production Systems through Water Electrolysis (물 전기분해에 의한 수소제조 기술)

  • Hwang, Gab-Jin;Choi, Ho-Sang
    • Membrane Journal
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    • v.27 no.6
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    • pp.477-486
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    • 2017
  • Hydrogen is one of energy storage systems, which could be transfer from electric energy to chemical energy or from chemical energy to electric energy, and is as an energy carrier. Water electrolysis is being investigating as one of the hydrogen production methods. Recently, water electrolysis receive attention for the element technology in PTG (power to gas) and PTL (power to liquid) system. In this paper, it was explained the principle and type for the water electrolysis, and recent research review for the alkaline water electrolysis.

Activation Characteristics of Metal Hydride Chemical-Treated and Fixed in an Adhesive (화성처리 및 성형화에 따른 금속수소화물의 활성화거동)

  • Han, H.K.;Park, C.K.
    • Journal of Hydrogen and New Energy
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    • v.6 no.2
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    • pp.85-90
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    • 1995
  • Activation behavior, hydriding rate and disintegration were tested for hydrogen storage alloy particles fixed in an adhesive after treating with inorganic solution. Commertial adhesive as a binder was used. Chemical-treated particles showed the best characteristics for activation and a little effect of prevention the break down of the powders themselves after several repeated operations. Furthermore activation characteristics were found to show a similar trend to chemical-treated powders even in the fixed one with an adhesive, except for a slight decrease in reaction velocity.

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Equilibrium and Hydriding Characteristics of Metal Hydride Chemical-Treated and Compacted in Pellet (화성처리 및 성형화에 따른 금속수소화물의 평형특성 및 수소흡장거동)

  • Park, C.K.;Cho, T.H.
    • Journal of Hydrogen and New Energy
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    • v.5 no.1
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    • pp.9-17
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    • 1994
  • Activation behavior, hydriding rate and disintegration were studied for a compact in pellet form and hydrogen storage alloy particles treated with newly developed inorganic solution. Cylindrical disc of 12.95mm diameter and of 7.1mm thickness was prepared by compressing(8ton) a mixture of $MmNi_{4.5}Al_{0.47}$ and PTFE. Chemical treatment of particles with 1mol of solution was performed at room temperature for several hours until the pH of solution did not change. Chemical treatment made much accelerated activation without any incubation period which generally exists in the untreated alloys and the hydriding reaction rate after full activation also was improved.

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A Study on the Response Technique for Toxic Chemicals Release Accidents - Hydrogen Fluoride and Ammonia - (독성 화학물질 누출사고 대응 기술연구 - 불산 및 암모니아 누출을 중심으로 -)

  • Yoon, Young Sam;Cho, Mun Sik;Kim, Ki Joon;Park, Yeon Shin;Hwang, Dong Gun;Yoon, Jun heon;Choi, Kyung Hee
    • Korean Journal of Hazardous Materials
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    • v.2 no.1
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    • pp.31-37
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    • 2014
  • Since the unprecedented hydrogen fluoride leak accident in 2012, there has been growing demand for customized technical information for rapid response and chemical accident management agencies including the Ministry of Environment, the National Emergency Management Agency, and the National Police Agency need more information on chemicals and accident management. In this regard, this study aims to provide reliable technical data and guidelines to initial response agencies, similar to accident management technical reports of the US and Canada. In this study, we conducted a questionnaire survey and interviews on initial response agencies like fire stations, police stations, and local governments to identify new information items for appropriate initial response and improvements of current guidelines. We also collected and reviewed the Canada's TIPS, US EPA's hydrogen fluoride documents, domestic and foreign literature on applicability tests of control chemicals, and interview data, and then produced items to be listed in the technical guidelines. In addition, to establish database of on-site technical information, we carried out applicability tests for accident control data including ① emergency shut down devide, safety guard, shut down valve, ground connection, dyke, transfer pipe, scrubber, and sensor; ② literature and field survey on distribution type and transportation/storage characteristics (container identification, valve, ground connection, etc.); ③ classification and identification of storage/transportation facilities and emergency management methodslike leak prevention, chemicals control, and cutoff or bypass of rain drainage; ④ domestic/foreign analysis methods and environmental standards including portable detection methods, test standards, and exposure limits; and ⑤ comparison/evaluation of neutralization efficiency of control chemicals on toxic substances.

Hydrogen Storage by Carbon Fibers Synthesized by Pyrolysis of Cotton Fibers

  • Sharon, Maheshwar;Sharon, Madhuri;Kalita, Golap;Mukherjee, Bholanath
    • Carbon letters
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    • v.12 no.1
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    • pp.39-43
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    • 2011
  • Synthesis of carbon fibers from cotton fiber by pyrolysis process has been described. Synthesis parameters are optimized using Taguchi optimization technique. Synthesized carbon fibers are used for studying hydrogen adsorption capacity using Seivert's apparatus. Transmission electron microscopy analysis and X-ray diffraction of carbon fiber from cotton suggested it to be very transparent type material possessing graphitic nature. Carbon synthesized from cotton fibers under the conditions predicted by Taguchi optimization methodology (no treatment of cotton fiber prior to pyrolysis, temperature of pyrolysis $800^{\circ}C$, Argon as carrier gas and paralyzing time for 2 h) exhibited 7.32 wt% hydrogen adsorption capacity.

Effects of Process Variables on the Growth of Dendrite in the Electrochemical Alane(AlH3) Production Process (전기화학적 알레인(AlH3) 제조 공정에서 덴드라이트의 성장에 미치는 공정 변수 영향)

  • KIM, HYOSUB;PARK, HYUNGYU;PARK, CHUSIK;BAE, KIKWANG;KIM, YOUNGHO
    • Journal of Hydrogen and New Energy
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    • v.26 no.6
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    • pp.532-540
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    • 2015
  • Electrochemical alane ($AlH_3$) production process can be provided as a synthesis route which close a reversible cycle. In this study, growth inhibition of dendrite as key issues in this process was investigated. Main cause of dendrite growth was because Al fine powder separated in consumption process of Al electrode was moved to Pd electrode. In an effort to avoid this, use of glass block with uniform holes was the most effective to inhibit the amount of dendrite to that of $AlH_3$. Furthermore, effects of Al electrode (anode) type and electrolyte concentration were investigated and the optimal condition for inhibiting dendrite formation was proposed.