• 제목/요약/키워드: Chemical factors

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전산기를 이용한 화학 공정 제어 (Computer aided chemical process control)

  • 김영철;노승백;김종득
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1986년도 한국자동제어학술회의논문집; 한국과학기술대학, 충남; 17-18 Oct. 1986
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    • pp.463-467
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    • 1986
  • Here are summarized the trends and the problems of process control. And both the structure and the elements of digital computer based process control systems are also illuminated ; Briefly introduced the factors, of importance, influencing design strategy, and those to be considered when the process control is applied to physical systems using computer and computer-related instruments.

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지하수 오염 (Groundwater Contamination)

  • 전효택
    • 수도
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    • 제25권1호통권88호
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    • pp.25-35
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    • 1998
  • Factors controlling water quality, water-quality standards, and normal ranges of concentrations in unpolluted fresh water and the sources of elements were explained in this paper. In particular, the sources of groundwater contamination such as the disposal of domestic waste water, landfills, chemical spills and leaking underground tanks, and agricultural and mining activities were discussed.

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Improved Performance in Polymer/Polymer Solar Cells

  • Kim, Young-Kyoo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1129-1129
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    • 2009
  • Here the improved performance of polymer/polymer solar cells, which are of importance to achieve real plastic solar cells in the near future, is reported. First, the progress in polymer/polymer solar cells is briefly reviewed and then the limiting factors are discussed in terms of charge transport.

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소비 생활용품의 노출계수 조사 방법의 고찰 (Review of Exposure Assessment to Obtain Exposure Factors of Consumer Products)

  • 박지영;이기영;신호상;양원호
    • 한국환경보건학회지
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    • 제39권6호
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    • pp.532-540
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    • 2013
  • Background: Exposure factors for consumer products have been developed since the 1980s. Such exposure factors are important in risk assessment. Since the exposure/use patterns of consumer products in a country may reflect its respective cultural, meteorological, and socio-economic circumstances, unique Korean exposure factors for consumer products are needed. Such exposure factors are required for newly-enacted chemical regulations in Korea. For this review, published papers and survey reports on exposure factors of consumer products were examined for their assessment methodologies. Results: Investigation into exposure factors for consumer products used a variety of methods: home visit, online, telephone, and mail surveys using questionnaires; face to face interviews; modeling using a constructed database; and direct measurement. To collect more accurate exposure information or to check the reliability of the sampling method, some studies were repeated using the same questionnaire, in-home observation, direct measurement of usage, and videotaping. In Korea, nationwide exposure surveys were conducted five times over five years to obtain Korean exposure factors. However, with the exception of the $5^{th}$-year study, the surveys were online questionnaires and only the $5^{th}$-year study validated the accuracy of exposure information by re-visits and direct measurement. Conclusion: Accurate exposure factors are an essential part of risk assessment to assure safe use of consumer products. For better and safer management of consumer products, accurate exposure factors in Korea should be assessed for various exposure pathways.

영천댐의 식물플랑크톤 군집과 환경요인의 동태 (Dynamics of Phytoplankton Community and the Physico-chemical Environmental Factors in Youngchun Dam)

  • 김숙찬;김한순
    • ALGAE
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    • 제19권3호
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    • pp.227-234
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    • 2004
  • A study on the dynamics of phytoplankton community and the physico-chemical environmental factors was performed biweekly from April 1998 to March 1999 in Youngchun Dam. A total 72 phytoplankton taxa was identified and dominant taxa were blue-green algae and diatoms. The highest value of phytoplankton standing crop (24,826cells·ml$^{-1}$) was observed in September 7, 1998, the blooming period of blue-green algae Phormidium sp., while the lowest (318cells·ml$^{-1}$) was measured in June 18, 1999. The phytoplankton communities were dominated by blue-green algae of Anabaena planktonica, Microcystis aeruginosa and Phormidium sp. during the summer and autumn periods and were dominated by diatoms of Synedra acus and Aulacoseira spp. during the spring and winter periods. Secchi disc transparency, chlorophyll-a, total nitrogen, total phosphorus and silicate concentration were varied in the ranges of 0.4-2.5 m, 2.4-32.2mg·m$^{-1}$, 0.845-2.352mg·l$^{-1}$, 0.005-0.093mg·l$^{-1}$, 0.2-15.7mg·l$^{-1}$, respectively. The trophic status of Youngchun Dam were estimated eutrophic according to Lake Trophic States Index (LTSI).

15-crown-5가 결합된 Silica Gel을 이용한 Sb(Ⅲ)의 분리 (Separation of Sb(Ⅲ) by the Silica Gel Bonded 15-crown-5)

  • 김해중;김정;김시중
    • 대한화학회지
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    • 제39권7호
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    • pp.524-529
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    • 1995
  • pH 1에서 15-crown-5(SGBM)을 결합시킨 silica gel를 고정상으로 하는 액체 크로마토그래피을 이용하여 혼합 금속이온 용액으로부터 금속이온들의 분리효율을 결정하였다. 여러가지 SGBM-금속이온들간의 결합상수 및 분리인자들을 측정한 결과 그 순위는 Li(Ⅰ) < Sr(Ⅱ) < Na(Ⅰ) < Cu(Ⅱ) < Mg(Ⅱ) < K(Ⅰ) < Ca(Ⅱ) < Bi(Ⅲ) < Sb(Ⅲ)로 나타났다. 이러한 사실은 금속이온의 크기 효과 및 전자 밀도 효과에 의해서 결정됨을 알 수 있었으며, 또한 알칼리, 알칼리 토금속이온 및 $Cu^{2+}$이 혼합된 용액에서 $Sb^{3+}$의 분리효율이 다른 이온들에 비해서 훨씬 좋게 나타남을 알았다.

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Resolution of Aryl α-Aminoalkyl Ketones on a Doubly Tethered Liquid Chromatographic Chiral Stationary Phase Based on (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic Acid

  • Jin, Kab-Bong;Kim, Hee-Jin;Hyun, Myung-Ho
    • 대한화학회지
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    • 제55권5호
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    • pp.751-755
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    • 2011
  • A doubly tethered chiral stationary phase (CSP) based on (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid was applied to the resolution of various aryl ${\alpha}$-aminoalkyl ketones with the use of 80% ethanol in water containing 10 mM sulfuric acid as a mobile phase. The chiral resolution was quite successful, the separation factors (${\alpha}$) and the resolutions ($R_S$) being in the range of 1.39-2.05 and 3.18-5.22, respectively. The separation factors (${\alpha}$) on the doubly tethered CSP were slightly worse than those on the corresponding singly tethered CSP. However, the resolutions ($R_S$) on the doubly tethered CSP were generally greater than those on the corresponding singly tethered CSP. The chromatographic behaviors for the resolution of aryl ${\alpha}$-aminoalkyl ketones on the doubly tethered CSP were demonstrated to be dependent on the type and the content of the organic and acidic modifiers in aqueous mobile phase and the column temperature.

Comparison Study of Sensitivity Factors of Elements in Glow Discharge- & Inductively Coupled Plasma- Mass Spectrometry

  • Kim, Young-Sang;Plotnikov, M.;Hoffmann, Volker
    • Bulletin of the Korean Chemical Society
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    • 제26권12호
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    • pp.1991-1995
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    • 2005
  • Sensitivity factors of elements by a glow discharge mass spectrometry (GD-MS) were intensively investigated and compared with a laser ablation inductively coupled plasma-mass spectrometry (ICP-MS). In case of copper matrix, the sensitivity factor by GD-MS generally decreases with the increase of the mass number of element. The details are a little different between each data measured by Faraday and multiplier detectors. The factor by a multiplier detector drastically decreases with the mass increase in the region of low mass as in Faraday detector’s case, but slowly in the high mass region. On the contrast, the sensitivity factor of solution standard by a conventional ICP-MS slowly increases with the increase of elemental mass number even though there are some exceptions such as gold and also the sensitivity factor by a laser ablation ICP MS generally increases with mass number of element in the specimen of glass type. In case of steel matrix, any definite trends could not be shown in the relationship between the GD-MS’s sensitivity factor and elemental mass.

금강 하구 퇴적토의 이화학적 성질과 종속영양세균의 분포에 관하여 (Distribution of heterotrophic bacteria and physico-chemical characteristics of sediments in Kum river estuary)

  • 이건형;아영칠;홍순우
    • 미생물학회지
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    • 제24권3호
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    • pp.308-316
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    • 1986
  • Vertical distribution of heterotrophic bacteria and physico-chemical characteristics were measuted in Kum River estuarine sediments. And interrelationship between heterotrophic bacterka and environmental factors was also studied. The type of sediment of Site 1 was silty clay, and sand at Site 2. Annual pH ranges were between 7.1 and 7.7 in the clay type sediment (Site 1) and 6.9-7.2 in the sand type sediment (Site 2). It was shown that organic matter contents were higher in the clay type sediment than those of sand type sediment. Redox potential values of sediments were decreased rapidly with depth at Site 1, but those of Sete 2 showed vertical fluctuation. Nitrogens(ammonia+amino acid-N, nitrate-N, nitrite-N) and phosphate in the clay type sediment showed higher values than those of sand type sediment. Annual distribution of heterotrophic bacteria were ranged $6.71{\times}10^4$ cells/g dry wt. $-2.50{\times}10^6$ cells/g dry wt. In the clay type sediment and $2.67{\times}10^3$ cells/g dry wt. $-1.94{\times}10^6$ cells/g dry wt. in the sand type sediment. Distribution of proteolytic, lipolytic, and amylolytic bacteria were decreased with the depth and the highest density was found in April and the lowest in January. Bacterial populations in sediments were closely correlated with such environmental factors as pH, redox potential, moisture content, organic matter contents, and inorganic nutrients such as nitrite-N and phosphate-P.

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Optimization for Scenedesmus obliquus Cultivation: the Effects of Temperature, Light Intensity and pH on Growth and Biochemical Composition

  • Zhang, Yonggang;Ren, Li;Chu, Huaqiang;Zhou, Xuefei;Yao, Tianming;Zhang, Yalei
    • 한국미생물·생명공학회지
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    • 제47권4호
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    • pp.614-620
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    • 2019
  • Microalgae have been explored as potential host species for biofuel production. Environmental factors affect algal growth and cellular composition. The effects of several key environmental factors, such as temperature, light, and pH of the medium on the growth and biochemical composition of Scenedesmus obliquus were investigated in this study. The highest growth rate of microalgae was observed at an optimal temperature of 25℃, 150 μmol/(m2·s) light intensity, and pH 10.0. The biochemical composition analysis revealed that the carbohydrate content decreased at lower (20℃) or higher temperature (35℃), whereas the protein and lipid contents increase at these temperatures. The fluctuation of light intensity significantly affected the contents of protein, carbohydrate, and lipid. The protein levels varied greatly when the pH of the medium was below 7.0. The carbohydrate and lipid contents significantly increased at pH above 7.0.