• Bulletin of the Korean Chemical Society
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• 제24권9호
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• pp.1333-1338
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• 2003

Hollow Fiber flow field-flow fractionation (HF-FlFFF) has been tested in polyacrylonitrile (PAN) membrane channel in order to compare it with polysulfone (PSf) membrane channel. It has been experimentally shown that the separation time of 0.05-0.304 ${mu}m$ polystyrene latex (PSL) standards in PAN membrane channel is shorter than that in PSf channel by approximately 65%. The optimized separation condition in PAN membrane is ${\dot V}_{out}/{\dot V}_{rad}=1.4/0.12\;mL/min$, which is equal to the condition in PSf membrane channel. In addition both the resolution ($R_s$) and plate height (H) in PAN membrane channel are better than that in PSf membrane channel. The membrane radius was obtained by back calculation with retention time. It shows that the PSf membrane is expanded by swelling and pressure, but the PAN membrane doesn't expand by swelling and pressure.

• Bulletin of the Korean Chemical Society
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• 제24권2호
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• pp.189-192
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• 2003

The reaction of 4-(2-methylaziridin-1-yl)-3-ureidobenzotrifluorides 4 with triphenylphosphine, carbon tetrachloride, and triethylamine (Appel's condition) led to the corresponding carbodiimides 5, which underwent intramolecular cycloaddition reaction with aziridine under the reaction condition to give the benzimidazolefused heterocycles, 2,3-dihydro-1H-imidazo[1,2-a]benzimidazoles 8 and 12,13-dihydro-5H-benzimidazo[2,3-b] [1,3]benzodiazepines 9.

• Bulletin of the Korean Chemical Society
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• 제10권1호
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• pp.112-112
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• 1989

• 대한기계학회논문집B
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• 제29권5호
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• pp.617-624
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• 2005

An analysis of the effects of $CO_{2}$ on fundamental combustion characteristics was performed in Oxygen enriched condition by comparing the laminar burning velocities, flame structures, fuel oxidation paths. Fictitious $CO_{2}$ was introduced to discriminate the chemical reaction effects of $CO_{2}$ from the thermal effects. PREMIX code was utilized to evaluate the laminar burning velocities. OPPDIF code was utilized to investigate the flame structure and fuel oxidation path variation. The contributions of thermal effects on laminar burning velocities are dominant at lowly oxygen-enriched condition but those of chemical reaction effects become dominant at highly oxygen-enriched condition. Chemical reaction effects caused the additional flame temperature decrease besides thermal effects and oxygen-leakage increase in non-premixed flame. Specific fuel oxidation path and CO production path is enhanced in spite of overall decrement of fuel consumption rate by chemical reaction effects of$CO_{2}$.

• Bulletin of the Korean Chemical Society
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• 제28권3호
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• pp.408-412
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• 2007

Combining the analytical transfer matrix method with supersymmetry algebra, a new quantization condition is suggested. To demonstrate the efficiency of the new quantization condition, the eigenenergies of the Coulomb potential are analytically derived. The scattering-led phase shifts are also determined and they are the same for all Coulomb potential states. It is found that the new quantization condition is mathematically simple and exact.

• Bulletin of the Korean Chemical Society
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• 제7권4호
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• pp.271-275
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• 1986

The Smoluchowski equation with a step potential is solved in one-dimensional case and three-dimensional case with spherical symmetry. Exact analytic expressions for the solution and the remaining probability are obtained in one-dimensional case for the reflecting boundary condition and the long time behavior of the remaining probability is compared with the earlier work. In three-dimensional case, only the long time behavior is evaluated. More general case with the radiation boundary condition is also investigated and the results are shown to approach correct limits of the reflecting boundary condition.

• Bulletin of the Korean Chemical Society
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• 제17권4호
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• pp.347-348
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• 1996

A set of substituent constants, σc+, has been widely used comparing the stability of carbocation in super acid condition. Plotting of 13C chemical shifts of cationic carbon (Δδc+) against σc+ constants yields an excellent correlation with a good correlation coefficient (r=0.999) for a cyclopentyl cation system. But these σc+ constants show poor linearity in norbornenyl cations that well known to show homoallylic stabilization in a cationic condition. We calculated the new substituent constant, σc+π, and found that the new substituent constants give an excellent correlation in π- and πσ-participating cation systems.

• Journal of Microbiology and Biotechnology
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• 제19권12호
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• pp.1596-1602
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• 2009

A lipase-catalyzed esterification reaction of (S)-naproxen ethyl ester by CALB (Candida antarctica lipase B) enzyme was performed in supercritical carbon dioxide. Experiments were performed in a high-pressure cell for 10 h at a stirring rate of 150 rpm over a temperature range of 313.15 to 333.15 K and a pressure range of 50 to 175 bar. The productivity of (S)-naproxen ethyl ester was compared with the result in ambient condition. The total reaction time and conversion yields of the catalyzed reaction in supercritical carbon dioxide were compared with those at ambient temperature and pressure. The experimental results show that the conversion and reaction rate were significantly improved at critical condition. The maximum conversion yield was 9.9% (216 h) at ambient condition and 68.9% (3 h) in supercritical state. The effects of varying amounts of enzyme and water were also examined and the optimum condition was found (7 g of enzyme and 2% water content).

• 한국안전학회지
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• 제31권4호
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• pp.27-34
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• 2016

Process Safety Management (PSM) system was introduced since 1996 and it makes voluntarily organizing and managing chemical accident prevention system by company itself that contributes to reduce the chemical accidents. However, large or small scaled chemical accidents had occurred frequently in these days. This trend is brought up the necessity to analyze and improve PSM system. In this study, it was conducted by the questionnaire survey and workshop for prevention of major industrial accidents in PSM sites in order to collect extensive opinions from all walks of life and identify overall operation condition. It was proposed to establish improvement plan of implementing condition assessment in PSM system. By results of the study, company's voluntary safety management will be induced by improved PSM system and management plan and it expects to prevent the major industrial accidents.

• Bulletin of the Korean Chemical Society
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• 제32권11호
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• pp.3963-3966
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• 2011

A series of pyranopyrazoles, was efficiently synthesized via one-pot, four component reaction of ethyl acetoacetate, hydrazine hydrate, aldehydes and malononitrile in the presence of catalytic amount silicotungstic acid under solvent free condition. NOE experiments confirmed that the product exist exclusively in the 2H form. The present protocol offers the advantages of clean reaction, short reaction time, high yield, easy purification and economic availability of the catalyst.