• Title/Summary/Keyword: Chemical compositions

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Comparison of Halloysitum Rubrum before and after Physical and Chemical Manipulation (적석지(赤石脂)의 포제전후의 성분 비교연구)

  • Kook, Yoon-Bum
    • The Korea Journal of Herbology
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    • v.20 no.2
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    • pp.17-26
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    • 2005
  • Objectives : The study has been undertaken to scrutinize the results of Halloysitum Rubrum before and after physical and chemical manipulation. Methods : I used X-rays diffracted analysis system(Phillips X'Pert - MPD System) on condition of 40Kv, Anode of Cu Ka to grasp the compositions of crude Halloysitum Rubrums which have been from here and there after pulverization them below 200 mesh. X-rays fluorescence analysis system have been used to check the chief elements content of the ore on condition of 40Kv, 95mA. ICP-MS analysis system(Perkin Elmer, Elan 6100)have been used after a micro-elements and a heavy metals take advantage of mixed acid were dissolved completely. Results : The compositions of the ore Halloysitum Rubrum are composed of large amount of Halloysite and Kaolinite, and small amount of Hematite, Alum, quartzite. The chief elements content of the ore Halloysitum Rubrum are composed of Al and Si. A heavy metals in Halloysitum Rubrum are As, Cd, Cr, Cu, Pb, Zn, etc. As and Zn's amounts was lessen after physical and chemical manipulation Halloysitum Rubrum are decreased at $400^{\circ}C\;and\;450-500^{\circ}C$ each by heat analysis system. Conclusion : Results of this study show that Halloysitum Rubrum can be used in a diverse ways to treat many kinds of disease.

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Chemical Compositions in Rainwater at Hiroshima Prefecture, Japan

  • Kim, Do-Hoon;Takeda, Kazuhiko;Sakugawa, Hiroshi;Lee, Jin-Sik
    • Analytical Science and Technology
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    • v.15 no.4
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    • pp.321-328
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    • 2002
  • From May 1999 to July 2000, concentration of 17 metals (Al, Ba, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, Pb, Sr, V, Zn), 4 ions (${NH_4}^+$, $Cl^-$, ${NO_3}^-$, ${SO_4}^{2-}$) and pH in rainwater were investigated. The volume-weighted mean concentrations (VWM) of ${NO_3}^-$ and ${SO_4}^{2-}$ were 16.0 and $17.0{\mu}mol\;L^{-1}$. The average pH was 4.53, which ranged from 3.83 to 6.06. The characteristic variations of these species were investigated in terms of the source of these species by principal component analysis (PCA) and interelement correlation coefficients. The elements were classified into three categories: anthropogenic source (Cd, Cu, Fe, Ni, Pb, V, Zn, ${NH_4}^+$, ${NO_3}^-$, ${SO_4}^{2-}$ and $H^+$), soil and crust dust (Al, Ba, Ca, Fe, Mn) and sea salts (Mg, Na, $Cl^-$). In addition, we compared the concentrations in rainwater, which were taken on the same day in three sites (Higashi-Hiroshima, an urban-facing area and a mountain-facing area of Mt. Gokurakuji) in order to examine the regional effect against the concentrations in them. At the urban-facing area of Mt. Gokurakuji, the concentrations of chemical compositions were higher than other areas.

Single Particle Characterization of Aerosol Particles Collected at Jeju Island, Korea, During 'ACE-Asia' Intensive Observation Period, Using Low-Z Particle Electron Probe X-ray Microanalysis (Low-Z Particle Electron Probe X-ray Microanalysis법을 이용한 2001년 ACE-Asia 집중 측정 기간 중 제주도 고산에서의 입자상 물질의 특성분석)

  • An Yong Hoon;Kim HyeKyeong;Ro Chul-Un
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.811-821
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    • 2004
  • Low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA) was applied to characterize aerosol particles collected at Gosan in Jeju island during an IOP (intensive observation period) for an international ACE-Asia project in April, 2001. Various types of atmospheric particles such as organics, carbon-rich, aluminosilicates, silicon oxide, sodium nitrate, sodium chloride, and ammonium sulfate were observed. The reacted sea salt particles such as sodium nitrate were the most abundantly encountered, but original sea salt particles were rarely observed. Since the Low-Z particle EPMA can provide quantitative information on the chemical composition of aerosol particles, many different particle types on the basis of their chemical compositions were observed and identified. In this study, it is demonstrated that the Low-Z particle EPMA can provide detailed information on the chemical compositions for the aerosol particles collected for six consecutive days in April, 2001, at Gosan super-site.

Effect of Anodic Gas Compositions on the Overpotential in a Molten Carbonate Fuel Cell

  • Lee C.G.;Kim D.H.;Hong S.W.;Park S.H.;Lim H.C.
    • Journal of the Korean Electrochemical Society
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    • v.9 no.2
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    • pp.77-83
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    • 2006
  • Anodic overpotential has been investigated with gas composition changes in a $100cm^2$ class molten carbonate fuel cell. The overpotential was measured with steady state polarization, reactant gas addition (RA), inert gas step addition (ISA), and electrochemical impedance spectroscopy (EIS) methods at different anodic inlet gas compositions, i.e., $H_2:CO_2:H_2O=0.69:0.17:0.14\;atm\;and\;H_2:CO_2:H_2O=0.33:0.33:0.33\;atm$, at a fixed $H_2$ flow rate. The results demonstrate that the anodic overpotential decreases with increasing $CO_2\;and\;H_2O$ flow rates, indicating the anode reaction is a gas-phase mass-transfer control process of the reactant species, $H_2,\;CO_2,\;and\;H_2O$. It was also found that the mass-transfer resistance due to the $H_2$ species slightly increases at higher $CO_2\;and\;H_2O$ flow rates. EIS showed reduction of the lower frequency semi-circle with increasing $H_2O\;and\;CO_2$ flow rate without affecting the high frequency semi-circle.

Determination of Chemical Compositions and Oxidation States for Corrosion Products in LiCl Molten Salts

  • Park, Yong-Joon;Pyo, Hyung-Ryul;Kim, Do-Yang;Jee, Kwang-Yong;Kim, Won-Ho
    • Nuclear Engineering and Technology
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    • v.32 no.5
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    • pp.514-520
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    • 2000
  • The mechanism of corrosion behavior has to be understood clearly to select an optimum material for handling molten salts to be used in the oxide reduction process of PWR spent fuel. In this study, the oxidation states of corrosion products on the surface of Inconel 600 and 800H as well as their chemical compositions and structural informations were determined by using XPS, ICP-AES, AAS, EPMA and XRD after the corrosion experiment with lithium molten salts at 75$0^{\circ}C$ for 25 hours. Nickel and oxygen were detected from the corrosion products on the surface of Inconel plates and chromium was found to be dissolved out into lithium molten salts leaving cracks on the surface. The corrosion products were identified as metal oxides such as Fe$_2$O$_3$, Cr$_2$O$_3$, NiO, NiFe$_2$O$_4$and MnO by using XPS and XRD.

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Characteristics and Effects of Radiation Treatment on Wood Pulping Process (목재 펄프 제조 공정에서의 방사선 효과 및 특성)

  • Won, So Ra;Shin, Hye Kyoung;Jeun, Joon Pyo;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.5 no.3
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    • pp.227-230
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    • 2011
  • Pulps were separated from wood chips using an Electron beam irradiation (EBI) treatment without a NaOH-AQ (anthraquinone) treatment for cooking. The methods were based on a hot water treatment after EBI and two-step bleaching processes. Chemical compositions and FT-IR spectroscopy demonstrated that the content of lignin and hemicellulose in the bleached wood pulps treated with various EBI dose decreased with an increase of EBI doses. Specifically, the lignin in the bleached with pulps treated at 600 kGy of EBI dose was almost completely removed. Moreover, TGA analysis showed that a thermal stability increased with increasing the content of cellulose but the lignin decomposed slowly over the wide region.

Characteristics of Chemical Compositions and Weathering of Glass Beads excavated from Andong Tumulus in Gildu-ri, Goheung (고흥 길두리 안동고분 출토 유리구슬의 화학조성 및 풍화특성)

  • Han, Min-Su;Lee, Han-Hyoung;Moon, Eun-Jung
    • Journal of Conservation Science
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    • v.27 no.3
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    • pp.323-332
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    • 2011
  • Microtexture and components of 7 glass bead fragments excavated from Andong tumulus in Gildu-ri, Goheung have been analyzed to determine the characteristics of their weathered condition as well as chemical compositions. Firstly, status of microtexture shows that there is a large quantity of pollutants which were presumably transferred from the buried environment into the surface and the gap of the cracks. The examination has displayed that there are less amount of alkali metal components such as sodium (Na) and potasium (K) in the gap of the cracks than on the surface. The chemical compositions analysis has confirmed that two samples belongs to potash glass group ($K_2O-SiO_2$), four to soda glass group ($Na_2O-SiO_2$), and one to the mixed alkali glass group. Chromophoric elements of the glass varies by different colours: blue and navy are cobalt (Co); greenish blue is copper (Cu) and iron (Fe); and light brown is Fe respectively. Such kind of scientific analysis of the excavated glass beads will contribute to the understanding of interchange between various local cultures and arts within the southwest region of Korean Peninsula during the 4th and the 5th centuries.

Studies on the Compositions of Mineral Components, Total Amino Acid, Free Amino Acid and Fatty Acid of Zizyphus jujuba Seed (대추씨(Zizyphus jujuba Seed)의 무기질, 구성 총 아미노산, 유리 아미노산 및 지질 구성 지방산조성에 관한 연구)

  • Kim, Han-Soo
    • Korean Journal of Human Ecology
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    • v.8 no.1
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    • pp.25-31
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    • 2005
  • Chemical components of the physiological activity substance in Zizyphus jujuba seed were analyzed for the use as an functional processed products. The proximate compositions of Zizyphus jujuba seed were carbohydrate 89.40%, moisture 8.23%, crude protein 1.22%, crude fat 0.65% and crude ash 0.50%, respectively. the richest mineral contained in Zizyphus jujuba seed was Mg(198.3mg/100g), followed by Mn(113.0mg/100g), K(100.2mg/100g), Ca(25.3mg/100g), P(25.6mg/100g_, Fe(23.5mg/100g), Zn(18.7mg/100g), Cu(7.4mg/100g) and Na(5.3mg/100g). Total amino acid contents of Zizyphys jujuba seed were 1103.12mg/100g, and the major amino acids were proline(235.17mg%), aspartic acid(175.941mg%), gltamic acid(101.46mg%), leucine(50.27mg%), serine(47.71mg%), aspartic acid(47.27mg%), glycine(41.60mg%) and lysine (33.78mg%), respectively. The amount of free amino acids in the protein of Zizyphus jujuba seed were 178.62 mg/100g, and the major free amino acids were proline(121.30mg%), alanine(6.01mg%), valine(2.63mg%) and arginine(2.04mg%), respectively. The compositions of major total fatty acid in the lipid Zizyphus jujuba seed were C18:2(n5c) 28.72%, C18:1(n9t) 23.76%, C18:1(n9c) 13.45%, C16:0 13.45% and C20:5(n3) 1.77% in order, respectively.

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Studies on the Chemical Compositions and Distributions of Ambient Sumicron Aerosols (Submicron 부유분진의 화학적 조성 및 분포에 관한 연구)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.1
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    • pp.11-23
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    • 1998
  • The purpose of this study was to survey chemical distribution of inorganic elements and ions in the submicron particles, to characterize qualitatively emitting sources by factor analysis, and finally to reveal existing patterns in terms of chemical compounds by a stepwise multiple regression analysis. Total of 141 samples were collected by a cascade impactor from 1989 to1996. Fifteen chemical species (Al, Ba, Cd, K, Pb, Cu, Fe, Ni, $Cl^-, NO_3^-, SO_4^{2-}, K^+, Mg^{2+}, Ca^{2+}, and Na^+$) were characterized by AAS and IC. The study showed that average seasonal levels of submicron particulate matters $(d_p<0.43 \mum)$ were 18.7 $\mug/m^3$ in spring, 15.5 $\mug/m^3$ in summer, 15.7 $\mug/m^3$ in fall, and 24.5 $\mug/m^3$ in winter, respectively. All of the anion concentrations in the particle were highest in the winter season. By applying a factor analysis, 5 source patterns were qualitatively obtained, such as sulfate related source, nitrate related source, oil burning source, calcium related source, and coal combustion source. Finally, when applying a stepwise multiple regression analysis, the results clearly showed that $Na^+ and Ca^{2+}, K^+ and Ca^{2+}, NO_3^-$ and relative humidity, $Cl^-$ and ambient temperature, $Ca^{2+} and Cl^-, Mg^{2+} and SO_4^{2-}, Na^+ and NO_3^-, and Ca^{2+} and NO_3^-$, respectively, are negatively contributed to each other. As a result of those statistical analysis, we could suggest that some chemical compounds in the submicron particles such as$NaNO_3, MgSO_4, Ca(NO_3)_2, and CaCl_2$ may not exist on the filter as final composing products; however, other compounds may possibly exist in the form of $Mg(NO_3)_2, CaSO_4, Na_2SO_4, K_2SO_4, MgCl_2, NaCl, and KCl$. Thus, it must be necessary to identify differences between the results of above statistical analysis and of the real world by laboratory experiments.

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Similarity Analysis of Chemical Profiles of Scrophularia buergeriana Based on HPLC-DAD

  • Kim, Dae-Hyun;Park, Jin-Ho;Kim, Young-Choong;Sung, Sang-Hyun;Kim, Seung-Hyun
    • Natural Product Sciences
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    • v.17 no.3
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    • pp.225-229
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    • 2011
  • A new approach for similarity analysis of chemical profiles of Scrophularia buergeriana was developed. The roots of S. buergeriana collected in Andong, Korea were analyzed using HPLC-DAD and the peak areas of the chromatograms were used to construct the chemical profiles of S. buergeriana. The analytical conditions were validated for specificity, precision and repeatability. The standard chemical profiles were established from the chromatograms of nine standard analytical extracts from three batches. The correlation coefficients of peak areas of characteristic compounds between the chromatograms of the standard and test samples were calculated for quantitative expression of the chemical profiles. The results showed that the HPLC chemical profiles of the samples of same geographic origin were relatively consistent. This new approach could be applied to the quality assessment of herbal medicines with complex chemical compositions.