• Title/Summary/Keyword: Chemical component analysis

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Analysis of Damaged Instance and Forming Fault for Disc Part in Automotive Steel Wheel (자동차용 스틸휠 디스크부품의 성형불량 및 파손사례분석)

  • Lee, Sung-Hee;Kim, M.Y.;Kim, T.G.;Yun, H.Y.;Kang, S.W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.234-238
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    • 2006
  • In this research, an analysis of damaged instance and forming fault for disc part in automotive steel wheel was performed. Rolled steel material, which had been used in the manufacturing of the damaged disc part, was prepared for tensile test, quantitative analysis of chemical component and acquirement of scanning electron microscope images. Although the results of mechanical properties and chemical component ratio for the material satisfied the suggested specification, some material inherent problem was found in the scanning electron microscope images. Finally, in an analysis of chemical component for the damaged disc part used in road condition, mismatching of chemical component ratio between the suggested specification and test result was found.

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Preparation of multi-component ceramic proton conductors for intermediate temperature fuel cell (중온형 연료전지를 위한 다성분계 세라믹 수소이온 전도체 제조)

  • Lim, Byeong-mu;Seo, Dong-ho;Park, Sang-sun;Lee, Hong-yeon;Shul, Yong-Gun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.410-411
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    • 2009
  • The multi-component ceramic proton conductor, $BaZr(Y)O_3-SiO_2-TiO_2-ZrO_2$ (BZY-STZ) and $LaPO_4-SiO_2-TiO_2-ZrO_2$ (LP-STZ), were synthesized by micro-emersion and sol-gel technique. The characterization of proton conductors were carried out using X-ray diffraction(XRD), thermogravimetric analysis(TGA), differential thermal analysis(DTA), impedance analysis. The proton conductors indicate the possibility of application for the intermediate temperature up to $700^{\circ}C$.

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Moving Window Principal Component Analysis for Detecting Positional Fluctuation of Spectral Changes

  • Ryu, Soo-Ryeon;Noda, Isao;Jung, Young-Mee
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2332-2338
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    • 2011
  • In this study, we proposed a new promising idea of utilizing moving window principal component analysis (MWPCA) as a sensitive diagnostic tool to detect the presence of peak position shift. In this approach, the moving window is constructed from a small data segment along the wavenumber axis. For each window bound by a narrow wavenumber region, separate PCA analysis was applied. Simulated spectra with complex spectral feature variations were analyzed to explore the possibility of MWPCA technique. This MWPCA-based detection of the peak shift, potentially coupled with 2D correlation analysis to provide additional verification, may offer an attractive solution.

Development of Component Reliability Database for Korean Nuclear Power Plants and Chemical Plants (국내 원자력 발전소 및 화학공장의 기기 신뢰도 데이터베이스 구축)

  • 최선영;한상훈
    • Proceedings of the Korean Reliability Society Conference
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    • 2000.11a
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    • pp.269-277
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    • 2000
  • The component reliability database is required in PSA (Probabilistic Safety Analysis) for NPP (Nuclear Power Plant). We have applied a generic database to the PSA for the Korean NPPs, since there is no specific component reliability database. Therefore we are developing the plant-specific component reliability database for domestic NPPs. We also extend the experience and knowledge of PSA and component reliability database for NPP to chemical industry We collect the raw data like component operation history and maintenance history and then input the required data for the component reliability database through failure analysis. With the database, we can not only perform PSA with real data but also perform maintenance optimization.

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Principal Component Analysis Based Two-Dimensional (PCA-2D) Correlation Spectroscopy: PCA Denoising for 2D Correlation Spectroscopy

  • Jung, Young-Mee
    • Bulletin of the Korean Chemical Society
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    • v.24 no.9
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    • pp.1345-1350
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    • 2003
  • Principal component analysis based two-dimensional (PCA-2D) correlation analysis is applied to FTIR spectra of polystyrene/methyl ethyl ketone/toluene solution mixture during the solvent evaporation. Substantial amount of artificial noise were added to the experimental data to demonstrate the practical noise-suppressing benefit of PCA-2D technique. 2D correlation analysis of the reconstructed data matrix from PCA loading vectors and scores successfully extracted only the most important features of synchronicity and asynchronicity without interference from noise or insignificant minor components. 2D correlation spectra constructed with only one principal component yield strictly synchronous response with no discernible a asynchronous features, while those involving at least two or more principal components generated meaningful asynchronous 2D correlation spectra. Deliberate manipulation of the rank of the reconstructed data matrix, by choosing the appropriate number and type of PCs, yields potentially more refined 2D correlation spectra.

Operation Modes Classification of Chemical Processes for History Data-Based Fault Diagnosis Methods (데이터 기반 이상진단법을 위한 화학공정의 조업모드 판별)

  • Lee, Chang Jun;Ko, Jae Wook;Lee, Gibaek
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.383-388
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    • 2008
  • The safe and efficient operation of the chemical processes has become one of the primary concerns of chemical companies, and a variety of fault diagnosis methods have been developed to diagnose faults when abnormal situations arise. Recently, many research efforts have focused on fault diagnosis methods based on quantitative history data-based methods such as statistical models. However, when the history data-based models trained with the data obtained on an operation mode are applied to another operating condition, the models can make continuous wrong diagnosis, and have limits to be applied to real chemical processes with various operation modes. In order to classify operation modes of chemical processes, this study considers three multivariate models of Euclidean distance, FDA (Fisher's Discriminant Analysis), and PCA (principal component analysis), and integrates them with process dynamics to lead dynamic Euclidean distance, dynamic FDA, and dynamic PCA. A case study of the TE (Tennessee Eastman) process having six operation modes illustrates the conclusion that dynamic PCA model shows the best classification performance.

Construction of Methanol-Sensing Escherichia coli by the Introduction of a Paracoccus denitrificans MxaY-Based Chimeric Two-Component System

  • Ganesh, Irisappan;Vidhya, Selvamani;Eom, Gyeong Tae;Hong, Soon Ho
    • Journal of Microbiology and Biotechnology
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    • v.27 no.6
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    • pp.1106-1111
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    • 2017
  • Escherichia coli was engineered to sense methanol by employing a chimeric two-component system (TCS) strategy. A chimeric MxaY/EnvZ (MxaYZ) TCS was constructed by fusing the Paracoccus denitrificans MxaY with the E. coli EnvZ. Real-time quantitative PCR analysis and GFP-based fluorescence analysis showed maximum transcription of ompC and the fluorescence at 0.01% of methanol, respectively. These results suggested that E. coli was successfully engineered to sense methanol by the introduction of chimeric MxaYZ. By using this strategy, various chimeric TCS-based bacterial biosensors can be constructed and used for the development of biochemical-producing recombinant microorganisms.

Study on the Chemical Characteristics of $PM_{10}$ at Background Area in Korean Peninsula (한반도 서해안 배경지역 미세입자의 화학적 특성 연구)

  • Bang So-Young;Baek Kwang-Wook;Chung Jin-Do;Nam Jae-Cheol
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.455-468
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    • 2004
  • The purpose of this paper is to understand the time series and origin of a chemical component and to compare the difference during yellow sand episodes for analysis $PM_{10}$ chemical components in the region of west in Korean Peninsula, 1999-2001. An annual mean concentration of $PM_{10}$ is $29.1\;{\mu}g/m^3$. A monthly mean and standard deviation of $PM_{10}$ concentration are very high in spring but there is no remarkably seasonal variation. Also, water soluble ionic component of $PM_{10}$ be influenced by double more total anion than total cation, be included $NO_{3}^-\;and\;SO_{4}^{2-}$ for the source of acidity and $NH_{4}^+$ to neutralize. Tracer metals of $PM_{10}$ slowly increases caused by emitted for soil and ocean (Fe, Al, Ca, Mg, Na) and Zn, Pb, Cu, Mn for anthropogenic source. According to method of enrichment factor (E.F) and statistics, assuming that the origin of metal component in $PM_{10}$ most of element in the Earth's crust e.g. Mg, Ca, Fe originates soil and Cu, Zn, Cd, Pb derives from anthropogenic sources. The ionic component for $Na^{+}\;Cl^-,\;Mg^{2+}\;and\;Ca^{2+}$ and Mg, Al, Ca, Fe originated by soil component largely increase during yellow sand period and then tracer metal component as Pb, Cd, Zn decrease. According to factor analysis, the first group is ionic component ($Na^+,\;Mg^{2+},\;Ca^{2+}$) and metal component (Na, Fe, Mn and Ni) be influenced by soil. The second group, Mg, Cr also be influenced by soil particle.

Non-Invasive Plasma Monitoring Tools and Multivariate Analysis Techniques for Sensitivity Improvement

  • Jang, Haegyu;Lee, Hak-Seung;Lee, Honyoung;Chae, Heeyeop
    • Applied Science and Convergence Technology
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    • v.23 no.6
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    • pp.328-339
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    • 2014
  • In this article, plasma monitoring tools and mulivariate analysis techniques were reviewed. Optical emission spectroscopy was reviewed for a chemical composition analysis tool and RF V-I probe for a physical analysis tool for plasma monitoring. Multivariate analysis techniques are discussed to the sensitivity improvement. Principal component analysis (PCA) is one of the widely adopted multivariate analysis techniques and its application to end-point detection of plasma etching process is discussed.