• 한국의류산업학회지
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• 제10권5호
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• pp.748-755
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• 2008

The purpose of this study is to investigate the effect of chitosan treatment on the dyeing of cotton fabric using charcoal as colorants. Particle size of charcoal, dyeability(K/S), SEM morphology of dyed fabrics and color fastness were also investigated. In this study, cotton fabrics were treated with a crosslinking agent epichlorohydrin in the presence of chitosan to provide the cotton fabrics the dyeing properties of natural dye by the chemical linking of chitosan to the cellulose structure. The results obtained were as follows; Mean average diameter of charcoal was 1.44 ${\mu}m$. According to various conditions, the dyeing effects of 1% chitosan treatment on the dyeing of cotton fabrics using charcoal were the highest with 10%(owb) of charcoal at $90^{\circ}C$ for 120minutes and non-treatment of cotton fabrics were the highest with 15%(owb) of charcoal at $90^{\circ}C$ for 150minutes. Overall, K/S value of 1% chitosan treatment of cotton fabrics on the natural dyeing using charcoal was higher than non-treatment of cotton fabrics. It was observed the surfaces of cotton fabrics treated with chitosan were adsorbed with charcoal powders of particle size more than a non-treated chitosan fabric by SEM. The cotton fabrics were dyed with blackish gray color by charcoal gradually according to treating chitosan. The K/S value, that is indicative of dye affinity, became higher as the increase of treated chitosan concentration. The color fastness of charcoal, washing and light fastness was excellent as 4-5 grade.

• 한국작물학회지
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• 제4권1호
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• pp.125-129
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• 1968

수확후 시일이 오래 경과되지 않은 금잔디종자의 발아촉진에 관하여 실험한 결과를 요약하면 다음과 같다. (1) 종자를 흡수시켜서 0~$2^{\circ}C$에 2~30일 냉장하는 것은 발아조장효과가 가장 현저하였다. (2) 종자를 농유산에 넣고 유리막대로 잘 교반하며 1분 30쯤 경과한 다음 수세 파종하는것도 발아조장의 효과가 컸다. 그러나 처리가 지나쳐서 종자가 흑별할 저오닥 되면 도리어 해롭다. (3) 잔디종자의 발아는 광선이 투입될 경우에 조장되며 복토는 발아를 감퇴시킨다. (4) 혼사종피마상 및 선부절제도 약간의 발아조장효과가 있는 것 같다. (5) 지벨레린, $NH_4$ $NO_3$, NAA 등의 처리는 발아조장효과가 거의 인정되지 않았다.

• 한국세라믹학회지
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• 제20권3호
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• pp.211-216
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• 1983

This work aims at characterizing silicon grains and its compacts. In order to remove iron silicon grains were washed with 5N hydrochloride at 60-7$0^{\circ}C$ for 170 hrs, and then followed the chemical analysis by atomic absorption spectrophotometer X-ray diffraction analysis SEM observation and specific surface area determination by B. E. T. Mixtures of graded silicon particles with two or three different sizes were made into packings by mechanical vibration. The mixtures were used to make compacts with 10 mm in diameter and 70mm in length by isostatically pressing at 1, 208 kg/$cm^2$ (20 kpsi) and 4, 255kg/$cm^2$ (60 kpsi) respectively. Bulk densities of packings and compacts were measured. A slip made of magnesium nitrate solution and fine silicon particles was spray-dried and then decomposed at 30$0^{\circ}C$ for the purpose of coating the uniform layer of magnesium oxide on the surface of particles. The results obtained are as follows: (1) About two thirds of iron content could be removed from silicon by washing silicon powders with hydrochloride. (2) Uniform layer of magnesium oxide on the surface of silicon could be prepared by spray-drying suspension and by decomposing it. (3) B. E. T. specific surface area of fine silicon particles was 2, 826.753$m^3$/kg. (4) In the binary system with two sizes of 40-53$\mu\textrm{m}$ particles and <10$\mu\textrm{m}$ particles the maximum bulk density of packing was 55% of theoretical value and that of compacts made at the pressure of 4, 255 kg./$cm^2$ (60 kpsi) was 73% of theoretical value. (5) In the ternary system with three sizes the maximum bulk density of packing was 1.43 g/$cm^3$and that of compacts was 1.80g/$cm^3$which is equivalent to 77.6% of theoretical value. The composition of the closest compact was consisted of 50% of 40-53$\mu\textrm{m}$ particles 20% of 10-30$\mu\textrm{m}$ particles and 30% of <10$\mu\textrm{m}$ parti-cles.

• Macromolecular Research
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• 제17권9호
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• pp.688-696
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• 2009

In this study, a new class of polyurethane (PU) nanofibers containing silver (Ag) nanoparticles (NPs) was synthesized by electrospinning. A simple method that did not depending on additional foreign chemicals was used to self synthesize the silver NPs in/on PU nanofibers. The synthesis of silver NPs was carried out by exploiting the reduction ability of N,N-dimethylformamide (DMF), which is used mainly to decompose silver nitrate to silver NPs. Typically, a sol-gel consisting of $AgNO_3$/PU was electrospun and aged for one week. Silver NPs were created in/on PU nanofibers. SEM confirmed the well oriented nanofibers and good dispersion of pure silver NPs. TEM indicated that the Ag NPs were 5 to 20 nm in diameter. XRD demonstrated the good crystalline features of silver metal. The mechanical properties of the nanofiber mats showed improvement with increasing silver NPs content. The fixedness of the silver NPs obtained on PU nanofibers was examined by harsh successive washing of the as-prepared mats using a large amount of water. The results confirmed the good stability of the synthesized nanofiber mats. Two model organisms, E. coli and S. typhimurium, were used to check the antimicrobial influence of these nanofiber mats. Subsequently, antimicrobial tests indicated that the prepared nanofibers have a high bactericidal effect. Accordingly, these results highlight the potential use of these nanofiber mats as antimicrobial agents.

• 약학회지
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• 제40권1호
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• pp.25-35
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• 1996

Magaldrate. an antiacid was synthesized by reacting magnesium oxide, aluminum sulfate, and dried aluminum hydroxide gel. The optimum synthesis conditions based on the yield of t he product were established by applying Box-Wilson experimental design. It was found that the optimum synthesis conditions of Magaldrate were as follows: Reaction temperature; 61~$85{\circ}C$, concentration of two reactants. Mgo and $Al(OH)_3$: 16~19.8%, molar concentration ratio of two reactants, [MgO]/[$Al(OH)_3$]; 4.2~5.0, temperature of washing water; 36~$41^{\circ}C$ and drying temperature of the product: 76~$80^{\circ}C$. Magaldrate was synthesized under the optimum synthesis conditions and identified by analyzing the chemical composition, and by differential scanning calorimetry and X-ray diffraction method. The Magaldrate sample synthesis under these conditions was used to prepare 15.6% Magaldrate original suspension which was utilized to make 13% Magaldrate suspension dispered in various concentrations of eight types of suspending agents. The acid-neutralizing capacity of 13% Magaldrate suspension dispersed in 0.25% suspending agents was examined by Rosset-Rice method. The maximum pH was reached within 1 minute in all suspension tested, and duration maintained between pH 3~5 was decreased in the order of Na alginate Na silicate(meta) Veegum HV pectin agar>Na>CMC>xanthan gum>bentonite. It was found that the hysteresis loop area was increased with temperature in the case of Riopan Plus and the addition of agar, whereas the area was decreased with temperature in the case of the addition of Na alginate and xanthan gum. 13% Magaldrate suspension tends to sediment by the addition of bentonite.

• 자원리싸이클링
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• 제16권6호
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• pp.39-45
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• 2007

황동 전구 base 제조과정에서 발생하는 황산폐수에 함유된 구리와 아연의 농도를 저감시키기 위해 중화법에 의한 최적조건을 조사하였다. 구리와 아연이 함유된 황산용액에 대해 화학반응과 물질수지를 고려하여 용액의 pH에 따른 구리와 아연의 농도분포와 용해도를 구하였다. 구리와 아연의 수산화물이 침전되는 pH영역에서 아연의 용해도가 구리의 용해도보다 크므로, 구리에 비해 아연의 제거율이 용액의 pH에 민감하였다. 응집제로 $Al_2(SO_4)_3$를 첨가하는 경우 아연의 제거율은 응집제의 첨가형태에 영향을 받지 않았으나, 구리의 경우에는 용액으로 첨가하는 것이 고체상태로 첨가하는 것보다 제거율이 높았다.

• 한국의상디자인학회지
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• 제16권4호
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• pp.229-235
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• 2014

This study conducted a research on burn-out printing convergence technology for cellulose blend knit fabrics. Printing technology, which forms color pattern on the fabric, can be generally classified into four according to printer or printing method, e.g. screen printing, roller printing, rotary printing, digital printing. However, these printing methods are flat in design or pattern, which have limitation to overcome monotonousness of fabric, so that recently burn-out process method, which expresses three-dimensional pattern effect by treating chemical on the surface of fabric as the method to appeal its esthetics to the customers. Particularly, in case of cellulose/polyester composite material, first, it is proceeded in 2 processes, by dyeing cellulose or polyester fabric and burning out cellulose fabric, in this process, due to pollution caused by disperse dye migration, color of polyester fabric part could be discolored, which has high falt risk. This research considered coloring burn-out technique, which simultaneously proceed dyeing and burn-out by reducing dyeing and burn-out process to 1 stage, which were proceeded in 2 stages previously. As the research result, it was confirmed that reasonable depth of roller was 0.04~0.06mm in roller printing process, heat treatment condition of burn-out far-infrared radiation was $185^{\circ}C{\times}30m/min$. Color fastness to washing was confirmed to be 4-5 grade, color fastness to rubbing, 3-4 grade, color fastness to light, 4 grade. Also, it was confirmed that energy reduction effect appeared 38.19%, in case of energy cost per yard compared to the existing production, also, 19.74%, in case of production cost.

• 헤리티지:역사와 과학
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• 제46권1호
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• pp.228-237
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• 2013

지류문화재는 유기질이라는 재질의 특성상 시간이 지나면서 여러 가지 복합적인 손상인자(물리적 화학적 생물학적 인위적 원인)에 의해 유물의 보존성에 영향을 받고 있다. 그리하여 그 손상 정도에 따라 적절한 보존처리를 실시하게 되는데 그중 유물의 오염원을 제거하는 습식클리닝 처리가 지류문화재를 구성하는 주 원료인 한지의 재질에 미치는 영향을 분석해 보고자 본 연구를 실시하였다. 분석방법은 공시재료로 인공열화지를 사용하였고 습식클리닝(침적식)을 적용하여 처리 전 후의 색차와, 내절강도를 분석하였다. 분석결과 습식클리닝(침적식)에 의한 색도의 변화와 내절강도는 30분 침적을 2회 반복 처리하였을 때 가장 높은 수치를 나타냈다. 따라서 이때가 클리닝의 효율과 재질의 안정성이 가장 양호함을 알 수 있었다.

• 청정기술
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• 제16권4호
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• pp.265-271
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• 2010

경유차 매연저감장치에서 비활성화된 디젤산화촉매(DOC)를 대상으로 여러 가지 조건에서 재제조한 후, 재제조된 DOC의 일산화탄소(CO)와 탄화수소화합물(THC)의 저감효율과 촉매물성 특성을 분석하여 비활성화된 DOC 촉매에 대한 재제조 효과를 관찰하였다. 재제조된 DOC촉매에 대한 오염물질 저감성능 평가는 디젤엔진 다이나모 장치를 이용, 배기가스를 일부 우회시켜 온도와 공간속도조절이 가능한 촉매반응장치로 수행하였으며, 촉매물성 분석은 광학현미경, EDX, ICP, TGA 그리고 porosimeter를 이용하였다. 연구수행 결과 비활성화된 DOC 촉매를 본 연구에서 적용된 고온배소세정, 산성/염기성용액에 의한 초음파세정, 세정 후 촉매활성성분 재함침에 의한 재제조를 수행할 경우, 재제조된 DOC 촉매의 성능이 신품 성능의 90% 이상으로 회복되는 것을 확인하였으며, 광학현미경, EDX, TGA와 ICP등의 분석을 통해 본 연구조건에서의 재제조 과정으로, 촉매의 활성 저하 원인이 되었던 각종 불순 성분 대부분이 비활성화된 DOC 촉매로부터 제거되는 것을 확인하였다.

• 한국의류산업학회지
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• 제25권3호
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• pp.398-408
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• 2023

Smart clothing products can experience a decrease in performance and reliability due to various mechanical, biological, and chemical stress factors that occur throughout their life cycle. These issues can hinder consumer acceptance of the products. This study aims to enhance the reliability of smart clothing and facilitate quality control by analyzing and identifying the current status of international standardization for smart clothing and electronic textiles (e-textiles). The focus of this analysis was on the durability test methods in the use environment. Furthermore, similar standards published by different standardization organizations for durability tests were compared in depth. The study showed that a total of 27 international standards have been developed or are currently under development. The current standardization efforts mainly aim to develop functionality and durability test methods for smart clothing and e-textile products. A detailed comparison was made between two international standards (IEC 63023-204-1:2023 and AATCC TM210:2019) specifically in relation to the washing durability test method and the electrical resistance measurement standards (BS EN 16812:2016 vs AATCC EP13-2021), before and after the environmental exposure tests. Based on this comparison, several suggestions have been made and discussed for the future revision of these international standards.