• Title/Summary/Keyword: Chemical Union

Search Result 80, Processing Time 0.033 seconds

A Union Model of Human and Agent for Processing the Information of the Complex System (복잡계 정보 처리를 위한 사람과 에이전트의 결합 모델)

  • 고성범;김동근
    • Journal of KIISE:Software and Applications
    • /
    • v.30 no.7_8
    • /
    • pp.752-763
    • /
    • 2003
  • In the large scale B2B transaction like buying ´Express-Train´ or selling ´Daewoo Motor`, a tremendous amount of variables and factors of chaos functionate in it directly or indirectly. To get the effective information processing on the so called complex system like this, it should be possible to unite the human´s ability on the implicit information processing and the agent´s ability on the explicit information processing. In this paper, we suggested a union model for uniting these two heterogeneous abilities and showed how the suggested model can be used for processing the information of such a complex system as B2B negotiation.

Estimation of the Liability Risk for Release of Chemicals at Chemical Plant (화학플랜트에서의 화학물질 누출사고에 대한 배상책임 위험도 산정)

  • Moon, Jung Man;Park, Dal Jae
    • Korean Chemical Engineering Research
    • /
    • v.58 no.3
    • /
    • pp.438-449
    • /
    • 2020
  • This study is to improve the method of calculating the risk of liability that arise from release and dispersion of chemicals outside the plant in process industries such as chemical and petrochemical plants. To achieve this goal, the correlation factors with the risk of chemical release accident is derived by simulating release and dispersion of substances (14 types) designated by Ministry of Environment as preparation for accident, analyzing the cases of chemical release and effects of plant life damage. The method of calculating chemical liability risk was modified and supplemented based on the results obtained from the study. The correlation coefficient between the probit value of 14 chemical types and the liability risk by EURAM (European Union Risk Ranking Method) was -0.526, while the correlation coefficient with the modified chemical release accident risk was 0.319. Thus, the value from modified method shows that they appear to be correlated. According to modified calculating methodology, the correlation between ERPG-2 value and liability risk of 97 chemical types was -0.494 which is 19 times higher than existing liability risk correlation as absolute value. And the correlation coefficient of corrosion risk was 0.91. The standardized regression coefficients (β) value of correlation factors that affected the increase and decrease of risk were derived in order of Corrosion Index(0.713), ERPG-2 (0.400) and NFPA Health Index (0.0680) by values. It is expected that these findings this study result will also enable the calculation of reasonable chemical release liability risk for existing and new chemical, and will help use them as quantitative liability risk management indicators for chemical plant site.

Classified Chemicals in Accordance with the Globally Harmonized System of Classification and Labeling of Chemicals: Comparison of Lists of the European Union, Japan, Malaysia and New Zealand

  • Yazid, Mohd Fadhil H.A.;Ta, Goh Choo;Mokhtar, Mazlin
    • Safety and Health at Work
    • /
    • v.11 no.2
    • /
    • pp.152-158
    • /
    • 2020
  • Background: The Globally Harmonized System of Classification and Labeling of Chemicals (GHS) was developed to enhance chemical classification and hazard communication systems worldwide. However, some of the elements such as building blocks and data sources have the potential to cause "disharmony" to the GHS, particularly in its classification results. It is known that some countries have developed their own lists of classified chemicals in accordance with the GHS to "standardize" the classification results within their respective countries. However, the lists of classified chemicals may not be consistent among these countries. Method: In this study, the lists of classified chemicals developed by the European Union, Japan, Malaysia, and New Zealand were selected for comparison of classification results for carcinogenicity, germ cell mutagenicity, and reproductive toxicity. Results: The findings show that only 54%, 66%, and 37% of the classification results for each Carcinogen, Mutagen and Reproductive toxicants hazard classes, respectively are the same among the selected countries. This indicates a "moderate" level of consistency among the classified chemicals lists. Conclusion: By using classification results for the carcinogenicity, germ cell mutagenicity, and reproductive toxicity hazard classes, this study demonstrates the "disharmony" in the classification results among the selected countries. We believe that the findings of this study deserve the attention of the relevant international bodies.

Effects of Pruning Season on Compartmentalization of Pruning Wounds in Acer palmatum and Pinus strobus

  • Lee, Kyu-Hwa;Lee, Kyung-Joon
    • Journal of Korean Society of Forest Science
    • /
    • v.99 no.2
    • /
    • pp.226-234
    • /
    • 2010
  • This study was conducted to examine the effects of pruning season on the compartmentalization of pruning wounds in Acer palmatum and Pinus strobus. A total of eighty five field-grown trees for each species were allocated to five different seasons, early- and late-winter, mid-spring, mid- and late-summer, for pruning treatments. Wound closure rate (WCR) of the two species for one year after treatment, area of discolored stem tissue on the medial longitudinal surface and cambial dieback length under the pruning wound of A. palmatum were measured. Changes of total phenols and variations of extractives, holocellulose and lignin at the treated branch unions were examined. In WCR of A. palmatum, late-winter (March, 39.8%) and mid-spring (May, 39.7%) were higher than any other seasons, while early-winter (November, 28.4%) was significantly lower than late-winter and mid-spring. P. strobus showed similar results with A. palmatum. The WCR of early-winter (57.2%) was the lowest significantly among the five seasons, and mid-spring (73.5%) and late-winter (71.4%) showed higher a WCR than other seasons. In the discolored/wound area ratio of A. palmatum, early-winter (73.2%) was the highest by far, and mid- (July) and latesummer (September, 36.7%, respectively) were the lowest among the five seasons. In the length of cambial dieback, two dormant seasons, early- and late-winter were longer than any other seasons. Phenol contents at the treated branch union were changed in line with the seasonal fluctuation of the tree. Total phenols in the below core of the treated union were higher than those of the branch union with living branch, while little differences were seen in the above core. At the branch core of the treated union, phenols of A. palmatum decreased one month after the treatments, but P. strobus maintained similar to or a little higher than those at the controls. The major changes in chemical composition at pruning wounds were extractives and lignin increased by less than 20% in A. palmatum, while extractives in P. strobus remarkably increased by 70%.

An Experimental Animal Model of Anomalous Pancreaticobiliary Duct Union (췌담관 합류이상의 실험동물 모델)

  • Han, Seok-Joo;Chang, Hang-Seok;Kim, Jong-Sung;Han, Jin-Soo;Kim, Ho-Geun;Hwang, Eui-Ho
    • Advances in pediatric surgery
    • /
    • v.4 no.2
    • /
    • pp.100-109
    • /
    • 1998
  • The anomalous pancreaticobiliary duct union (APBDU) might cause the formation of choledochal cyst and malignancies of hepatopancreaticobiliary system. The purpose of this study is to make an experimental animal model of APBDU similar to that of human. One to two-month-old Mongrel dogs (n=12) were divided into two groups; the control group (n=2) had a sham operation performed, and in the experimental group (n=10) the end of distal ' common bile duct (CBD) was anastomosed to the side of the dorsal pancreatic duct making APBDD. Serum was obtained for chemical analysis on the 10th postoperative day. The dogs were sacrificed at the 5th week (n=3), the 6th week (n=3), the 7th week (n=2), the 8th week (n=2) and the 6th month (n=2) after the experimental surgery. With sacrifice, operative cholangiogram was taken, and bile juice was obtained for chemistry and bacterial culture. The en-bloc specimens of the hepatopancreaticobiliary system were removed for microscopic examination. Serum and bile juice amylase levels were elevated in the experimental group(n=10), but not in the control group(n=2). Operative cholangiograms of control group revealed no evidence of bile duct dilatation.. On the other hand, the bile duct in the experimental group was markedly dilated without any evidence of stenosis at the anastomosis site (n=10). Histologic examination of the hepatopancreaticobiliary system in the experimental group resembled the findings of choledochal cyst in human. The APBDU of this animal model can produce bile duct dilatation by pancreaticobiliary reflux. We think that this animal model can be potentially promising for the research about the APBDU associated hepatopancreaticobiliary diseases.

  • PDF

Analysis of Chemical Constitutions of MTA and 3 Portland Cements (EDS (Energy Dispersive Spectrometry)를 이용한 Mineral Trioxide Aggregate와 3종의 포틀랜드 시멘트의 성분비교에 관한 연구)

  • Chang, Seok-Woo;Bae, Kwang-Shik
    • Journal of Dental Rehabilitation and Applied Science
    • /
    • v.23 no.1
    • /
    • pp.79-84
    • /
    • 2007
  • Mineral Trioxide Aggregate(MTA) has been used in Endodontic treatment successfully for more than 10 years. But the high cost of MTA limits its use in endodontics in Korea. Recently many studies have been done to compare MTA and Portland cements. To investigate the chemical constitutions of MTA (Proroot MTA, Tulsa Dental), Gray Portland cement (Lafarge Halla cement), White Portland cement(Union corp), and fast setting cement (SSangyong cement), we performed SEM(scanning electron microscope)(S4700, Hitachi) examination and EDS(Energy dispersive spectrometry)(emax, Horiba) analysis. SEM examination and EDS analysis were committed to and performed in SNU DRI (Seoul National University Dental Research Institute). We found that particles of MTA were relatively round, uniform in size, and compactly packed compared to Portland cements. Chemical constitutions of MTA, GPC, WPC and FSC were similar. It was shown that MTA contains much BiO2 . MTA and WPC showed less heavy metals such as Fe and Mg compared to GPC and FSC. FSC showed remarkably high aluminum content.

Comparative Study of Exposure Potential and Toxicity Factors used in Chemical Ranking and Scoring System (화학물질 우선순위선정 시스템에서 고려되는 노출.독성인자 비교연구)

  • An, Youn-Joo;Jeong, Seung-Woo;Kim, Min-Jin;Yang, Chang-Yong
    • Environmental Analysis Health and Toxicology
    • /
    • v.24 no.2
    • /
    • pp.95-105
    • /
    • 2009
  • Chemical Ranking and Scoring (CRS) system is a useful tool to screen priority chemicals of large body of substances. The relative ranking of chemicals based on CRS system has served as a decision-making support tools. Exposure potential and toxicity are significant parameters in CRS system, and there are differences in evaluating those parameters in each CRS system. In this study, the parameters of exposure potential, human toxicity, and ecotoxicity were extensively compared. In addition the scoring methods in each parameter were analyzed. The CRS systems considered in this study include the CHEMS-1 (Chemical Hazard Evaluation for Management Strategies), SCRAM (Scoring and Ranking Assessment Model), EURAM (European Union Risk Ranking Method), ARET (Accelerated Reduction/Elimination of Toxics), and CRS-Korea. An comparative analysis of the several CRS systems is presented based on their assessment parameters and scoring methods.

Characteristics and Co-Occurrence Patterns of Fragrance Allergens in Consumer Chemical Products (생활화학제품의 알레르기반응가능 향료성분 함유 현황 및 동시 출현 패턴 조사)

  • Kim, Soomin;Lee, Kiyoung;Lim, Miyoung
    • Journal of Environmental Health Sciences
    • /
    • v.48 no.4
    • /
    • pp.206-215
    • /
    • 2022
  • Background: Fragrance substances in consumer products can cause adverse health effects such as contact allergy. In South Korea, consumer chemical products must list 26 known fragrance allergens on product labels when they contain more than 0.01%. Fragrance substances are mostly used in combination, so co-exposure can occur via use of a consumer chemical product. Co-exposure to fragrance allergens may show a synergistic effect on the human body. Objectives: The aims of the study were to analyze the characteristics of fragrance allergens in consumer chemical products available on public websites and to identify the co-occurrence patterns of fragrance allergens. Methods: The chemicals in 1,443 ingredient disclosures for consumer chemical products were collected through the Ecolife database. The 26 labelled fragrance allergens were identified by category of consumer chemical product. The co-occurrence patterns of the 26 labelled fragrance allergens were analyzed by frequent pattern mining. The unlabelled fragrance allergens presented by European Union Scientific Committee on Consumer Safety were also identified. Results: Consumer chemical products contained an average of 5.3±4.2 substances among the 26 labelled fragrance allergens. More than 85% of air fresheners, deodorizing agents, and fabric softeners contained at least one of the 26 labelled fragrance allergens. The most frequently contained fragrance allergens were limonene (50.5%), linalool (49.9%), hexyl cinnamal (34.0%), and citronellol (28.3%). 16.7% of consumer chemical products showed a co-occurrence of limonene, linalool, hexyl cinnamal, and citronellol. Thirty-eight unlabelled fragrance allergens were found in the consumer chemical products, with hexamethylindanopyran (25.2%) being the most frequently contained substance. Conclusions: The characteristics and co-occurrence patterns of 26 labelled fragrance allergens would be useful information for the management of co-exposure to fragrance allergens in consumer chemical products. It is necessary for attention to be paid to unlabelled fragrance allergens.

Some of the Food Color Additives Are Potent Inhibitors of Human Protein Tyrosine Phosphatases

  • Shrestha, Suja;Bhattarai, Bharat Raj;Lee, Keun-Hyeung;Cho, Hyeong-Jin
    • Bulletin of the Korean Chemical Society
    • /
    • v.27 no.10
    • /
    • pp.1567-1571
    • /
    • 2006
  • Synthetic color additives approved for general food use are sixteen in European Union, seven in U. S. A. and twelve in Japan. Twelve food dyes were examined for their inhibitory potency against human protein tyrosine phosphatases (PTPases). Half of the food colorants inhibited PTPases significantly and three of them were potent inhibitors with low micromolar IC50 values. Also examined were the synthetic dyes structurally similar but not allowed in food. Some of them were potent inhibitors of PTPases. Considering the importance of PTPases in cellular signal transduction, inhibition of PTPases by food colorants might cause harmful effects in human health.

Technology Trend for Photochemical Hydrogen Production by the Patent Analysis (특허분석에 의한 광화학적 수소제조 기술동향)

  • Moon, Sang-Jin;Kang, Kyung-Seok;Han, Hye-Jeong;Baeg, Jin-Ook;Kim, Jong-Wook
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.18 no.2
    • /
    • pp.197-206
    • /
    • 2007
  • There are several methods for the hydrogen production such as steam reforming of natural gas, photochemical method, biological method, electrolysis and thermochemical method, etc. Many researches have been widely performed for the hydrogen production method having low production cost and high efficiency. In this paper, the patents concerning the photochemical hydrogen production method were gathered and analyzed. The search range was limited in the open patents of USA(US), European Union(EP), Japan(JP), and Korea(KR) from 1996 to 2005. Patents were gathered by using key-words searching and filtered by filtering criteria. The patent application trend was analyzed by the years, countries, companies, and technologies.