• Title/Summary/Keyword: Chemical Treatments

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Environmentally Friendly Surface Treatments for Improvement of Corrosion of Steel Sheets: Synergy Effect by Multicoating (강판의 내식성 향상을 위한 환경 친화형 표면처리: 다중코팅에 의한 시너지 효과)

  • Jeon Sangik;Park Chan-Young;Ryou Jin-Ho;Lee Won-Ki
    • Journal of Environmental Science International
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    • v.14 no.1
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    • pp.97-103
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    • 2005
  • Because of the toxicity of hexavelant chromium ion, treatments of metallic surface with chromate compounds to retard corrosion are undesirable for safety control in industrial uses and protection of environment. In this study, we investigated several compounds such as inorganic, organic, and polymer materials in order to sub­stitute the chromate conversion treatment on steel sheet. The corrosion property was investigated in a salt spray tester with 3.5 $wt.{\%}\;NaCI\;at\;35^{\circ}C.$ The results showed that the zirconium/silane/polymer triple coatings on the galvanized steel exhibited a significant retardation of corrosion. Although the multicoating system needs a com­plexed processing, we can confirm a possibility of development of a chromate-free chemical conversion treat­ment for galvanized steel sheet.

Effect of Chemical Treatment with Citric Acid or Ozonated Water on Microbial Growth and Polyphenoloxidase Activity in Lettuce and Cabbage

  • Youm, Hyoung-Jun;Jang, Jae-Won;Kim, Kyu-Ri;Kim, Hyo--Jjung;Jeon, Eun-Hee;Park, Eun-Kyoung;Kim, Mee-Ree;Song, Kyung-Bin
    • Preventive Nutrition and Food Science
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    • v.9 no.2
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    • pp.121-125
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    • 2004
  • Effects of chemical treatment with a citric acid solution or ozonated water on microbiological changes in lettuce and cabbage during storage were studied. Fresh lettuce and cabbage samples were cut into small pieces and treated by soaking in either ozonated water or a citric acid solution. After treatment, populations of total bacteria, yeast and mold, and E. coli were determined. Numbers of microorganisms increased during storage, but ozonated water and citric acid treatments retarded the increase in microbial growth. Among treatments, 1 % citric acid treatment was the most effective in terms of microbiological change and inhibition of polyphenoloxidase (PPO). For lettuce, citric acid treatment decreased the microbial growth overall by 1.5 log CFU/g and inhibited the PPO activity by 80%. These results indicate that chemical-treated lettuce and cabbage retained a better quality than those of the control during storage.

Effects of Continuous Application of Green Manures on Microbial Community in Paddy Soil

  • Kim, Sook-Jin;Kim, Kwang Seop;Choi, Jong-Seo;Kim, Min-Tae;Lee, Yong Bok;Park, Ki-Do;Hur, Seonggi
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.5
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    • pp.528-534
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    • 2015
  • Green manure crops have been well recognized as the alternative for chemical fertilizer, especially N fertilizer, because of its positive effect on soil and the environment. Hairy vetch and green barley are the most popular crops for cultivation of rice in paddy field. This study was conducted to evaluate effects of hairy vetch and green barley on soil microbial community and chemical properties during short-term application (three years). For this study, treatments were composed of hairy vetch (Hv), green barley (Gb), hairy vetch + green barley (Hv+Gb), and chemical fertilizer without green manure crops (Con.). Hv+Gb treatment showed the highest microbial biomass among treatments. Principal component analysis (PCA) showed that PC1 (73.0 %) was affected by microbial biomass and PC2 (21.5 %) was affected by fungi, cy19:0/18:$1{\omega}7c$ (stress indicator). Combined treatment with hairy vetch and green barley could be more efficient than green manure crop treatment as well as chemical fertilizer treatment for improvement of soil microorganisms.

Isolation of Bovine Spermatozoal Components by Physical or Chemical Treatments (물리.화학적 처리에 의한 소 정자세포구성분의 분리)

  • 최승철;천장혜;이상호
    • Korean Journal of Animal Reproduction
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    • v.17 no.4
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    • pp.339-346
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    • 1994
  • An understanding of the structure and function of mammalian spermatozoa requires the iso-lation of these components. In this study, frozen-thawed bovine spermatozoa were treated by physical treatments (vortexing, 26 gauge needle, strained 26 gauge needles and freezing-thawing) or chemical treatments (trypsin, dithiothreitol, sodium dodecylsulfate and $\beta$-mercaptoethanoJ) to yield free heads and tails. The most effective treatment was repeated pumping of sperm suspension through a strained 26 gauge needle conneted to a syringe. Spermatozoa by this treatment were mainly broken at the junction of the head and the tail, resulting in 90-100% yields. Also, sperm head surface did not modify during strained 26 gauge needle treatment when either spermatozoa or sperm heads were incubated in 250${\mu}\textrm{g}$/ml of FITC-UEA 1 for 1 h at room temperature to detect the modification of sperm surface components. Other physical treatments were less efficient for the breakdown of spermatozoa. The effects of chemical treatments on bovine spermatozoa are not noticeable. Dissected sperm heads and tails should be fractional leading to nearly pure components by sucrose gradient centrifugation at 1,000 rpm for 15 min. The result suggest that the established method may be useful for the biochemical study of spermatozoal components, and the understanding of oocyte activation mechanism either by spermatozoal components during fertilization or microinjection of isolated components.

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Structural Development of Scalp Hair in Children and Effects of Cosmetologic Physico-Chemical Treatments on Adult Scalp Hair (어린아이 머리털의 구조 변화 및 물리화학적 미용기법이 어른 머리털에 미치는 영향)

  • Park, Chang-Hyun;Choi, Ki-Ju;Moon, Sung-Jin;Uhm, Chang-Sub
    • Applied Microscopy
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    • v.32 no.4
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    • pp.339-344
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    • 2002
  • Recently, there has been an increase in the cosmetologic treatments on hair in Korea. To investigate the time when morphological characteristics of human scalp hair take mature form, hairs of 0, 3, 6, 12, 24 months, and of adult scalp hair were compared. Also, the physico-chemical effects of commonly used cosmetological treatments; hair-dryed, dye coated, stained and permanent waved scalp hairs were observed by scanning electron microscopy. Two year-old hair was similar to the adult hair, and all hairs received cosmetologic treatments except for coated hair showed various degree of deformation and damage. These results suggest that routinely used cosmetologic treatments may give harmful effects on hairs. More detailed studies in large scale may be necessary.

Treatments Effect on Biological Values of Defatted Rice Polishings

  • Khalique, Anjum;Lone, K.P.;Khan, A.D.;Pasha, T.N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.2
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    • pp.209-216
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    • 2006
  • Defatted rice polishings (DRP) was subjected to chemical treatments i.e., 0.4 N HCl, and 6% $H_2O_2$, with or without physical treatment i.e. extrusion cooking. The treated DRP was evaluated chemically and biologically using male broiler chicks (108) of approximately uniform weight, selected out of 220 chicks, previously fed on commercial diets for 7 days as a settlement period. The chicks were then divided into 36 experimental units of 3 chicks each. Each experimental diet was randomly allotted to three experimental units and fed for 10 days to broiler chicks. The experimental diets were designated as A (Commercial), B (10% HCl treated DRP), C (20% HCl treated DRP), D (10% HCl plus extruded DRP), E (20% HCl plus extruded DRP), F (10% $H_2O_2$ DRP) and G (20% $H_2O_2$ DRP), H (10% $H_2O_2$ plus extrusion DRP) and I (20% $H_2O_2$ plus extrusion DRP), J (10% untreated DRP), K (20% untreated DRP) and L (Protein free). The birds fed on diet L were used to measure the endogenous nitrogen loss. The biological evaluations of diets containing differently treated DRP were compared with a commercial feed and feeds containing untreated defatted rice polishings. It was observed that these treatments liberated bound nutrients, making them more accessible to the normal digestive enzymes and increased their apparent nutrient availability. This process probably also detoxified the anti-nutritive factors i.e. phytates, lectin, trypsin inhibitor present in DRP. The results of the feeding trials revealed that diets containing 6% $H_2O_2$ treated DRP showed better weight gain, feed consumption and utilization, protein efficiency and digestibility, biological value and net protein utilization than all other treatments.

Modification of isotropic coal-tar pitch by acid treatments for carbon fiber melt-spinning

  • Yoo, Mi Jung;Ko, Hyo Jun;Lim, Yun-Soo;Kim, Myung-Soo
    • Carbon letters
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    • v.15 no.4
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    • pp.247-254
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    • 2014
  • In this work, thermal treatment accompanied with different acid treatments was applied to a commercial coal tar pitch (CTP) to obtain a spinnable precursor pitch for carbon fiber. In the case of thermal treatment only, a relatively high reaction temperature of between $380^{\circ}C$ and $400^{\circ}C$ was required to obtain a softening point (SP) range of $220^{\circ}C-260^{\circ}C$ and many meso-phase particles were created during the application of high reaction temperature. When nitric acid or sulfuric acid treatment was conducted before the thermal treatment, the precursor pitch with a proper SP range could be obtained at reaction temperatures of $280^{\circ}C-300^{\circ}C$, which were about $100^{\circ}C$ lower than those for the case of thermal treatment only. With the acid treatments, the yield and SP of the precursor pitch increased dramatically and the formation of meso-phase was suppressed due to the lower reaction temperatures. Since the precursor pitches with acid and thermal treatment were not spinnable due to the inhomogeneity of properties such as molecular weight distribution and viscosity, the CTP was mixed with ethanol before the consecutive nitric acid and thermal treatments. The precursor pitches with ethanol, nitric acid, and thermal treatments were easily spinnable, and their spinning and carbon fiber properties were compared to those of air blowing and thermal treated CTP.

Enhanced oxidative stability of meat by including tannin-rich leaves of woody plants in goat diet

  • Garcia, Elisa Mariana;Lopez, Agustin;Zimerman, Maria;Hernandez, Olegario;Arroquy, Jose Ignacio;Nazareno, Monica Azucena
    • Asian-Australasian Journal of Animal Sciences
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    • v.32 no.9
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    • pp.1439-1447
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    • 2019
  • Objective: The aim of this study was to evaluate the effect of dietary incorporation of tanninrich woody species on meat oxidative stability, carcass traits and meat quality in goats. Methods: Two tannin-rich species were tested using a three-treatments feeding trial, where treatments consisted of: Larrea divaricata and Acacia aroma both at 12.5% in dry matter basis of the diet and a control diet (alfalfa hay). All feeding diets were iso-protein and iso-energy. Carcass conformation, carcass compactness, carcass fatness and subcutaneous fat deposition were evaluated. Intake, liveweigh, Longissimus thoracis et lumborum muscles of goats were analyzed in order to evaluate quality parameters such as pH value, instrumental color evaluation, water holding capacity, total phenolic content, antioxidant activity, meat oxidative stability and fatty acid profiles in meat. Results: Feed intake, liveweight gain, carcass, and meat traits did not differ among treatments. Changes in meat lipid profile among treatments were observed for oleic and elaidic acid contents. Meat total phenolic content and antioxidant activity did not differ among treatments; although, meat oxidative status after storage at room temperature, as well as under refrigerated and frozen conditions were different between control and both supplemented groups. Conclusion: The inclusion of Acacia aroma and Larrea divaricata leaves in goat diet enhanced meat oxidative stability. Modulation of the ruminal biohydrogenation of fatty acids produced by condensed tannins of these plant species need to be further investigated.

Comparison of Nitrate Accumulation in Lettuce Grown under Chemical Fertilizer or Compost Applications (화학비료와 퇴비 시용으로 재배한 상추의 질산염 축적 비교)

  • Lee, Yoon-Jung;Chung, Jong-Bae
    • Korean Journal of Environmental Agriculture
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    • v.25 no.4
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    • pp.339-345
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    • 2006
  • Accumulation of nitrate in green vegetables is undesirable due to potential risks to human health. Lettuce was cultivated in pots under greenhouse conditions with compost applications of 2,000 and 4,000 kg/10a, and the growth and nitrate accumulation of lettuce were compared with those found in the lettuce cultivated with chemical fertilizers of recommended levels. Content of $NH_4-N$ in the soils of compost applications were much lower than those found in the soil of chemical fertilizer application. Two weeks after lettuce transplant $NH_4-N$ was not found in the soils of compost applications, and in the soils of chemical fertilizers application $NH_4-N$ was not found three weeks after lettuce transplant. One week after lettuce transplant content of $NO_3-N$ was much higher in the soils of compost applications, and the contents were rapidly decreased. While, the content of $NO_3-N$ in the soil of chemical fertilizers application was rapidly increased due to the nitrification of $NH_4$ released from the applied urea. At the time of harvest contents of $NO_3-N$ in the soils of compost applications were less than 1.4 mg/kg, but in the soil of chemical fertilizers application the content of $NO_3-N$ was 54.2 mg/kg. Contents of $NH_4$ in lettuce were about 20 mg/kg FW and were not much different among the treatments. However, contents of $NO_3$ in lettuce were significantly different between the treatments of chemical fertilizer and compost. There were significant differences in fresh and dry weights, and growth of lettuce in the compost treatment of 4,000 kg/10a was highest among the treatments. These results indicate that the cultivation with compost only as N source can produce higher yield of lettuce and significantly reduce nitrate accumulation as compared to the conventional cultivation with chemical fertilizers.

Effect of Acid Treatments on Hydrogen Storage Behaviors of Ordered Mesoporous Carbons (화학적 산처리가 중기공 탄소체의 수소저장거동에 미치는 영향)

  • Lee, Seul-Yi;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.229.1-229.1
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    • 2010
  • We investigated the effect of chemical acid treatments on hydrogen storage behaviors of the ordered mesoporous carbons (MCs). The surface functional groups and specific elements of the MCs were characterized with Fourier Transform Infrared (FT-IR) spectrometry and X-ray photoelectron spectroscopy (XPS). Also, the changes in the surface functional groups of the MCs were quantitatively detected by Boehm's titration method. The structural properties of the MCs were investigated using X-ray diffraction (XRD). The hydrogen adsorption capacity of the MCs was evaluated by means of adsorption isotherms at 77 K/1 bar. The formation of surface functional groups by the acidic treatments could influence on the hydrogen storage capacity of the MCs.

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