• Title/Summary/Keyword: Chemical Storage System

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Nonlinear response of complex fluids under LAOS(large amplitude oscillatory shear) flow

  • Ahn, Kyung-Hyun;Kyu Hyun;Nam, Jung-Gun;Manfred Wilhelm;Lee, Seung-Jong
    • Korea-Australia Rheology Journal
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    • v.15 no.2
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    • pp.97-105
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    • 2003
  • In the previous paper (Hyun et al.,2002), we have investigated the shape of storage modulus (G') and loss modulus (G") of complex fluids under large amplitude oscillatory shear (LAOS) flow. As the strain amplitude increases, owever, the stress curve becomes distorted and some important information may be smothered during data processing. Thus we need to investigate the stress data more precisely and systematically. In this work, we have obtained the stress data using high performance ADC (analog digital converting) card, and investigated the nonlinear response of complex fluids, 4wt% xanthan gum (XG), 2 wt% PVA/ 1 wt% Borax, and 1 wt% hyaluronic acid (HA) solutions, using Fourier transformation (FT) rheology. Comparing the strain signals in time domain with FT parameters in frequency domain, we could illustrate the sensitivity and importance of FT rheology. Diverse and unique stress patterns were observed depending on the material system as well as flow environment. It was found that they are not the outcome of experimental deficiency like wall slip but characteristics of the material system. When nonlinear response of complex fluids is analyzed, the intensity and phase angle of higher harmonic contributions should be considered together, and the shape of the stress signal was found to be strongly dependent upon phase angle.ngle.

Mobile Robot-based Leak Detection and Tracking System for Advanced Response and Training to Hazardous Materials Incidents (화학물질 저장시설의 사고대응 및 훈련을 위한 로봇기반 누출감지 및 추적시스템)

  • Park, Myeongnam;Kim, Chang Won;Kim, Tae-Ok;Shin, Dongil
    • Journal of the Korean Institute of Gas
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    • v.23 no.2
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    • pp.17-27
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    • 2019
  • In recent years, dangerous materials and gas leak accidents have been frequently occurred. The hazardous materials storage facility accidents are not rapidly controlled when a leak is detected, unlike other chemical plants can be controled. Externally, the human has to approach and respond to the source of leaking directly. As a result, the human and material damage are likely to larger result in the process. The current approach has been passive response after ringing the alarm. In this study, the suggested tracking system of the leak resource is designed system to track the resource actively by utilizing the mobile sensor robot platform, which can be made easily through recent rapid development technology, is verified through prototype system. Thus, a suggested system should pave the way for minimizing the spread and damage of the accident based on the exact site situation of the initial leak and quick and early measures.

Development of Emergency Response System by Risk Assessment Methodology in Energy Facility (에너지 시설물의 위험성 평가에 따른 비상대응 시스템 구축)

  • Lee, Heon-Seok;Kang, Seung-Gyun;Jung, In-Hee;Kim, Bum-Su;Yoo, Jin-Hwan;Park, Chul-Hwan;Kim, Dae-Heum;Ko, Jae-Wook
    • Journal of the Korean Institute of Gas
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    • v.12 no.2
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    • pp.118-123
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    • 2008
  • There are many facilities, such as facilities for high pressure gas storage and systems related to high pressure pipes, to handle hazardous materials in energy industries. Because the foundation of the proper risk analysis and management system has not been established, there is the possibility of an accident and Korea has met higher accident rate than developed countries. These accidents in energy facilities could cause great damage to facilities including the surrounding area, We have conducted the present research in order to systematize the emergency response system (ERS) using a lot of information on the degree of damage in an accident by consequence analysis.

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Development of Micro-Tubular Perovskite Cathode Catalyst with Bi-Functionality on ORR/OER for Metal-Air Battery Applications

  • Jeon, Yukwon;Kwon, Ohchan;Ji, Yunseong;Jeon, Ok Sung;Lee, Chanmin;Shul, Yong-Gun
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.425-431
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    • 2019
  • As rechargeable metal-air batteries will be ideal energy storage devices in the future, an active cathode electrocatalyst is required with bi-functionality on both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) during discharge and charge, respectively. Here, a class of perovskite cathode catalyst with a micro-tubular structure has been developed by controlling bi-functionality from different Ru and Ni dopant ratios. A micro-tubular structure is achieved by the activated carbon fiber (ACF) templating method, which provides uniform size and shape. At the perovskite formula of $LaCrO_3$, the dual dopant system is successfully synthesized with a perfect incorporation into the single perovskite structure. The chemical oxidation states for each Ni and Ru also confirm the partial substitution to B-site of Cr without any changes in the major perovskite structure. From the electrochemical measurements, the micro-tubular feature reveals much more efficient catalytic activity on ORR and OER, comparing to the grain catalyst with same perovskite composition. By changing the Ru and Ni ratio, the $LaCr_{0.8}Ru_{0.1}Ni_{0.1}O_3$ micro-tubular catalyst exhibits great bi-functionality, especially on ORR, with low metal loading, which is comparable to the commercial catalyst of Pt and Ir. This advanced catalytic property on the micro-tubular structure and Ru/Ni synergy effect at the perovskite material may provide a new direction for the next-generation cathode catalyst in metal-air battery system.

A Quality Assurance Study for the Application of Cook/chill System in School Foodservice Operation (I) - Broiled Spanish Mackerel - (학교급식에 Cook/chill system 적용을 위한 품질보증연구(I) - 삼치구이 -)

  • Kwak, Tong-Kyung;Moon, Hye-Kyung;Park, Hye-Won;Hong, Wan-Soo;Ryu, Kyung;Chang, Hye-Ja;Kim, Sung-Hee;Choi, Eun-Jung
    • Journal of Food Hygiene and Safety
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    • v.13 no.3
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    • pp.278-293
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    • 1998
  • The purposes of this study were to develop Hazard Analysis Critical Control Point-based standardized recipe applicable to cook/chilled Broiled Spanish Mackerel in school foodservice operations and to establish reasonable shelf-life limits by assessing food quality during chilled storage period of 5 days. HACCP for the production of menu items was identified in simulation study. At each critical control point, time-temperature profile was recorded and microbiological analysis was done. Also chemical analyses and sensory evaluation were conducted for 5 days of chilled storage. The results of time-temperature measurement of Broiled Spanish Mackerel by each production phase showed satisfactory condition that met the standards. Broiled Spanish Mackerel showed excellent microbiological quality from raw ingredient phase ($TPC:2.58{\pm}0.12\;Log\;CFU/g$) to holding phase ($TPC:2.70{\pm}0.42\;Log\;CFU/g$). Coliform (0.84 Log MPN/g) and fecal coliform (0.84 Log MPN/g) were detected from marinating phase ($TPC:3.82{\pm}0.52\;Log\;CFU/g$). After heating, only few mesophiles were detected ($TPC:1.83{\pm}0.49\;Log\;CFU/g$). No psychrophiles, coliforms and fecal coliforms were detected. In the phases after rapid chilling, during chilled storage and after reheating and distribution, almost none of the above microbes were detected. Salmonella and Listeria monocytogenes were not detected in all production phases. The pH immediately after cooking was 6.65 and then increased significantly to 6.81 on the third day of chilled storage (p<0.001). Acid value did not show significant changes while total volatile based nitrogen (TVBN) dramatitically increased during storage periods (p<0.01). In the result of sensory evaluation, general acceptability points had been rated high in the first day of storage, and then, the points were decreased significantly on the third day (p<0.05). General acceptability points ranged from 8.86 to 10.68. Accordingly, Broiled Spanish Mackerel is highly recommendable cook/chill system. Considering the DHSS standards for storage, the ideal shelf-life recommended for Broiled Spanish Mackerel is within 4 days excluding cooking day. For Broiled Spanish Mackerel, critical control points were purchasing and receiving of frozen Spanish Mackerel, heating, chilling, chilled storage, reheating and distribution.

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Design and Manufacturing of Natural Composite Chemical Container Tank Using Resin Flow Simulation

  • Kim, Myungsub;Park, Hyunbum
    • International Journal of Aerospace System Engineering
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    • v.4 no.1
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    • pp.9-12
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    • 2017
  • In this study, an investigation on mechanical properties of flax natural fiber composite is performed as a precedent study on the design of eco-friendly structure using flax natural fiber composite. The Vacuum Assisted Resin Transfer Molding-Light (VARTML) manufacturing method is adopted for manufacturing the flax fiber composite panel. The VARTML is a manufacturing process that the resin is injected into the dry layered-up fibers enclosed by a rigid mold tool under vacuum. In this work, the resin flow analysis of VARTM manufacturing method is performed. A series of flax composite panels are manufactured, and several kinds of specimens cut out from the panels are tested to obtain mechanical performance data. Based on this, structural design of chemical storage tank for agricultural vehicle was performed using flax/vinyl ester. After structural design and analysis, the resin flow analysis of VARTM manufacturing method was performed.

Design of Natural Fiber Composites Chemical Container Using Resin Flow Simulation of VARTML Process

  • Lee, Haseung;Park, Gwanglim;Kong, Changduk;Park, Hyunbum
    • International Journal of Aerospace System Engineering
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    • v.1 no.1
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    • pp.21-28
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    • 2014
  • In this study, an investigation on mechanical properties of flax natural fiber composite is performed as a precedent study on the design of eco-friendly structure using flax natural fiber composite. The Vacuum Assisted Resin Transfer Molding-Light (VARTML) manufacturing method is adopted for manufacturing the flax fiber composite panel. The VARTML is a manufacturing process that the resin is injected into the dry layered -up fibers enclosed by a rigid mold tool under vacuum. In this work, the resin flow analysis of VARTM manufacturing method is performed. A series of flax composite panels are manufactured, and several kinds of specimens cut out from the panels are tested to obtain mechanical performance data. Based on this, structural design of chemical storage tank for agricultural vehicle was performed using flax/vinyl ester. After structural design and analysis, the resin flow analysis of VARTM manufacturing method was performed.

A Study on change in thermal properties and chemical structure of Zr-Ni delay system by aging (노화에 따른 Zr-Ni계 지연관의 열 특성 및 화학적 구조 변화에 관한 연구)

  • Park, Byung Chan;Chang, Il Ho;Kim, Sun Tae;Hwang, Taek Sung;Lee, Seungho
    • Analytical Science and Technology
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    • v.22 no.4
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    • pp.285-292
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    • 2009
  • It has been observed that, after long term storage, some ammunitions are misfired by tamping (combustionstopping) due to aging of the chemicals loaded in the ammunitions. Used in ammunitions are percussion powder which provides the initial energy, igniter which ignites the percussion powder, and a delay system that delays the combustion for a period of time. The percussion powder is loaded first, followed by the igniter and then the delay system, and the ammunitions explode by the energy being transferred in the same order. Tamping occurs by combustion-stopping of the igniter or insufficient energy transfer from the igniter to the delay system or the combustion-stopping of the delay system, which are suspected to be caused by low purity of the components, inappropriate mixing ratio, size distribution of particulate components, type of the binder, blending method, hydrolysis by the humidity penetrated during the long term storage, and chemical changes of the components by high temperature. Goal of this study is to find the causes of the combustion-stopping of the igniter and the delay system of the ammunitions after long term storage. In this study, a method was developed for testing of the combustion-stopping, and the size distributions of the particulate components were analyzed with field-flow fractionation (FFF), and then the mechanism of chemical change during long term storage was investigated by thermal analysis (differential scanning calorimetry), XRD (X-ray diffractometry), and XPS (X-ray photoelectron spectroscopy). For the ignition system, M (metal)-O (oxygen) and M-OH peaks were observed at the oxygen's 1s position in the XPS spectrum. It was also found by XRD that $Fe_3O_4$ was produced. Thus it can be concluded that the combustion-stopping is caused by reduction in energy due to oxidation of the igniter.

Research Review of Sodium and Sodium Ion Battery (나트륨을 활용한 이차전지 연구동향)

  • Ryu, Cheol-Hwi;Kang, Seong-Gu;Kim, Jin-Bae;Hwang, Gab-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.1
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    • pp.54-63
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    • 2015
  • The secondary battery using sodium is investigating as one of power storage system and power in electric vehicles. The secondary battery using sodium as a sodium battery and sodium ion battery had merits such as a abundant resources, high energy density and safety. Sodium battery (sodium molten salt battery) is operated at lower temperature ($100^{\circ}C$) compared to NAS and ZEBRA battery ($300{\sim}350^{\circ}C$). Sodium ion battery is investigating as one of the post lithium ion battery. In this paper, it is explained for the principle and recent research trends in sodium molten salt and sodium ion battery.

Using oscillatory shear to probe the effects of bidispersity in inverse ferrofluids

  • Ekwebelam, C.C.;See, H.
    • Korea-Australia Rheology Journal
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    • v.19 no.1
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    • pp.35-42
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    • 2007
  • The effects of particle size distribution on the magnetorheological response of inverse ferrofluids was investigated using controlled mixtures of two monodisperse non-magnetisable powders of sizes $4.6\;{\mu}m\;and\;80{\mu}m$ at constant volume fraction of 30%, subjected to large amplitude oscillatory shear flow. In the linear viscoelastic regime (pre-yield region), it was found that the storage and loss moduli were dependent on the particle size as well as the proportion of small particles, with the highest storage modulus occurring for the monodisperse small particles. In the nonlinear regime (post yield region), Fourier analysis was used to compare the behaviour of the $1^{st}\;and\;3^{rd}$ harmonics ($I_{1}\;and\;I_{3}\;respectively$) as well as the fundamental phase angle as functions of the applied strain amplitude. The ratio of $I_{3}/I_{1}$ was found to become more pronounced with decreasing particle size as well as with increasing proportion of small particles in the bidisperse mixtures. Furthermore, the phase angle was able to clearly show the transition from solid-like to viscous behaviour. The results suggested that the nonlinear response of a bidisperse IFF is dependent on particle size as well as the proportion of small particles in the system.