• Title/Summary/Keyword: Chemical Sensors

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Characteristics of polycrystalline 3C-SiC thin films grown on AlN buffer layer for M/NEMS applications (AlN 버퍼층위에 성장된 M/NEMS용 다결정 3C-SiC 박막의 특성)

  • Chung, Gwiy-Sang;Kim, Kang-San;Lee, Jong-Hwa
    • Journal of Sensor Science and Technology
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    • v.16 no.6
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    • pp.457-461
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    • 2007
  • This paper describes the characteristics of poly (polycrystalline) 3C-SiC grown on $SiO_{2}$ and AlN substrates, respectively. The crystallinity and the bonding structure of poly 3C-SiC grown on each substrate were investigated according to various growth temperatures. The crystalline quality of poly 3C-SiC was improved from resulting in decrease of FWHM (full width half maximum) of XRD and FT-IR by increasing the growth temperature. The minimum growth temperature of poly 3C-SiC was $1100^{\circ}C$. The surface chemical composition and the electron mobility of poly 3C-SiC grown on each substrate were investigated by XPS and Hall Effect, respectively. The chemical compositions of surface of poly 3C-SiC films grown on $SiO_{2}$ and AlN were not different. However, their electron mobilities were $7.65{\;}cm^{2}/V.s$ and $14.8{\;}cm^{2}/V.s$, respectively. Therefore, since the electron mobility of poly 3C-SiC films grown on AlN buffer layer was two times higher than that of 3C-SiC/$SiO_{2}$, a AlN film is a suitable material, as buffer layer, for the growth of poly 3C-SiC thin films with excellent properties for M/NEMS applications.

Ag-functionalized SnO2 Nanowires Based Sensor for NO2 Detection at Low Operating Temperature (NO2 감응을 위한 Ag 금속입자가 기능화된 SnO2 나노선 기반 저온동작 센서)

  • Choi, Myung Sik;Kim, Min Young;Ahn, Jihye;Choi, Seung Joon;Lee, Kyu Hyoung
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.2
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    • pp.11-17
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    • 2020
  • In this study, Ag-functionalized SnO2 nanowires are presented for NO2 gas sensitive sensors at low temperatures (50℃). SnO2 nanowires were synthesized using vapor-liquid-solid method, and Ag metal particles were functionalized on the surface of SnO2 nanowires using flame chemical vapor deposition method. As a result of the sensing test about Ag-functionalized SnO2 nanowires based sensor, the response (Rg/Ra) to 10 ppm NO2 was 1.252 at 50℃. We believe that metal-functionalizing is a one of good way to increase the feasibility about semiconductor gas sensor.

Conducting Polymers with Functional Dopants and their Applications in Energy, Environmental Technology, and Nanotechnology

  • Kim, Sung Yeol;Song, Hyun-Kon
    • Clean Technology
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    • v.21 no.1
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    • pp.12-21
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    • 2015
  • Development of novel conducting polymers (CPs) is expected to facilitate the advancement of functional materials used for energy, environmental, and nanotechnology. Recent research efforts are focused on doping CPs with functional dopants to enhance their performance or add additional functions that are not inherent in CPs. This review surveys literatures about the doped CPs focusing on the roles of functional dopants, unlike other reviews focusing on the development of new conducting polymer backbones. The functional dopants presented in this review include redox active molecules, carbon nanomaterials, biopolymers, and chelating molecules. Depending on the dopants and their physicochemical properties, the doped CPs can be used for a variety of applications such as polymer batteries, membranes for waste water treatment, and chemical sensors. A major challenge of the CPs is presented and the ways to overcome the challenge is also suggested for the future development of stable, high performance CPs.

Rubber Composites with Piezoresistive Effects (고무 복합재료의 압저항 효과)

  • Jung, Joonhoo;Yun, Ju Ho;Kim, Il;Shim, Sang Eun
    • Elastomers and Composites
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    • v.48 no.1
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    • pp.76-84
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    • 2013
  • The term 'Piezoresistive effect' describes a change in the electrical resistance of the material from deformed to its original shape by the external pressure, e.g., elongation, compression, etc. This phenomenon has various applications of sensors for monitoring pressure, vibration, and acceleration. Although there are many materials which have the piezoresistive effect, rubber (nano)composites with conductive fillers have attracted a great deal of attention because the piezoresistive effect appears at the various range of pressure by controlling the type of filler, particle size, particle shape, aspect ratio of particles, and filler content. Especially one can obtain the composites with elasticity and flexibility by using the rubber as a matrix. This paper aims to review the piezoresistive effect itself, their basic principles, and the various conductive rubber-composites with piezoresistive effect.

Soft sensor design based on PLS with hybrid inner model (내적 조합 모델 PLS를 이용한 소프트 센서 설계)

  • Hong Sun Ju;Han Chong Hun
    • Journal of the Korean Institute of Gas
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    • v.2 no.3
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    • pp.49-53
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    • 1998
  • It takes quite a long time for an analyzer, such as gas chromatography, to measure a bulk property of a system, which prevents on-line measurements. Also, the cost of installation and maintenance is very high. Consequently, some other means is needed for on-line measurements of properties and the development of soft sensors based on process variables like temperature and pressure is of great interest. In the field of gas industry, the development of a soft sensor which makes indirect on-line measurements of gas compositions and flow rate, is in progress. In this paper, we proposed a hybrid inner model PLS which improved the prediction performance by taking into account the data structure, as an empirical modeling algorithm. When applied to a design of a soft sensor of a distillation tower, the hybrid inner model PLS showed better prediction performance than other methods.

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Tallium(I) Ion-Selective Electrodes Based on Crown Ethers (크라온에테르를 이용한 탈륨(I) 이온 선택성 전극)

  • Sung Min Kim;Sung Uk Jung;Jineun Kim;Jae Sang Kim
    • Journal of the Korean Chemical Society
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    • v.37 no.8
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    • pp.773-778
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    • 1993
  • Poly(vinyl chloride)(PVC) membrane electrodes based on the lipophilic neutral carrier, dibenzo-18-crown-6(DB18C6) and benzo-15-crown-5 (B15C5) as the active sensors for Tl$^+$ ion have been prepared and tested in different content of the potassium tetrakis(4-chlorophenyl)borate (KTClPB) as lipophilic salt. Dioctyl adipate (DOA), 2-nitrophenyl phenyl ether (NPPE) and o-nitrophenyl actyl ether (NPOE) were used as plasticizing solvent mediators. Electrodes exhibited good linear responses of 40∼55 mV decade$^{-1}$ for Tl$^+$ ion within the concentration ranges 10$^{-1}$∼10$^{-5}$M TlNO$_3$. Selectivity coefficients of interfering ions (alkali metal, alkaline earth metal and some transition metal ions) for Tl$^+$-ISE were determined by separate solution method and were sufficiently small for most of them. These crown ether type ion-selective electrodes are suitable for use with aqueous solution at pH > 3.

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A Pilot Experiments for Evaluation of Cover Soil Loss from Inclined Upland around Remediated Abandoned Mine Site - The Condition of Chemical Characteristics and Inclination - (광해복원 경사지 밭의 토양유실 평가를 위한 현장실험 - 화학적 성질과 경사도 조건에서 -)

  • Yun, Sung-Wook;Kang, Hui-Cheon;Kwon, Yo-Seb;Koh, Il-Ha;Jeong, Mun-Ho;Yu, Chan
    • Journal of The Korean Society of Agricultural Engineers
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    • v.64 no.2
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    • pp.37-45
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    • 2022
  • In-situ pilot experiment was carried out to establish a countermeasure on the soil loss from the hill side uplands that was rehabilitated by soil remediation method nearby abandoned mine sites for 2 years. It was considered that the affect of an inclination of cover surface, a stabilization treatment of cover layer by lime and steel refining slag (SRS) and a vegetation of soil surface as an effect factors in the experiment. It was constructed 4 lysimeters (plots, 22 m long, 4 m width) on the hilly side (37% inclination). One plot was control and two plots was treated by 1% lime and SRS. A remind one plot was modified a inclination to 27% to compare the affect of inclination on the amount of cover soil loss. It was attached a reservior tank and water level gauge in the end of lysimeters to measure the amount of the surface water flow and soil loss. It was also installed the automated sensors that could be collect the precipitation, soil moisture content, tension of cover layer in each plots. It was observed that the event of precipitation were caused the soil loss and it were related the physical and chemical properties of cover soil and inclination of surface layer of plots. During the experiment, it was exceeded the national regulation (50 t/ha/yr) in 37% inclination plots even though it was vegetated on the cover soil surface. However, in 27% inclination plot, it was shown that the amount of soil loss was maintained below the national regulation and, more ever, vegetation could reduce the the amount of soil loss. Therefore it was expected that such results could be applied to the future design of rehabilitation projects on the polluted farmland nearby abandoned mine sites.

Development of Three-Dimensional Deformable Flexible Printed Circuit Boards Using Ag Flake-Based Conductors and Thermoplastic Polyamide Substrates

  • Aram Lee;Minji Kang;Do Young Kim;Hee Yoon Jang;Ji-Won Park;Tae-Wook Kim;Jae-Min Hong;Seoung-Ki Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.420-426
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    • 2024
  • This study proposes an innovative methodology for developing flexible printed circuit boards (FPCBs) capable of conforming to three-dimensional shapes, meeting the increasing demand for electronic circuits in diverse and complex product designs. By integrating a traditional flat plate-based fabrication process with a subsequent three-dimensional thermal deformation technique, we have successfully demonstrated an FPCB that maintains stable electrical characteristics despite significant shape deformations. Using a modified polyimide substrate along with Ag flake-based conductive ink, we identified optimized process variables that enable substrate thermal deformation at lower temperatures (~130℃) and enhance the stretchability of the conductive ink (ε ~30%). The application of this novel FPCB in a prototype 3D-shaped sensor device, incorporating photosensors and temperature sensors, illustrates its potential for creating multifunctional, shape-adaptable electronic devices. The sensor can detect external light sources and measure ambient temperature, demonstrating stable operation even after transitioning from a planar to a three-dimensional configuration. This research lays the foundation for next-generation FPCBs that can be seamlessly integrated into various products, ushering in a new era of electronic device design and functionality.

Ultrasensitive Crack-based Mechanosensor Inspired by Spider's Sensory Organ (거미의 감각기관을 모사한 초민감 균열기반 진동압력센서)

  • Suyoun Oh;Tae-il Kim
    • Journal of the Microelectronics and Packaging Society
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    • v.31 no.1
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    • pp.1-6
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    • 2024
  • Spiders detect even tiny vibrations through their vibrational sensory organs. Leveraging their exceptional vibration sensing abilities, they can detect vibrations caused by prey or predators to plan attacks or perceive threats, utilizing them for survival. This paper introduces a nanoscale crack-based sensor mimicking the spider's sensory organ. Inspired by the slit sensory organ used by spiders to detect vibrations, the sensor with the cracks detects vibrations and pressure with high sensitivity. By controlling the depth of these cracks, they developed a sensor capable of detecting external mechanical signals with remarkable sensitivity. This sensor achieves a gauge factor of 16,000 at 2% strain with an applied tensile stress of 10 N. With high signal-to-noise ratio, it accurately recognizes desired vibrations, as confirmed through various evaluations of external force and biological signals (speech pattern, heart rate, etc.). This underscores the potential of utilizing biomimetic technology for the development of new sensors and their application across diverse industrial fields.

Effects of Blended TIPS-pentacene:ph-BTBT-10 Organic Semiconductors on the Photoresponse Characteristics of Organic Field-effect Transistors (TIPS-pentacene:ph-BTBT-10 혼합 유기반도체가 유기전계효과트랜지스터 광반응 특성에 미치는 영향)

  • Chae Min Park;Eun Kwang Lee
    • Clean Technology
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    • v.30 no.1
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    • pp.13-22
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    • 2024
  • In this study, blended 6,13-Bis(triisopropylsilylethynyl)pentacene (TP):2-Decyl-7-phenyl[1]benzothieno[3,2-b][1] benzothiophene (BT):Poly styrene (PS) TFT at different ratios were explored for their potential application as light absorption sensors. Due to the mixing of BT, both off current reduction and on/off ratio improvement were achieved at the same time. In particular, the TP:BT:PS (1:0.25:1 w/w) sample showed excellent light absorption characteristics, which proved that it is possible to manufacture a high-performance light absorption device. Through analysis of the crystal structure and electrical properties of the various mixing ratios, it was confirmed that the TP:BT:PS (1:0.25:1 w/w) sample was optimal. The results of this study outline the expected effects of this innovation not only for the development of light absorption devices but also for the development of mixed organic semiconductor (OSC) optoelectronic systems. Through this study, the potential to create a multipurpose platform that overcomes the limitations of using a single OSC and the potential to fabricate a high-performance OSC TFT with a fine-tuned optical response were confirmed.